Electrochemical Dehydrogenative sp2-Coupling Reaction of Naphthols Accessing a Polycyclic Naphthalenone Motif

A novel polycyclic naphthalenone motif was obtained by electrochemical synthesis starting from naphthols. The process is solvent controlled, and the highly diastereoselective cyclization is due to a solvent cage. The direct, anodic dehydrogenative sp2-coupling was carried out by flow electrolysis. T...

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Veröffentlicht in:Organic letters 2024-12
Hauptverfasser: Buchholz, Julian, Oehl, Elisabeth K, Hielscher, Maximilian M, Kuhn, Simone L, Schollmeyer, Dieter, Waldvogel, Siegfried R
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Sprache:eng
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