Synthetic Studies of Javaberine A Based on Intramolecular Hydroamination of Alkenes

A total synthesis of javaberine A was achieved through a lithium amide-mediated intramolecular hydroamination of an N-allyl aminoalkene. The desired hydroamination was accomplished using an excess of i-Pr NH with a substoichiometric amount of n-BuLi. Using an excess of both n-BuLi and i-Pr NH led to...

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Veröffentlicht in:	Chemical & pharmaceutical bulletin 2024-12, Vol.72 (12), p.1043-1047, Article c24-00693
Hauptverfasser:	Yamamoto, Yasutomo, Baba, Hiromi, Toriyama, Miki, Tomioka, Kiyoshi
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes - chemical synthesis Alkenes - chemistry Amination Cyclization Molecular Structure Stereoisomerism
Online-Zugang:	Volltext
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