Microwave/ultrasonic powered in-liquid plasma-assisted synthesis of 3D-hierarchical nanoporous network wheat-straw lignin/thiadiazole amide-modified cellulose sponge composite for oil-in-water emulsion separation and microbiological disinfection
Innovative super-hydrophilic/superoleophobic eco-friendly sponge composite is fabricated by integrating chemically-modified cellulose with lignin derived from bio-waste wheat-straw. Such combination is implemented by modifying cellulose with thiadiazole-amide and integrating it with lignin using mic...
Gespeichert in:
| Veröffentlicht in: | International journal of biological macromolecules 2025-01, Vol.284 (Pt 1), p.138127, Article 138127 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | |
|---|---|
| container_issue | Pt 1 |
| container_start_page | 138127 |
| container_title | International journal of biological macromolecules |
| container_volume | 284 |
| creator | Kanaan, Belal M. Algohary, Ayman M. Alhalafi, Zahra H. Rizk, Sameh A. Darwish, Atef S. |
| description | Innovative super-hydrophilic/superoleophobic eco-friendly sponge composite is fabricated by integrating chemically-modified cellulose with lignin derived from bio-waste wheat-straw. Such combination is implemented by modifying cellulose with thiadiazole-amide and integrating it with lignin using microwave/ultrasonic-powered in-liquid plasma. Physicochemical characteristics of sponge-composite (WL-TDAC) are studied using FTIR, N2-physisorption, DLS, SEM, chemical-computational analysis, and surface wettability. In-liquid plasma irradiations inspire formation of abundant hydrogen bonds between cellulose and lignin, constructing highly negatively-charged sponge (ζAv = −36 eV) of developed surface character and 3D-hierarchical interconnected porous structure with a pore-size of ~2 nm. Sponge-composite displays underwater-oil-contact angles of 124° and 164.8° for n-hexane/water and dichloromethane/water mixtures, respectively, with water-contact-angle near 0°. Superhydrophilic-superoleophobic sponge powerfully separates light-oil/water and heavy-oil/water mixtures yielding water-permeation-fluxes of 8812.5 and 7500 L/m2/h, respectively, keeping separation-efficiencies >96 % for ten-cycles. Sponge-composite is a gorgeous disinfectant against hazardous bacteria/fungi. Cellulose-based lignin sponge seeds as promissory futuristic oil-in-water emulsion antimicrobial separator features for cleaning wastewater from oils and noxious microorganisms.
•Cellulose was modified by thiadiazole amide heterocyclic compound.•In-liquid plasma-aided coupling of organo-modified cellulose by wheat straw-lignin.•In-liquid plasma firmly assists cellulose hydrogen bonded by lignin to form sponge.•Modified cellulose/lignin sponge owes super oil/water emulsion separation efficacy.•Organo-modified cellulose/lignin sponge possesses excellent biocidal activity. |
| doi_str_mv | 10.1016/j.ijbiomac.2024.138127 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_3134065759</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0141813024089384</els_id><sourcerecordid>3134065759</sourcerecordid><originalsourceid>FETCH-LOGICAL-c278t-c6a730340978b289f420f55c068657f5db8fab34ff151edad7db9d4f6d0f2a5e3</originalsourceid><addsrcrecordid>eNqNUsuO1DAQjBCIHRZ-YeUjl8zYeecGWp7SIi5wjjp2e9KDY2ftZKPlv7njMLtc4eRXdVdXuZLkSvC94KI6nPZ06smNIPcZz4q9yBuR1U-SnWjqNuWc50-THReFSBuR84vkRQineFuVonmeXORtxZsyy3bJry8kvVvhDg-LmT0EZ0myya3oUTGyqaHbhRSbDIQRUgiBwhxfwr2dB4wH5jTL36UDoQcvB5JgmAXrJufdEpjFeXX-B1sHhDkNkWFlho6W7GEeCBTBT2eQwUgK09Ep0hS7SzRmMS4gC5OzR2TSjZMLNCPTzjNHJo2jrTCjZzguJpCzLOAEHuZtC1axcRMWLTLu-GcoRYGsRrkBXibPNJiArx7Wy-T7h_ffrj-lN18_fr5-e5PKrG7mVFZQ5zwveFs3fda0usi4LkvJq6Yqa12qvtHQ54XWohSoQNWqb1WhK8V1BiXml8nrc9_Ju9sFw9yNFDZxYDG60-WiLLKyyevsP6BxjshathFanaFRYAgedTd5GsHfd4J3Wzq6U_eYjm5LR3dORyy8euBY-hHV37LHOETAmzMAoyl38Uu7IAmtREU-OtcpR__i-A3BHdgc</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3134065759</pqid></control><display><type>article</type><title>Microwave/ultrasonic powered in-liquid plasma-assisted synthesis of 3D-hierarchical nanoporous network wheat-straw lignin/thiadiazole amide-modified cellulose sponge composite for oil-in-water emulsion separation and microbiological disinfection</title><source>MEDLINE</source><source>Elsevier ScienceDirect Journals</source><creator>Kanaan, Belal M. ; Algohary, Ayman M. ; Alhalafi, Zahra H. ; Rizk, Sameh A. ; Darwish, Atef S.</creator><creatorcontrib>Kanaan, Belal M. ; Algohary, Ayman M. ; Alhalafi, Zahra H. ; Rizk, Sameh A. ; Darwish, Atef S.</creatorcontrib><description>Innovative super-hydrophilic/superoleophobic eco-friendly sponge composite is fabricated by integrating chemically-modified cellulose with lignin derived from bio-waste wheat-straw. Such combination is implemented by modifying cellulose with thiadiazole-amide and integrating it with lignin using microwave/ultrasonic-powered in-liquid plasma. Physicochemical characteristics of sponge-composite (WL-TDAC) are studied using FTIR, N2-physisorption, DLS, SEM, chemical-computational analysis, and surface wettability. In-liquid plasma irradiations inspire formation of abundant hydrogen bonds between cellulose and lignin, constructing highly negatively-charged sponge (ζAv = −36 eV) of developed surface character and 3D-hierarchical interconnected porous structure with a pore-size of ~2 nm. Sponge-composite displays underwater-oil-contact angles of 124° and 164.8° for n-hexane/water and dichloromethane/water mixtures, respectively, with water-contact-angle near 0°. Superhydrophilic-superoleophobic sponge powerfully separates light-oil/water and heavy-oil/water mixtures yielding water-permeation-fluxes of 8812.5 and 7500 L/m2/h, respectively, keeping separation-efficiencies >96 % for ten-cycles. Sponge-composite is a gorgeous disinfectant against hazardous bacteria/fungi. Cellulose-based lignin sponge seeds as promissory futuristic oil-in-water emulsion antimicrobial separator features for cleaning wastewater from oils and noxious microorganisms.
•Cellulose was modified by thiadiazole amide heterocyclic compound.•In-liquid plasma-aided coupling of organo-modified cellulose by wheat straw-lignin.•In-liquid plasma firmly assists cellulose hydrogen bonded by lignin to form sponge.•Modified cellulose/lignin sponge owes super oil/water emulsion separation efficacy.•Organo-modified cellulose/lignin sponge possesses excellent biocidal activity.</description><identifier>ISSN: 0141-8130</identifier><identifier>ISSN: 1879-0003</identifier><identifier>EISSN: 1879-0003</identifier><identifier>DOI: 10.1016/j.ijbiomac.2024.138127</identifier><identifier>PMID: 39608522</identifier><language>eng</language><publisher>Netherlands: Elsevier B.V</publisher><subject>cellulose ; Cellulose - analogs & derivatives ; Cellulose - chemistry ; disinfectants ; disinfection ; Disinfection - methods ; Emulsions ; hydrogen ; Hydrophobic and Hydrophilic Interactions ; In-liquid plasma irradiation ; lignin ; Lignin - chemistry ; Lignin/thiadiazole amide-modified cellulose ; methylene chloride ; Microwaves ; Nanopores ; Oil-in-water emulsion separation and biological activity ; Oils - chemistry ; Plasma Gases - chemistry ; Porosity ; Thiadiazoles - chemistry ; Triticum - chemistry ; ultrasonics ; wastewater ; Water - chemistry ; wettability ; wheat straw</subject><ispartof>International journal of biological macromolecules, 2025-01, Vol.284 (Pt 1), p.138127, Article 138127</ispartof><rights>2024 Elsevier B.V.</rights><rights>Copyright © 2024 Elsevier B.V. All rights reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c278t-c6a730340978b289f420f55c068657f5db8fab34ff151edad7db9d4f6d0f2a5e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0141813024089384$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27903,27904,65309</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/39608522$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Kanaan, Belal M.</creatorcontrib><creatorcontrib>Algohary, Ayman M.</creatorcontrib><creatorcontrib>Alhalafi, Zahra H.</creatorcontrib><creatorcontrib>Rizk, Sameh A.</creatorcontrib><creatorcontrib>Darwish, Atef S.</creatorcontrib><title>Microwave/ultrasonic powered in-liquid plasma-assisted synthesis of 3D-hierarchical nanoporous network wheat-straw lignin/thiadiazole amide-modified cellulose sponge composite for oil-in-water emulsion separation and microbiological disinfection</title><title>International journal of biological macromolecules</title><addtitle>Int J Biol Macromol</addtitle><description>Innovative super-hydrophilic/superoleophobic eco-friendly sponge composite is fabricated by integrating chemically-modified cellulose with lignin derived from bio-waste wheat-straw. Such combination is implemented by modifying cellulose with thiadiazole-amide and integrating it with lignin using microwave/ultrasonic-powered in-liquid plasma. Physicochemical characteristics of sponge-composite (WL-TDAC) are studied using FTIR, N2-physisorption, DLS, SEM, chemical-computational analysis, and surface wettability. In-liquid plasma irradiations inspire formation of abundant hydrogen bonds between cellulose and lignin, constructing highly negatively-charged sponge (ζAv = −36 eV) of developed surface character and 3D-hierarchical interconnected porous structure with a pore-size of ~2 nm. Sponge-composite displays underwater-oil-contact angles of 124° and 164.8° for n-hexane/water and dichloromethane/water mixtures, respectively, with water-contact-angle near 0°. Superhydrophilic-superoleophobic sponge powerfully separates light-oil/water and heavy-oil/water mixtures yielding water-permeation-fluxes of 8812.5 and 7500 L/m2/h, respectively, keeping separation-efficiencies >96 % for ten-cycles. Sponge-composite is a gorgeous disinfectant against hazardous bacteria/fungi. Cellulose-based lignin sponge seeds as promissory futuristic oil-in-water emulsion antimicrobial separator features for cleaning wastewater from oils and noxious microorganisms.
•Cellulose was modified by thiadiazole amide heterocyclic compound.•In-liquid plasma-aided coupling of organo-modified cellulose by wheat straw-lignin.•In-liquid plasma firmly assists cellulose hydrogen bonded by lignin to form sponge.•Modified cellulose/lignin sponge owes super oil/water emulsion separation efficacy.•Organo-modified cellulose/lignin sponge possesses excellent biocidal activity.</description><subject>cellulose</subject><subject>Cellulose - analogs & derivatives</subject><subject>Cellulose - chemistry</subject><subject>disinfectants</subject><subject>disinfection</subject><subject>Disinfection - methods</subject><subject>Emulsions</subject><subject>hydrogen</subject><subject>Hydrophobic and Hydrophilic Interactions</subject><subject>In-liquid plasma irradiation</subject><subject>lignin</subject><subject>Lignin - chemistry</subject><subject>Lignin/thiadiazole amide-modified cellulose</subject><subject>methylene chloride</subject><subject>Microwaves</subject><subject>Nanopores</subject><subject>Oil-in-water emulsion separation and biological activity</subject><subject>Oils - chemistry</subject><subject>Plasma Gases - chemistry</subject><subject>Porosity</subject><subject>Thiadiazoles - chemistry</subject><subject>Triticum - chemistry</subject><subject>ultrasonics</subject><subject>wastewater</subject><subject>Water - chemistry</subject><subject>wettability</subject><subject>wheat straw</subject><issn>0141-8130</issn><issn>1879-0003</issn><issn>1879-0003</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2025</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqNUsuO1DAQjBCIHRZ-YeUjl8zYeecGWp7SIi5wjjp2e9KDY2ftZKPlv7njMLtc4eRXdVdXuZLkSvC94KI6nPZ06smNIPcZz4q9yBuR1U-SnWjqNuWc50-THReFSBuR84vkRQineFuVonmeXORtxZsyy3bJry8kvVvhDg-LmT0EZ0myya3oUTGyqaHbhRSbDIQRUgiBwhxfwr2dB4wH5jTL36UDoQcvB5JgmAXrJufdEpjFeXX-B1sHhDkNkWFlho6W7GEeCBTBT2eQwUgK09Ep0hS7SzRmMS4gC5OzR2TSjZMLNCPTzjNHJo2jrTCjZzguJpCzLOAEHuZtC1axcRMWLTLu-GcoRYGsRrkBXibPNJiArx7Wy-T7h_ffrj-lN18_fr5-e5PKrG7mVFZQ5zwveFs3fda0usi4LkvJq6Yqa12qvtHQ54XWohSoQNWqb1WhK8V1BiXml8nrc9_Ju9sFw9yNFDZxYDG60-WiLLKyyevsP6BxjshathFanaFRYAgedTd5GsHfd4J3Wzq6U_eYjm5LR3dORyy8euBY-hHV37LHOETAmzMAoyl38Uu7IAmtREU-OtcpR__i-A3BHdgc</recordid><startdate>20250101</startdate><enddate>20250101</enddate><creator>Kanaan, Belal M.</creator><creator>Algohary, Ayman M.</creator><creator>Alhalafi, Zahra H.</creator><creator>Rizk, Sameh A.</creator><creator>Darwish, Atef S.</creator><general>Elsevier B.V</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7S9</scope><scope>L.6</scope></search><sort><creationdate>20250101</creationdate><title>Microwave/ultrasonic powered in-liquid plasma-assisted synthesis of 3D-hierarchical nanoporous network wheat-straw lignin/thiadiazole amide-modified cellulose sponge composite for oil-in-water emulsion separation and microbiological disinfection</title><author>Kanaan, Belal M. ; Algohary, Ayman M. ; Alhalafi, Zahra H. ; Rizk, Sameh A. ; Darwish, Atef S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c278t-c6a730340978b289f420f55c068657f5db8fab34ff151edad7db9d4f6d0f2a5e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2025</creationdate><topic>cellulose</topic><topic>Cellulose - analogs & derivatives</topic><topic>Cellulose - chemistry</topic><topic>disinfectants</topic><topic>disinfection</topic><topic>Disinfection - methods</topic><topic>Emulsions</topic><topic>hydrogen</topic><topic>Hydrophobic and Hydrophilic Interactions</topic><topic>In-liquid plasma irradiation</topic><topic>lignin</topic><topic>Lignin - chemistry</topic><topic>Lignin/thiadiazole amide-modified cellulose</topic><topic>methylene chloride</topic><topic>Microwaves</topic><topic>Nanopores</topic><topic>Oil-in-water emulsion separation and biological activity</topic><topic>Oils - chemistry</topic><topic>Plasma Gases - chemistry</topic><topic>Porosity</topic><topic>Thiadiazoles - chemistry</topic><topic>Triticum - chemistry</topic><topic>ultrasonics</topic><topic>wastewater</topic><topic>Water - chemistry</topic><topic>wettability</topic><topic>wheat straw</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kanaan, Belal M.</creatorcontrib><creatorcontrib>Algohary, Ayman M.</creatorcontrib><creatorcontrib>Alhalafi, Zahra H.</creatorcontrib><creatorcontrib>Rizk, Sameh A.</creatorcontrib><creatorcontrib>Darwish, Atef S.</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>AGRICOLA</collection><collection>AGRICOLA - Academic</collection><jtitle>International journal of biological macromolecules</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kanaan, Belal M.</au><au>Algohary, Ayman M.</au><au>Alhalafi, Zahra H.</au><au>Rizk, Sameh A.</au><au>Darwish, Atef S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Microwave/ultrasonic powered in-liquid plasma-assisted synthesis of 3D-hierarchical nanoporous network wheat-straw lignin/thiadiazole amide-modified cellulose sponge composite for oil-in-water emulsion separation and microbiological disinfection</atitle><jtitle>International journal of biological macromolecules</jtitle><addtitle>Int J Biol Macromol</addtitle><date>2025-01-01</date><risdate>2025</risdate><volume>284</volume><issue>Pt 1</issue><spage>138127</spage><pages>138127-</pages><artnum>138127</artnum><issn>0141-8130</issn><issn>1879-0003</issn><eissn>1879-0003</eissn><abstract>Innovative super-hydrophilic/superoleophobic eco-friendly sponge composite is fabricated by integrating chemically-modified cellulose with lignin derived from bio-waste wheat-straw. Such combination is implemented by modifying cellulose with thiadiazole-amide and integrating it with lignin using microwave/ultrasonic-powered in-liquid plasma. Physicochemical characteristics of sponge-composite (WL-TDAC) are studied using FTIR, N2-physisorption, DLS, SEM, chemical-computational analysis, and surface wettability. In-liquid plasma irradiations inspire formation of abundant hydrogen bonds between cellulose and lignin, constructing highly negatively-charged sponge (ζAv = −36 eV) of developed surface character and 3D-hierarchical interconnected porous structure with a pore-size of ~2 nm. Sponge-composite displays underwater-oil-contact angles of 124° and 164.8° for n-hexane/water and dichloromethane/water mixtures, respectively, with water-contact-angle near 0°. Superhydrophilic-superoleophobic sponge powerfully separates light-oil/water and heavy-oil/water mixtures yielding water-permeation-fluxes of 8812.5 and 7500 L/m2/h, respectively, keeping separation-efficiencies >96 % for ten-cycles. Sponge-composite is a gorgeous disinfectant against hazardous bacteria/fungi. Cellulose-based lignin sponge seeds as promissory futuristic oil-in-water emulsion antimicrobial separator features for cleaning wastewater from oils and noxious microorganisms.
•Cellulose was modified by thiadiazole amide heterocyclic compound.•In-liquid plasma-aided coupling of organo-modified cellulose by wheat straw-lignin.•In-liquid plasma firmly assists cellulose hydrogen bonded by lignin to form sponge.•Modified cellulose/lignin sponge owes super oil/water emulsion separation efficacy.•Organo-modified cellulose/lignin sponge possesses excellent biocidal activity.</abstract><cop>Netherlands</cop><pub>Elsevier B.V</pub><pmid>39608522</pmid><doi>10.1016/j.ijbiomac.2024.138127</doi></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0141-8130 |
| ispartof | International journal of biological macromolecules, 2025-01, Vol.284 (Pt 1), p.138127, Article 138127 |
| issn | 0141-8130 1879-0003 1879-0003 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_3134065759 |
| source | MEDLINE; Elsevier ScienceDirect Journals |
| subjects | cellulose Cellulose - analogs & derivatives Cellulose - chemistry disinfectants disinfection Disinfection - methods Emulsions hydrogen Hydrophobic and Hydrophilic Interactions In-liquid plasma irradiation lignin Lignin - chemistry Lignin/thiadiazole amide-modified cellulose methylene chloride Microwaves Nanopores Oil-in-water emulsion separation and biological activity Oils - chemistry Plasma Gases - chemistry Porosity Thiadiazoles - chemistry Triticum - chemistry ultrasonics wastewater Water - chemistry wettability wheat straw |
| title | Microwave/ultrasonic powered in-liquid plasma-assisted synthesis of 3D-hierarchical nanoporous network wheat-straw lignin/thiadiazole amide-modified cellulose sponge composite for oil-in-water emulsion separation and microbiological disinfection |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-28T02%3A48%3A34IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Microwave/ultrasonic%20powered%20in-liquid%20plasma-assisted%20synthesis%20of%203D-hierarchical%20nanoporous%20network%20wheat-straw%20lignin/thiadiazole%20amide-modified%20cellulose%20sponge%20composite%20for%20oil-in-water%20emulsion%20separation%20and%20microbiological%20disinfection&rft.jtitle=International%20journal%20of%20biological%20macromolecules&rft.au=Kanaan,%20Belal%20M.&rft.date=2025-01-01&rft.volume=284&rft.issue=Pt%201&rft.spage=138127&rft.pages=138127-&rft.artnum=138127&rft.issn=0141-8130&rft.eissn=1879-0003&rft_id=info:doi/10.1016/j.ijbiomac.2024.138127&rft_dat=%3Cproquest_cross%3E3134065759%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=3134065759&rft_id=info:pmid/39608522&rft_els_id=S0141813024089384&rfr_iscdi=true |