Joule-Heated Interfacial Catalysis for Advanced Electrified Esterification with High Conversion and Energy Efficiency
Esterification reactions are crucial in industries such as chemicals, fragrances, and pharmaceuticals but often face limitations due to high reversibility and low reactivity, leading to restricted yields. In this work, an electrified esterification pathway utilizing a Joule-heated interfacial cataly...
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| Veröffentlicht in: | Advanced materials (Weinheim) 2025-01, Vol.37 (4), p.e2413949 |
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| container_title | Advanced materials (Weinheim) |
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| creator | Zhang, Jifang Zhang, Xinyuan Shen, Yue Fu, Bo Wu, Yijin Kang, Jian Chen, Shan Wang, Guozhong Zhang, Haimin Yin, Huajie Zhao, Huijun |
| description | Esterification reactions are crucial in industries such as chemicals, fragrances, and pharmaceuticals but often face limitations due to high reversibility and low reactivity, leading to restricted yields. In this work, an electrified esterification pathway utilizing a Joule-heated interfacial catalysis (JIC) system is proposed, where a hydrophilic, sulfonic acid-functionalized covalent organic framework grown on carbon felt (COF─SO
H@CF) acts as the interfacial catalyst, and the carbon felt serves as the electric heat source. This approach achieves an acetic acid conversion of 80.5% at a heating power density of 0.49 W cm
, without additional reagents by vaporizing reaction products, surpassing the theoretical equilibrium limit of 62.5% by 1.29 times. Comprehensive analysis indicates that the intimate contact between the electric heat source and the COF─SO
H catalyst enables efficient, localized Joule heating directly at catalytic sites, minimizing thermal losses and allowing precise control over reaction interfaces. This finding demonstrates that this JIC system not only enhances esterification efficiency but may also offer a sustainable, energy-efficient pathway for high-yield chemical processes. |
| doi_str_mv | 10.1002/adma.202413949 |
| format | Article |
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H@CF) acts as the interfacial catalyst, and the carbon felt serves as the electric heat source. This approach achieves an acetic acid conversion of 80.5% at a heating power density of 0.49 W cm
, without additional reagents by vaporizing reaction products, surpassing the theoretical equilibrium limit of 62.5% by 1.29 times. Comprehensive analysis indicates that the intimate contact between the electric heat source and the COF─SO
H catalyst enables efficient, localized Joule heating directly at catalytic sites, minimizing thermal losses and allowing precise control over reaction interfaces. This finding demonstrates that this JIC system not only enhances esterification efficiency but may also offer a sustainable, energy-efficient pathway for high-yield chemical processes.</description><identifier>ISSN: 0935-9648</identifier><identifier>ISSN: 1521-4095</identifier><identifier>EISSN: 1521-4095</identifier><identifier>DOI: 10.1002/adma.202413949</identifier><identifier>PMID: 39588892</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>Acetic acid ; Carbon ; Catalysis ; Catalysts ; Catalytic converters ; Chemical reactions ; Electric contacts ; Energy conversion efficiency ; Esterification ; Ohmic dissipation ; Reaction products ; Reagents ; Resistance heating ; Sulfonic acid</subject><ispartof>Advanced materials (Weinheim), 2025-01, Vol.37 (4), p.e2413949</ispartof><rights>2024 Wiley‐VCH GmbH.</rights><rights>2025 Wiley‐VCH GmbH</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c208t-111e705adc7d3eeefca0dc29cefcf174a294f740069c50077d9c2c07142098e43</cites><orcidid>0000-0002-9036-9084 ; 0000-0002-3028-0459</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/39588892$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Zhang, Jifang</creatorcontrib><creatorcontrib>Zhang, Xinyuan</creatorcontrib><creatorcontrib>Shen, Yue</creatorcontrib><creatorcontrib>Fu, Bo</creatorcontrib><creatorcontrib>Wu, Yijin</creatorcontrib><creatorcontrib>Kang, Jian</creatorcontrib><creatorcontrib>Chen, Shan</creatorcontrib><creatorcontrib>Wang, Guozhong</creatorcontrib><creatorcontrib>Zhang, Haimin</creatorcontrib><creatorcontrib>Yin, Huajie</creatorcontrib><creatorcontrib>Zhao, Huijun</creatorcontrib><title>Joule-Heated Interfacial Catalysis for Advanced Electrified Esterification with High Conversion and Energy Efficiency</title><title>Advanced materials (Weinheim)</title><addtitle>Adv Mater</addtitle><description>Esterification reactions are crucial in industries such as chemicals, fragrances, and pharmaceuticals but often face limitations due to high reversibility and low reactivity, leading to restricted yields. In this work, an electrified esterification pathway utilizing a Joule-heated interfacial catalysis (JIC) system is proposed, where a hydrophilic, sulfonic acid-functionalized covalent organic framework grown on carbon felt (COF─SO
H@CF) acts as the interfacial catalyst, and the carbon felt serves as the electric heat source. This approach achieves an acetic acid conversion of 80.5% at a heating power density of 0.49 W cm
, without additional reagents by vaporizing reaction products, surpassing the theoretical equilibrium limit of 62.5% by 1.29 times. Comprehensive analysis indicates that the intimate contact between the electric heat source and the COF─SO
H catalyst enables efficient, localized Joule heating directly at catalytic sites, minimizing thermal losses and allowing precise control over reaction interfaces. This finding demonstrates that this JIC system not only enhances esterification efficiency but may also offer a sustainable, energy-efficient pathway for high-yield chemical processes.</description><subject>Acetic acid</subject><subject>Carbon</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Catalytic converters</subject><subject>Chemical reactions</subject><subject>Electric contacts</subject><subject>Energy conversion efficiency</subject><subject>Esterification</subject><subject>Ohmic dissipation</subject><subject>Reaction products</subject><subject>Reagents</subject><subject>Resistance heating</subject><subject>Sulfonic acid</subject><issn>0935-9648</issn><issn>1521-4095</issn><issn>1521-4095</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2025</creationdate><recordtype>article</recordtype><recordid>eNpd0cFLwzAYBfAgipvTq0cpePHS-SVNm-Y4xnTKwIueS0y_zEiXzqRV9t-bsrmDpzzCL4_AI-SawpQCsHtVb9SUAeM0k1yekDHNGU05yPyUjEFmeSoLXo7IRQifACALKM7JKJN5WZaSjUn_3PYNpktUHdbJk-vQG6WtapK56lSzCzYkpvXJrP5WTkeyaFB33ho75BB5jFp1tnXJj-0-kqVdfyTz1n2jD8OlctE59OtdsjCRWnR6d0nOjGoCXh3OCXl7WLzOl-nq5fFpPlulmkHZpZRSFJCrWos6Q0SjFdSaSR2ToYIrJrkRHKCQOgcQopaaaRCUM5Al8mxC7va9W99-9Ri6amODxqZRDts-VBnNWMkF0CLS23_0s-29i7-LqgDBIJdD4XSvtG9D8Giqrbcb5XcVhWoYpBoGqY6DxAc3h9r-fYP1kf8tkP0CAMSHSQ</recordid><startdate>202501</startdate><enddate>202501</enddate><creator>Zhang, Jifang</creator><creator>Zhang, Xinyuan</creator><creator>Shen, Yue</creator><creator>Fu, Bo</creator><creator>Wu, Yijin</creator><creator>Kang, Jian</creator><creator>Chen, Shan</creator><creator>Wang, Guozhong</creator><creator>Zhang, Haimin</creator><creator>Yin, Huajie</creator><creator>Zhao, Huijun</creator><general>Wiley Subscription Services, Inc</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-9036-9084</orcidid><orcidid>https://orcid.org/0000-0002-3028-0459</orcidid></search><sort><creationdate>202501</creationdate><title>Joule-Heated Interfacial Catalysis for Advanced Electrified Esterification with High Conversion and Energy Efficiency</title><author>Zhang, Jifang ; Zhang, Xinyuan ; Shen, Yue ; Fu, Bo ; Wu, Yijin ; Kang, Jian ; Chen, Shan ; Wang, Guozhong ; Zhang, Haimin ; Yin, Huajie ; Zhao, Huijun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c208t-111e705adc7d3eeefca0dc29cefcf174a294f740069c50077d9c2c07142098e43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2025</creationdate><topic>Acetic acid</topic><topic>Carbon</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Catalytic converters</topic><topic>Chemical reactions</topic><topic>Electric contacts</topic><topic>Energy conversion efficiency</topic><topic>Esterification</topic><topic>Ohmic dissipation</topic><topic>Reaction products</topic><topic>Reagents</topic><topic>Resistance heating</topic><topic>Sulfonic acid</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Jifang</creatorcontrib><creatorcontrib>Zhang, Xinyuan</creatorcontrib><creatorcontrib>Shen, Yue</creatorcontrib><creatorcontrib>Fu, Bo</creatorcontrib><creatorcontrib>Wu, Yijin</creatorcontrib><creatorcontrib>Kang, Jian</creatorcontrib><creatorcontrib>Chen, Shan</creatorcontrib><creatorcontrib>Wang, Guozhong</creatorcontrib><creatorcontrib>Zhang, Haimin</creatorcontrib><creatorcontrib>Yin, Huajie</creatorcontrib><creatorcontrib>Zhao, Huijun</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><jtitle>Advanced materials (Weinheim)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Jifang</au><au>Zhang, Xinyuan</au><au>Shen, Yue</au><au>Fu, Bo</au><au>Wu, Yijin</au><au>Kang, Jian</au><au>Chen, Shan</au><au>Wang, Guozhong</au><au>Zhang, Haimin</au><au>Yin, Huajie</au><au>Zhao, Huijun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Joule-Heated Interfacial Catalysis for Advanced Electrified Esterification with High Conversion and Energy Efficiency</atitle><jtitle>Advanced materials (Weinheim)</jtitle><addtitle>Adv Mater</addtitle><date>2025-01</date><risdate>2025</risdate><volume>37</volume><issue>4</issue><spage>e2413949</spage><pages>e2413949-</pages><issn>0935-9648</issn><issn>1521-4095</issn><eissn>1521-4095</eissn><abstract>Esterification reactions are crucial in industries such as chemicals, fragrances, and pharmaceuticals but often face limitations due to high reversibility and low reactivity, leading to restricted yields. In this work, an electrified esterification pathway utilizing a Joule-heated interfacial catalysis (JIC) system is proposed, where a hydrophilic, sulfonic acid-functionalized covalent organic framework grown on carbon felt (COF─SO
H@CF) acts as the interfacial catalyst, and the carbon felt serves as the electric heat source. This approach achieves an acetic acid conversion of 80.5% at a heating power density of 0.49 W cm
, without additional reagents by vaporizing reaction products, surpassing the theoretical equilibrium limit of 62.5% by 1.29 times. Comprehensive analysis indicates that the intimate contact between the electric heat source and the COF─SO
H catalyst enables efficient, localized Joule heating directly at catalytic sites, minimizing thermal losses and allowing precise control over reaction interfaces. This finding demonstrates that this JIC system not only enhances esterification efficiency but may also offer a sustainable, energy-efficient pathway for high-yield chemical processes.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>39588892</pmid><doi>10.1002/adma.202413949</doi><orcidid>https://orcid.org/0000-0002-9036-9084</orcidid><orcidid>https://orcid.org/0000-0002-3028-0459</orcidid></addata></record> |
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| subjects | Acetic acid Carbon Catalysis Catalysts Catalytic converters Chemical reactions Electric contacts Energy conversion efficiency Esterification Ohmic dissipation Reaction products Reagents Resistance heating Sulfonic acid |
| title | Joule-Heated Interfacial Catalysis for Advanced Electrified Esterification with High Conversion and Energy Efficiency |
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