Anatase/TiO2(B) homojunction nanosheets with a gold cocatalyst for direct photocatalytic coupling of methane to ethane
An anatase/TiO2(B) homojunction loaded with Au nanoparticles was synthesized, achieving a C2H6 yield rate of 170 μmol g−1 h−1 in a flow photoreactor. The homojunction reduces TiO2(B)'s strong oxidative ability, offering a more moderate environment for methane dehydrogenation, while Au aids in c...
Gespeichert in:
| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2024-11, Vol.60 (96), p.14276-14279 |
|---|---|
| Hauptverfasser: | , , , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 14279 |
|---|---|
| container_issue | 96 |
| container_start_page | 14276 |
| container_title | Chemical communications (Cambridge, England) |
| container_volume | 60 |
| creator | Lu, Xuanzhao Luo, Huanhuan Xu, Biyang Liu, Zhuo Cao, Yue Li, Kai Yang, Xiaohan Xie, Liangyiqun Guan, Tao Zhu, Wenlei Zhou, Yang |
| description | An anatase/TiO2(B) homojunction loaded with Au nanoparticles was synthesized, achieving a C2H6 yield rate of 170 μmol g−1 h−1 in a flow photoreactor. The homojunction reduces TiO2(B)'s strong oxidative ability, offering a more moderate environment for methane dehydrogenation, while Au aids in charge mitigation and methyl radical coupling. The catalyst highlights homojunction engineering and a ternary synergistic effect in photocatalytic CH4 coupling. |
| doi_str_mv | 10.1039/d4cc05090h |
| format | Article |
| fullrecord | <record><control><sourceid>proquest</sourceid><recordid>TN_cdi_proquest_miscellaneous_3128825901</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3133665863</sourcerecordid><originalsourceid>FETCH-LOGICAL-p146t-42f8c7f9d914e409d13279fbaed06e3a097c603ff3ff2b2819b7ffa021776a1d3</originalsourceid><addsrcrecordid>eNpdjktLAzEUhYMoWKsbf0HATV2MzXsmy1p8QaGbCu5KJpN0UqbJOMko_nsj7crLgXvgfudyALjF6AEjKucN0xpxJFF7BiaYClZwVn2c_3kui5IyfgmuYtyjPJhXE_C18CqpaOYbtyazx3vYhkPYj14nFzz0yofYGpMi_HaphQruQtdAHXQOdT8xQRsG2LjB6AT7NqTTITmdobHvnN_BYOHBpFZ5A1OAR3cNLqzqork57Sl4f37aLF-L1frlbblYFT1mIhWM2EqXVjYSM8OQbDAlpbS1Mg0ShiokSy0QtTaL1KTCsi6tVYjgshQKN3QKZse__RA-RxPT9uCiNl2XO4QxbikmVUW4RDijd__QfRgHn9tlilIheCUo_QVYLGzG</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3133665863</pqid></control><display><type>article</type><title>Anatase/TiO2(B) homojunction nanosheets with a gold cocatalyst for direct photocatalytic coupling of methane to ethane</title><source>Royal Society Of Chemistry Journals</source><source>Alma/SFX Local Collection</source><creator>Lu, Xuanzhao ; Luo, Huanhuan ; Xu, Biyang ; Liu, Zhuo ; Cao, Yue ; Li, Kai ; Yang, Xiaohan ; Xie, Liangyiqun ; Guan, Tao ; Zhu, Wenlei ; Zhou, Yang</creator><creatorcontrib>Lu, Xuanzhao ; Luo, Huanhuan ; Xu, Biyang ; Liu, Zhuo ; Cao, Yue ; Li, Kai ; Yang, Xiaohan ; Xie, Liangyiqun ; Guan, Tao ; Zhu, Wenlei ; Zhou, Yang</creatorcontrib><description>An anatase/TiO2(B) homojunction loaded with Au nanoparticles was synthesized, achieving a C2H6 yield rate of 170 μmol g−1 h−1 in a flow photoreactor. The homojunction reduces TiO2(B)'s strong oxidative ability, offering a more moderate environment for methane dehydrogenation, while Au aids in charge mitigation and methyl radical coupling. The catalyst highlights homojunction engineering and a ternary synergistic effect in photocatalytic CH4 coupling.</description><identifier>ISSN: 1359-7345</identifier><identifier>ISSN: 1364-548X</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/d4cc05090h</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Anatase ; Coupling ; Dehydrogenation ; Ethane ; Gold ; Homojunctions ; Methane ; Methyl radicals ; Synergistic effect ; Titanium dioxide</subject><ispartof>Chemical communications (Cambridge, England), 2024-11, Vol.60 (96), p.14276-14279</ispartof><rights>Copyright Royal Society of Chemistry 2024</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Lu, Xuanzhao</creatorcontrib><creatorcontrib>Luo, Huanhuan</creatorcontrib><creatorcontrib>Xu, Biyang</creatorcontrib><creatorcontrib>Liu, Zhuo</creatorcontrib><creatorcontrib>Cao, Yue</creatorcontrib><creatorcontrib>Li, Kai</creatorcontrib><creatorcontrib>Yang, Xiaohan</creatorcontrib><creatorcontrib>Xie, Liangyiqun</creatorcontrib><creatorcontrib>Guan, Tao</creatorcontrib><creatorcontrib>Zhu, Wenlei</creatorcontrib><creatorcontrib>Zhou, Yang</creatorcontrib><title>Anatase/TiO2(B) homojunction nanosheets with a gold cocatalyst for direct photocatalytic coupling of methane to ethane</title><title>Chemical communications (Cambridge, England)</title><description>An anatase/TiO2(B) homojunction loaded with Au nanoparticles was synthesized, achieving a C2H6 yield rate of 170 μmol g−1 h−1 in a flow photoreactor. The homojunction reduces TiO2(B)'s strong oxidative ability, offering a more moderate environment for methane dehydrogenation, while Au aids in charge mitigation and methyl radical coupling. The catalyst highlights homojunction engineering and a ternary synergistic effect in photocatalytic CH4 coupling.</description><subject>Anatase</subject><subject>Coupling</subject><subject>Dehydrogenation</subject><subject>Ethane</subject><subject>Gold</subject><subject>Homojunctions</subject><subject>Methane</subject><subject>Methyl radicals</subject><subject>Synergistic effect</subject><subject>Titanium dioxide</subject><issn>1359-7345</issn><issn>1364-548X</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpdjktLAzEUhYMoWKsbf0HATV2MzXsmy1p8QaGbCu5KJpN0UqbJOMko_nsj7crLgXvgfudyALjF6AEjKucN0xpxJFF7BiaYClZwVn2c_3kui5IyfgmuYtyjPJhXE_C18CqpaOYbtyazx3vYhkPYj14nFzz0yofYGpMi_HaphQruQtdAHXQOdT8xQRsG2LjB6AT7NqTTITmdobHvnN_BYOHBpFZ5A1OAR3cNLqzqork57Sl4f37aLF-L1frlbblYFT1mIhWM2EqXVjYSM8OQbDAlpbS1Mg0ShiokSy0QtTaL1KTCsi6tVYjgshQKN3QKZse__RA-RxPT9uCiNl2XO4QxbikmVUW4RDijd__QfRgHn9tlilIheCUo_QVYLGzG</recordid><startdate>20241128</startdate><enddate>20241128</enddate><creator>Lu, Xuanzhao</creator><creator>Luo, Huanhuan</creator><creator>Xu, Biyang</creator><creator>Liu, Zhuo</creator><creator>Cao, Yue</creator><creator>Li, Kai</creator><creator>Yang, Xiaohan</creator><creator>Xie, Liangyiqun</creator><creator>Guan, Tao</creator><creator>Zhu, Wenlei</creator><creator>Zhou, Yang</creator><general>Royal Society of Chemistry</general><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope></search><sort><creationdate>20241128</creationdate><title>Anatase/TiO2(B) homojunction nanosheets with a gold cocatalyst for direct photocatalytic coupling of methane to ethane</title><author>Lu, Xuanzhao ; Luo, Huanhuan ; Xu, Biyang ; Liu, Zhuo ; Cao, Yue ; Li, Kai ; Yang, Xiaohan ; Xie, Liangyiqun ; Guan, Tao ; Zhu, Wenlei ; Zhou, Yang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p146t-42f8c7f9d914e409d13279fbaed06e3a097c603ff3ff2b2819b7ffa021776a1d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Anatase</topic><topic>Coupling</topic><topic>Dehydrogenation</topic><topic>Ethane</topic><topic>Gold</topic><topic>Homojunctions</topic><topic>Methane</topic><topic>Methyl radicals</topic><topic>Synergistic effect</topic><topic>Titanium dioxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lu, Xuanzhao</creatorcontrib><creatorcontrib>Luo, Huanhuan</creatorcontrib><creatorcontrib>Xu, Biyang</creatorcontrib><creatorcontrib>Liu, Zhuo</creatorcontrib><creatorcontrib>Cao, Yue</creatorcontrib><creatorcontrib>Li, Kai</creatorcontrib><creatorcontrib>Yang, Xiaohan</creatorcontrib><creatorcontrib>Xie, Liangyiqun</creatorcontrib><creatorcontrib>Guan, Tao</creatorcontrib><creatorcontrib>Zhu, Wenlei</creatorcontrib><creatorcontrib>Zhou, Yang</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lu, Xuanzhao</au><au>Luo, Huanhuan</au><au>Xu, Biyang</au><au>Liu, Zhuo</au><au>Cao, Yue</au><au>Li, Kai</au><au>Yang, Xiaohan</au><au>Xie, Liangyiqun</au><au>Guan, Tao</au><au>Zhu, Wenlei</au><au>Zhou, Yang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Anatase/TiO2(B) homojunction nanosheets with a gold cocatalyst for direct photocatalytic coupling of methane to ethane</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><date>2024-11-28</date><risdate>2024</risdate><volume>60</volume><issue>96</issue><spage>14276</spage><epage>14279</epage><pages>14276-14279</pages><issn>1359-7345</issn><issn>1364-548X</issn><eissn>1364-548X</eissn><abstract>An anatase/TiO2(B) homojunction loaded with Au nanoparticles was synthesized, achieving a C2H6 yield rate of 170 μmol g−1 h−1 in a flow photoreactor. The homojunction reduces TiO2(B)'s strong oxidative ability, offering a more moderate environment for methane dehydrogenation, while Au aids in charge mitigation and methyl radical coupling. The catalyst highlights homojunction engineering and a ternary synergistic effect in photocatalytic CH4 coupling.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d4cc05090h</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2024-11, Vol.60 (96), p.14276-14279 |
| issn | 1359-7345 1364-548X 1364-548X |
| language | eng |
| recordid | cdi_proquest_miscellaneous_3128825901 |
| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| subjects | Anatase Coupling Dehydrogenation Ethane Gold Homojunctions Methane Methyl radicals Synergistic effect Titanium dioxide |
| title | Anatase/TiO2(B) homojunction nanosheets with a gold cocatalyst for direct photocatalytic coupling of methane to ethane |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-29T16%3A35%3A47IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Anatase/TiO2(B)%20homojunction%20nanosheets%20with%20a%20gold%20cocatalyst%20for%20direct%20photocatalytic%20coupling%20of%20methane%20to%20ethane&rft.jtitle=Chemical%20communications%20(Cambridge,%20England)&rft.au=Lu,%20Xuanzhao&rft.date=2024-11-28&rft.volume=60&rft.issue=96&rft.spage=14276&rft.epage=14279&rft.pages=14276-14279&rft.issn=1359-7345&rft.eissn=1364-548X&rft_id=info:doi/10.1039/d4cc05090h&rft_dat=%3Cproquest%3E3133665863%3C/proquest%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=3133665863&rft_id=info:pmid/&rfr_iscdi=true |