Copper Versatility in Hydroxyapatite: Valence States, Clusters, and Optical Absorption Properties

The solid-state reaction between a stoichiometric hydroxyapatite (HA) and CuO at temperatures above 1100 °C produces pure Cu x -HA phases for x ≤ 0.7 with the general formula Ca10CuI x (PO4)6(OH)2–x O x . The Cu atoms are located at the center of the hexagonal tunnels between two hydroxyl ligands, a...

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Veröffentlicht in:Inorganic chemistry 2024-11, Vol.63 (46), p.22181-22193
Hauptverfasser: Bazin, Tiphaine, Gaudon, Manuel, Champion, Eric, Julien, Isabelle, Prestipino, Carmelo, Figueroa, Santiago J.A., Duttine, Mathieu, Demourgues, Alain
Format: Artikel
Sprache:eng
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