Electrodeposition of Crack-Free Amorphous Zn-Ni Alloy from Ethylene Glycol Mixed ZnCl2-NiCl2-EMIC Ambient-Temperature Molten Salt Bath

Electrodeposition of Crack-Free Amorphous Zn-Ni Alloy from Ethylene Glycol Mixed ZnCl2-NiCl2-EMIC Ambient-Temperature Molten Salt Bath

The authors investigated deopsits of Zn-Ni alloys from a ZnCl2-NiCl2-EMIC ambient-temperature molten salt bath with various organic solvents added. It was found that the organic solvents had an effect on the surface morphology of alloys and the deposition conditions. The electrodeposit, which had a...

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Veröffentlicht in:Hyōmen gijutsu 2007, Vol.58(11), pp.682-682
Hauptverfasser: KOURA, Nobuyuki, KAMIURA, Naoko, TAKEUCHI, Ken, UI, Koich, YAMAZAKI, Takashi
Format: Artikel
Sprache:eng ; jpn
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Ambient-Temperature Molten Salt
Amorphous
Electrodeposition
Zn-Ni alloy
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container_end_page 682
container_issue 11
container_start_page 682
container_title Hyōmen gijutsu
container_volume 58
creator KOURA, Nobuyuki
KAMIURA, Naoko
TAKEUCHI, Ken
UI, Koich
YAMAZAKI, Takashi
description The authors investigated deopsits of Zn-Ni alloys from a ZnCl2-NiCl2-EMIC ambient-temperature molten salt bath with various organic solvents added. It was found that the organic solvents had an effect on the surface morphology of alloys and the deposition conditions. The electrodeposit, which had a smooth, glossy, and crack-free surface, was obtained at low current density using ethylene glycol as a solvent. In addition, a smoother, denser, and more uniform deposition was performed by agitation applying gas bubbling. A crack-free and smooth amorphous Zn-Ni deposit was obtained under the conditions of 80°C, 2.0mA ⋅ cm–2, and 1.0mol% NiCl2 content in a bath with gas bubbling.
doi_str_mv 10.4139/sfj.58.682
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subjects Ambient-Temperature Molten Salt
Amorphous
Electrodeposition
Zn-Ni alloy
title Electrodeposition of Crack-Free Amorphous Zn-Ni Alloy from Ethylene Glycol Mixed ZnCl2-NiCl2-EMIC Ambient-Temperature Molten Salt Bath
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