Layer-By-Layer Magnetic Ordering via Idle Spins and the Optical Signature of Jahn–Teller Cr2+ Ions in Sr2Cr(PO4)2

Blue/turquoise crystals of Sr2CrII(PO4)2 with prismatic shape and edge-length of up to 1 mm were obtained by a vapor-phase moderated solid-state reaction at 1273 K in sealed silica tubes. Its crystal structure was solved and refined from a triply twinned (“trilling”) crystal [Pbca (no. 61), Z = 12,...

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Veröffentlicht in:Inorganic chemistry 2024-11, Vol.63 (44), p.21000-21011
Hauptverfasser: Nimoh, Hicham, Mentré, Olivier, Hammer, Eva-Maria, Jähnig, Maximilian, Dittrich, Volker, Minaud, Claire, Colin, Claire V., Arevalo-Lopéz, Angel, Glaum, Robert
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Sprache:eng
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