Integrated geochemical analysis of urban and peri-urban soils: a case study of Lamia City, Greece
The occurrence of Potentially Toxic Elements (PTEs) and other chemical elements in urban and peri-urban soils impacts human health and quality of life, posing a challenge for geoscientists. This study investigated the soil geochemistry of Lamia City, focusing on identifying the geogenic and anthropo...
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| description | The occurrence of Potentially Toxic Elements (PTEs) and other chemical elements in urban and peri-urban soils impacts human health and quality of life, posing a challenge for geoscientists. This study investigated the soil geochemistry of Lamia City, focusing on identifying the geogenic and anthropogenic origins of elements. A total of 168 topsoil samples (0–10 cm) were collected in April 2023, and the analysis included the near-total concentrations of 51 elements. Descriptive, correlation, multivariate statistics (i.e., Factor Analysis-FA and Hierarchical Cluster Analysis-HCA), Geographic Information Systems (GIS) mapping, and mineralogical analysis were employed to identify potential element sources. The results indicated that the elements in soils originated from geogenic, anthropogenic, and mixed sources. Geogenic origins are associated with ultramafic rocks (e.g., Mg, Cr, Ni, Co, Fe, Sc, Mn), carbonate rocks (e.g., Ca, Sr), and Quaternary sediments (e.g., K, Na, Ba, Tl, Be, Rb, Ti, V, Ga, and Rare Earth Elements-REEs); associations are linked to specific identified minerals. All applied statistical analyses reveal that the mobility of chemical elements in the urban and peri-urban soils of Lamia city is primarily affected by geochemical processes such as element substitution, chemical weathering, pedogenesis, adsorption, precipitation, evaporation, and organic matter presence. The P, Ag, Hg, Pb, Sn, Zn, Sb, Cd, Cu, and U were associated with anthropogenic influences, particularly in areas with high population density, heavy vehicle traffic, and intensive agricultural practices. Additionally, some elements (e.g., Ca, Cd, Cu, Mo, Mn, and Li) exhibited mixed origins. This integrated approach offers valuable insights into the spatial distribution and sources of PTEs in urban and peri-urban environments, providing critical information for environmental management and public health protection strategies. |
| doi_str_mv | 10.1007/s10661-024-13223-8 |
| format | Article |
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This study investigated the soil geochemistry of Lamia City, focusing on identifying the geogenic and anthropogenic origins of elements. A total of 168 topsoil samples (0–10 cm) were collected in April 2023, and the analysis included the near-total concentrations of 51 elements. Descriptive, correlation, multivariate statistics (i.e., Factor Analysis-FA and Hierarchical Cluster Analysis-HCA), Geographic Information Systems (GIS) mapping, and mineralogical analysis were employed to identify potential element sources. The results indicated that the elements in soils originated from geogenic, anthropogenic, and mixed sources. Geogenic origins are associated with ultramafic rocks (e.g., Mg, Cr, Ni, Co, Fe, Sc, Mn), carbonate rocks (e.g., Ca, Sr), and Quaternary sediments (e.g., K, Na, Ba, Tl, Be, Rb, Ti, V, Ga, and Rare Earth Elements-REEs); associations are linked to specific identified minerals. All applied statistical analyses reveal that the mobility of chemical elements in the urban and peri-urban soils of Lamia city is primarily affected by geochemical processes such as element substitution, chemical weathering, pedogenesis, adsorption, precipitation, evaporation, and organic matter presence. The P, Ag, Hg, Pb, Sn, Zn, Sb, Cd, Cu, and U were associated with anthropogenic influences, particularly in areas with high population density, heavy vehicle traffic, and intensive agricultural practices. Additionally, some elements (e.g., Ca, Cd, Cu, Mo, Mn, and Li) exhibited mixed origins. This integrated approach offers valuable insights into the spatial distribution and sources of PTEs in urban and peri-urban environments, providing critical information for environmental management and public health protection strategies.</description><identifier>ISSN: 0167-6369</identifier><identifier>ISSN: 1573-2959</identifier><identifier>EISSN: 1573-2959</identifier><identifier>DOI: 10.1007/s10661-024-13223-8</identifier><identifier>PMID: 39402277</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Agricultural practices ; Anthropogenic factors ; Antimony ; Atmospheric Protection/Air Quality Control/Air Pollution ; Cadmium ; Calcium ; Carbonate rocks ; Carbonates ; Chemical elements ; Chemical weathering ; Cities ; Cluster analysis ; Copper ; Earth and Environmental Science ; Ecology ; Ecotoxicology ; Elements ; Environment ; Environmental Management ; Environmental Monitoring ; Evaporation ; Factor analysis ; Geochemistry ; Geographic Information Systems ; Geographical information systems ; Greece ; Heavy vehicles ; Human influences ; Information management ; Information systems ; Integrated approach ; Intensive farming ; Manganese ; Mercury ; Monitoring/Environmental Analysis ; Multivariate analysis ; Multivariate statistical analysis ; Organic matter ; Origins ; Population density ; Public health ; Quality of life ; Quaternary ; Rare earth elements ; Remote sensing ; Sediments ; Silver ; Soil ; Soil - chemistry ; Soil formation ; Soil Pollutants - analysis ; Soils ; Spatial distribution ; Statistical analysis ; Statistical methods ; Topsoil ; Ultramafic rocks ; Urban areas ; Urban environments</subject><ispartof>Environmental monitoring and assessment, 2024-11, Vol.196 (11), p.1052, Article 1052</ispartof><rights>The Author(s), under exclusive licence to Springer Nature Switzerland AG 2024. 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The Author(s), under exclusive licence to Springer Nature Switzerland AG.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c256t-4c1711fc78642d6c61168f0b1dfe3eec18309e96b2b3d2d562b69e4fcaea4b463</cites><orcidid>0000-0001-8078-3516 ; 0009-0008-1444-5189</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10661-024-13223-8$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10661-024-13223-8$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/39402277$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Papazotos, Panagiotis</creatorcontrib><creatorcontrib>Liakopoulos, Alexandros</creatorcontrib><creatorcontrib>Kontodimos, Konstantinos</creatorcontrib><creatorcontrib>Koukoulis, Athanasios</creatorcontrib><title>Integrated geochemical analysis of urban and peri-urban soils: a case study of Lamia City, Greece</title><title>Environmental monitoring and assessment</title><addtitle>Environ Monit Assess</addtitle><addtitle>Environ Monit Assess</addtitle><description>The occurrence of Potentially Toxic Elements (PTEs) and other chemical elements in urban and peri-urban soils impacts human health and quality of life, posing a challenge for geoscientists. This study investigated the soil geochemistry of Lamia City, focusing on identifying the geogenic and anthropogenic origins of elements. A total of 168 topsoil samples (0–10 cm) were collected in April 2023, and the analysis included the near-total concentrations of 51 elements. Descriptive, correlation, multivariate statistics (i.e., Factor Analysis-FA and Hierarchical Cluster Analysis-HCA), Geographic Information Systems (GIS) mapping, and mineralogical analysis were employed to identify potential element sources. The results indicated that the elements in soils originated from geogenic, anthropogenic, and mixed sources. Geogenic origins are associated with ultramafic rocks (e.g., Mg, Cr, Ni, Co, Fe, Sc, Mn), carbonate rocks (e.g., Ca, Sr), and Quaternary sediments (e.g., K, Na, Ba, Tl, Be, Rb, Ti, V, Ga, and Rare Earth Elements-REEs); associations are linked to specific identified minerals. All applied statistical analyses reveal that the mobility of chemical elements in the urban and peri-urban soils of Lamia city is primarily affected by geochemical processes such as element substitution, chemical weathering, pedogenesis, adsorption, precipitation, evaporation, and organic matter presence. The P, Ag, Hg, Pb, Sn, Zn, Sb, Cd, Cu, and U were associated with anthropogenic influences, particularly in areas with high population density, heavy vehicle traffic, and intensive agricultural practices. Additionally, some elements (e.g., Ca, Cd, Cu, Mo, Mn, and Li) exhibited mixed origins. This integrated approach offers valuable insights into the spatial distribution and sources of PTEs in urban and peri-urban environments, providing critical information for environmental management and public health protection strategies.</description><subject>Agricultural practices</subject><subject>Anthropogenic factors</subject><subject>Antimony</subject><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>Cadmium</subject><subject>Calcium</subject><subject>Carbonate rocks</subject><subject>Carbonates</subject><subject>Chemical elements</subject><subject>Chemical weathering</subject><subject>Cities</subject><subject>Cluster analysis</subject><subject>Copper</subject><subject>Earth and Environmental Science</subject><subject>Ecology</subject><subject>Ecotoxicology</subject><subject>Elements</subject><subject>Environment</subject><subject>Environmental Management</subject><subject>Environmental Monitoring</subject><subject>Evaporation</subject><subject>Factor analysis</subject><subject>Geochemistry</subject><subject>Geographic Information Systems</subject><subject>Geographical information systems</subject><subject>Greece</subject><subject>Heavy vehicles</subject><subject>Human influences</subject><subject>Information management</subject><subject>Information systems</subject><subject>Integrated approach</subject><subject>Intensive farming</subject><subject>Manganese</subject><subject>Mercury</subject><subject>Monitoring/Environmental Analysis</subject><subject>Multivariate analysis</subject><subject>Multivariate statistical analysis</subject><subject>Organic matter</subject><subject>Origins</subject><subject>Population density</subject><subject>Public health</subject><subject>Quality of life</subject><subject>Quaternary</subject><subject>Rare earth elements</subject><subject>Remote sensing</subject><subject>Sediments</subject><subject>Silver</subject><subject>Soil</subject><subject>Soil - chemistry</subject><subject>Soil formation</subject><subject>Soil Pollutants - analysis</subject><subject>Soils</subject><subject>Spatial distribution</subject><subject>Statistical analysis</subject><subject>Statistical methods</subject><subject>Topsoil</subject><subject>Ultramafic rocks</subject><subject>Urban areas</subject><subject>Urban environments</subject><issn>0167-6369</issn><issn>1573-2959</issn><issn>1573-2959</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNp9kblOxDAQhi0EguV4AQpkiYYCg6_YMR1acay0Eg3UluNMlqAci50U-_Z4CYdEQTXy-PM3Gv8InTJ6xSjV15FRpRihXBImOBck30EzlmlBuMnMLppRpjRRQpkDdBjjG6XUaGn20YEwknKu9Qy5RTfAKrgBSryC3r9CW3vXYNe5ZhPriPsKj6FwXeqUeA2hJtMx9nUTb7DD3kXAcRjLzZZdurZ2eF4Pm0v8EAA8HKO9yjURTr7qEXq5v3ueP5Ll08NifrsknmdqINIzzVjlda4kL5VXjKm8ogUrKxDJw3JBDRhV8EKUvMwUL5QBWXkHThZSiSN0MXnXoX8fIQ62raOHpnEd9GO0IgmV1jnPE3r-B33rx5A2niiZqZzKRPGJ8qGPMUBl16FuXdhYRu02ADsFYFMA9jMAu1WffanHooXy58n3jydATEBMV90Kwu_sf7QfF3WPvg</recordid><startdate>20241101</startdate><enddate>20241101</enddate><creator>Papazotos, Panagiotis</creator><creator>Liakopoulos, Alexandros</creator><creator>Kontodimos, Konstantinos</creator><creator>Koukoulis, Athanasios</creator><general>Springer International Publishing</general><general>Springer Nature B.V</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QH</scope><scope>7QL</scope><scope>7SN</scope><scope>7ST</scope><scope>7T7</scope><scope>7TG</scope><scope>7TN</scope><scope>7U7</scope><scope>7UA</scope><scope>8FD</scope><scope>C1K</scope><scope>F1W</scope><scope>FR3</scope><scope>H97</scope><scope>K9.</scope><scope>KL.</scope><scope>L.G</scope><scope>M7N</scope><scope>P64</scope><scope>SOI</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-8078-3516</orcidid><orcidid>https://orcid.org/0009-0008-1444-5189</orcidid></search><sort><creationdate>20241101</creationdate><title>Integrated geochemical analysis of urban and peri-urban soils: a case study of Lamia City, Greece</title><author>Papazotos, Panagiotis ; Liakopoulos, Alexandros ; Kontodimos, Konstantinos ; Koukoulis, Athanasios</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c256t-4c1711fc78642d6c61168f0b1dfe3eec18309e96b2b3d2d562b69e4fcaea4b463</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Agricultural practices</topic><topic>Anthropogenic factors</topic><topic>Antimony</topic><topic>Atmospheric Protection/Air Quality Control/Air Pollution</topic><topic>Cadmium</topic><topic>Calcium</topic><topic>Carbonate rocks</topic><topic>Carbonates</topic><topic>Chemical elements</topic><topic>Chemical weathering</topic><topic>Cities</topic><topic>Cluster analysis</topic><topic>Copper</topic><topic>Earth and Environmental Science</topic><topic>Ecology</topic><topic>Ecotoxicology</topic><topic>Elements</topic><topic>Environment</topic><topic>Environmental Management</topic><topic>Environmental Monitoring</topic><topic>Evaporation</topic><topic>Factor analysis</topic><topic>Geochemistry</topic><topic>Geographic Information Systems</topic><topic>Geographical information systems</topic><topic>Greece</topic><topic>Heavy vehicles</topic><topic>Human influences</topic><topic>Information management</topic><topic>Information systems</topic><topic>Integrated approach</topic><topic>Intensive farming</topic><topic>Manganese</topic><topic>Mercury</topic><topic>Monitoring/Environmental Analysis</topic><topic>Multivariate analysis</topic><topic>Multivariate statistical analysis</topic><topic>Organic matter</topic><topic>Origins</topic><topic>Population density</topic><topic>Public health</topic><topic>Quality of life</topic><topic>Quaternary</topic><topic>Rare earth elements</topic><topic>Remote sensing</topic><topic>Sediments</topic><topic>Silver</topic><topic>Soil</topic><topic>Soil - 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This study investigated the soil geochemistry of Lamia City, focusing on identifying the geogenic and anthropogenic origins of elements. A total of 168 topsoil samples (0–10 cm) were collected in April 2023, and the analysis included the near-total concentrations of 51 elements. Descriptive, correlation, multivariate statistics (i.e., Factor Analysis-FA and Hierarchical Cluster Analysis-HCA), Geographic Information Systems (GIS) mapping, and mineralogical analysis were employed to identify potential element sources. The results indicated that the elements in soils originated from geogenic, anthropogenic, and mixed sources. Geogenic origins are associated with ultramafic rocks (e.g., Mg, Cr, Ni, Co, Fe, Sc, Mn), carbonate rocks (e.g., Ca, Sr), and Quaternary sediments (e.g., K, Na, Ba, Tl, Be, Rb, Ti, V, Ga, and Rare Earth Elements-REEs); associations are linked to specific identified minerals. All applied statistical analyses reveal that the mobility of chemical elements in the urban and peri-urban soils of Lamia city is primarily affected by geochemical processes such as element substitution, chemical weathering, pedogenesis, adsorption, precipitation, evaporation, and organic matter presence. The P, Ag, Hg, Pb, Sn, Zn, Sb, Cd, Cu, and U were associated with anthropogenic influences, particularly in areas with high population density, heavy vehicle traffic, and intensive agricultural practices. Additionally, some elements (e.g., Ca, Cd, Cu, Mo, Mn, and Li) exhibited mixed origins. This integrated approach offers valuable insights into the spatial distribution and sources of PTEs in urban and peri-urban environments, providing critical information for environmental management and public health protection strategies.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><pmid>39402277</pmid><doi>10.1007/s10661-024-13223-8</doi><orcidid>https://orcid.org/0000-0001-8078-3516</orcidid><orcidid>https://orcid.org/0009-0008-1444-5189</orcidid></addata></record> |
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| subjects | Agricultural practices Anthropogenic factors Antimony Atmospheric Protection/Air Quality Control/Air Pollution Cadmium Calcium Carbonate rocks Carbonates Chemical elements Chemical weathering Cities Cluster analysis Copper Earth and Environmental Science Ecology Ecotoxicology Elements Environment Environmental Management Environmental Monitoring Evaporation Factor analysis Geochemistry Geographic Information Systems Geographical information systems Greece Heavy vehicles Human influences Information management Information systems Integrated approach Intensive farming Manganese Mercury Monitoring/Environmental Analysis Multivariate analysis Multivariate statistical analysis Organic matter Origins Population density Public health Quality of life Quaternary Rare earth elements Remote sensing Sediments Silver Soil Soil - chemistry Soil formation Soil Pollutants - analysis Soils Spatial distribution Statistical analysis Statistical methods Topsoil Ultramafic rocks Urban areas Urban environments |
| title | Integrated geochemical analysis of urban and peri-urban soils: a case study of Lamia City, Greece |
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