Catalytic asymmetric fragmentation of cyclopropanes

The stereoselective activation of alkanes constitutes a long-standing and grand challenge for chemistry. Although metal-containing enzymes oxidize alkanes with remarkable ease and selectivity, chemical approaches have largely been limited to transition metal-based catalytic carbon-hydrogen functiona...

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Veröffentlicht in:	Science (American Association for the Advancement of Science) 2024-10, Vol.386 (6718), p.225-230
Hauptverfasser:	Raut, Ravindra Krushnaji, Matsutani, Satoshi, Shi, Fuxing, Kataoka, Shuta, Poje, Margareta, Mitschke, Benjamin, Maeda, Satoshi, Tsuji, Nobuya, List, Benjamin
Format:	Artikel
Sprache:	eng
Schlagworte:	Binding sites Catalysts Cyclopropane Enantiomers Nitrogen atoms Organic compounds Ring opening
Online-Zugang:	Volltext
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