Second harmonic scattering reveals different orientational orders inside the hydrophobic cavity of hybrid nanotubes

Second Harmonic Scattering (SHS) is a suitable technique to investigate the orientational correlations between molecules. This article explores the organization of different dye molecules adsorbed within the hydrophobic porosity of a hybrid organic–inorganic nanotube. Experimental polarization resol...

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Veröffentlicht in:The Journal of chemical physics 2024-10, Vol.161 (13)
Hauptverfasser: Dhaini, Ali, Prelot, Bénédicte, Thill, Antoine, Martin-Gassin, Gaelle, Gassin, Pierre-Marie
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container_issue 13
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creator Dhaini, Ali
Prelot, Bénédicte
Thill, Antoine
Martin-Gassin, Gaelle
Gassin, Pierre-Marie
description Second Harmonic Scattering (SHS) is a suitable technique to investigate the orientational correlations between molecules. This article explores the organization of different dye molecules adsorbed within the hydrophobic porosity of a hybrid organic–inorganic nanotube. Experimental polarization resolved SHS measurements highlight different orientational orders ranking from highly ordered and rigid organizations to disordered assemblies. Microscopic models of assemblies inside the pores are presented and discussed in the context of orientational correlation between the dye molecules. This work shows that the degree of order in the nanotube cavity follows the molecule’s affinity within the porosity.
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title Second harmonic scattering reveals different orientational orders inside the hydrophobic cavity of hybrid nanotubes
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