Proton vs Electron: The Dual Role of Redox-Inactive Metal Ions in Permanganate Oxidation Kinetics

Redox-inactive metal-ion-driven modulation of the oxidation behavior of high-valent metal–oxo complex has garnered significant interest in biological and chemical synthesis; however, their role in permanganate (Mn(VII)) oxidation for the removal of organic pollutants has been largely neglected. Her...

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Veröffentlicht in:	Environmental science & technology 2024-10, Vol.58 (40), p.18041-18051
Hauptverfasser:	Luo, Mengfan, Zhang, Heng, Guo, Jianhua, Zhao, Jia, Feng, Can, Yin, Jialong, Xu, Chang, Du, Ye, Liu, Yang, He, Chuan-Shu, Lai, Bo
Format:	Artikel
Sprache:	eng
Schlagworte:	Acidic oxides Acidity Aluminum calcium Calcium ions Chemical synthesis Decontamination Direct reduction Electrochemistry Electron transfer Electrons energy environmental science Intermediates Ions Isotope effect isotopes Kinetics Lewis acids Magnesium Manganese Compounds - chemistry Metal ions Metals - chemistry Microenvironments Oxidation Oxidation-Reduction Oxides - chemistry oxygen Oxygen transfer Phenolic compounds Phenols Physico-Chemical Treatment and Resource Recovery Pollutant removal Pollutants Protons Reaction kinetics Substrates synthesis Thioanisole Water purification Zinc
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