Ligand effects on gas adsorption in nanoporous phthalocyanine crystals

X-ray diffraction is used to study the sorption of CO and NO in two phthalocyanine nanoporous crystals (PNCs) with 4,4' bipyridine or 4,4' bipyrimidine coordinated to open Co sites, demonstrating how the coordinated ligands influence the gas sorption properties and structures of the PNCs.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2024-10, Vol.60 (81), p.11508-11511
Hauptverfasser: Stamos, Nikolaos-Angelos, McMonagle, Charles J, Turner, Gemma F, Allan, David R, Warren, Mark R, Warren, Anna J, McKeown, Neil B, Moggach, Stephen A
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Sprache:eng
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Zusammenfassung:X-ray diffraction is used to study the sorption of CO and NO in two phthalocyanine nanoporous crystals (PNCs) with 4,4' bipyridine or 4,4' bipyrimidine coordinated to open Co sites, demonstrating how the coordinated ligands influence the gas sorption properties and structures of the PNCs.
ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/d4cc03896g