An unexpected imidazole-induced porphyrinylphosphonate-based MOF-to-HOF structural transformation leading to the enhancement of proton conductivity

Post-synthetic modification of proton-conducting metal-organic frameworks (MOFs) by loading small molecules capable of generating protons into pores is an efficient approach for developing a new type of material with improved ionic conductivity. Herein, the synthesis, characterization and proton con...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2024-10, Vol.53 (39), p.16345-16354
Hauptverfasser:	Zhigileva, Ekaterina A, Enakieva, Yulia Yu, Chernyshev, Vladimir V, Senchikhin, Ivan N, Demina, Liudmila I, Martynov, Alexander G, Stenina, Irina A, Yaroslavtsev, Andrey B, Gorbunova, Yulia G, Tsivadze, Aslan Yu
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical synthesis Hydrogen bonding Imidazole Ion currents Metal-organic frameworks Palladium Porphyrins Protons Relative humidity
Online-Zugang:	Volltext
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