Effect of the Polyanion Structure on the Mechanism of Alcohol Oxidation with H2O2 Catalyzed by Zr-Substituted Polyoxotungstates

Zr-monosubstituted polyoxometalates (Zr-POMs) of the Lindqvist (Bu4N)6[{W5O18Zr­(μ-OH)}2] (1), Keggin (Bu4N)8[{PW11O39Zr­(μ-OH)}2] (2), and Wells–Dawson (Bu4N)11.3K2.5H0.2[{P2W17O61Zr}2(μ-OH)2] (3) structures catalyze oxidation of alcohols using aqueous hydrogen peroxide as an oxidant. With 1 equiv...

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Veröffentlicht in:	Inorganic chemistry 2024-09, Vol.63 (39), p.18043-18057
Hauptverfasser:	Maksimchuk, Nataliya V., Marikovskaya, Sofia M., Larionov, Kirill P., Evtushok, Vasilii Yu, Yanshole, Vadim V., Antonov, Artem A., Kholdeeva, Oxana A.
Format:	Artikel
Sprache:	eng
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