Metal ion-driven formation of 2H-silolides and -germolides
The synthesis of potassio-1H-silolides and -germolides substituted with an amidinate-stabilized silylene is reported. Both anions undergo a thermal rearrangement to the 2H-isomer yielding cyclic sila- and germavinyl anions. The reaction is driven by complex formation with metal ions.
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2024-10, Vol.60 (80), p.11295-11298 |
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| container_end_page | 11298 |
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| container_issue | 80 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Liu, Chenghuan Schmidtmann, Marc Müller, Thomas |
| description | The synthesis of potassio-1H-silolides and -germolides substituted with an amidinate-stabilized silylene is reported. Both anions undergo a thermal rearrangement to the 2H-isomer yielding cyclic sila- and germavinyl anions. The reaction is driven by complex formation with metal ions. |
| doi_str_mv | 10.1039/d4cc03984j |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2024-10, Vol.60 (80), p.11295-11298 |
| issn | 1359-7345 1364-548X 1364-548X |
| language | eng |
| recordid | cdi_proquest_miscellaneous_3106463618 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Anions Complex formation |
| title | Metal ion-driven formation of 2H-silolides and -germolides |
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