Agricultural waste–based biochars for sustainable removal of heavy metals from stabilized landfill leachate
In this work, biochars were used as adsorbents to remove Cu, Cd, and Zn ions in a real stabilized leachate from a controlled landfill. Oak fruit shells biochar (OFSBC) and date palm fibers biochar (DPFBC) were obtained by pyrolysis of oak fruit shells and date palm fibers at 700 °C and 400 °C, respe...
Gespeichert in:
| Veröffentlicht in: | Environmental science and pollution research international 2024-10, Vol.31 (47), p.57733-57747 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 57747 |
|---|---|
| container_issue | 47 |
| container_start_page | 57733 |
| container_title | Environmental science and pollution research international |
| container_volume | 31 |
| creator | Soudani, Amina Youcef, Leila Chebbi, Meriem Bulgariu, Laura Patel, Nageshvar |
| description | In this work, biochars were used as adsorbents to remove Cu, Cd, and Zn ions in a real stabilized leachate from a controlled landfill. Oak fruit shells biochar (OFSBC) and date palm fibers biochar (DPFBC) were obtained by pyrolysis of oak fruit shells and date palm fibers at 700 °C and 400 °C, respectively. OFSBC and DPFBC showed well-developed structures and high specific surface areas (520.16 m
2
/g and 470.46 m
2
/g, respectively). Equilibrium adsorption of heavy metal ions on DPFBC and OFSBC occurred after 4 h and 2 h of stirring. The removal efficiencies of Cu, Cd, and Zn ions were 97.01%, 94.40%, and 80.59% with DPFBC and 90.10%, 88.33%, and 76.16% using OFSBC, respectively. The Avrami fractional order model was appropriate for describing kinetic adsorption. Increasing the dose of adsorbent improves heavy metal ion retention. Thermodynamic tests have proven the spontaneous and endothermic adsorption of these heavy metals. The electrostatic attraction, ion exchange, complexation, metal-π bending, and surface precipitation and pore filling were regarded as the most predominant heavy metal retention mechanisms from the landfill leachate onto the biochar surface. Separately, the DPFBC showed the best performance than OFSBC regarding the improvement of leachate quality. Chemical oxygen demand (COD), biological oxygen demand (BOD
5
), ammoniacal nitrogen (NH
3
-N), and phosphorus (P) were respectively removed at an efficiency of 53.57%, 29.17%, 36.07%, and 37.5%, respectively. Thus, the results allow highlighting that the adsorption on DPFBC and OFSBC can be an effective alternative in the practice of landfill leachate treatment. |
| doi_str_mv | 10.1007/s11356-024-34946-8 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_3106460054</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3106460054</sourcerecordid><originalsourceid>FETCH-LOGICAL-c1718-ee77e187aaabad2444ec904a8db9b22934f34358dd472ed74be82ddafce06453</originalsourceid><addsrcrecordid>eNp90ctO3DAUBmALFTHcXoBFZakbNim-JY6XCBWoNFI37K3j-ASCnPHUTqjoqu_QN-RJcJmhVF2wsiV__n3kn5ATzj5zxvRZ5lzWTcWEqqQyqqnaHbLPG64qrYz58M9-QQ5yvmdMMCP0HllII1ojmnqfjOe3aejmMM0JAv0BecKnX78dZPTUDbG7g5RpHxPNc55gWIELSBOO8aHw2NM7hIdHOuIEobgUR1qYG8LwswQEWPl-CIEGhJI04RHZ7QvE4-16SG4uv9xcXFfLb1dfL86XVcc1bytErZG3GgAceKGUws4wBa13xglhpOqlknXrvdICvVYOW-E99B2yRtXykJxuYtcpfp8xT3YccoehzINxzlbywhrGalXop__ofZzTqgxXFK-FYrqRRYmN6lLMOWFv12kYIT1azuyfLuymC1u6sC9d2LZc-riNnt2I_u-V188vQG5ALkerW0xvb78T-wx48JdM</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3115240763</pqid></control><display><type>article</type><title>Agricultural waste–based biochars for sustainable removal of heavy metals from stabilized landfill leachate</title><source>SpringerNature Journals</source><creator>Soudani, Amina ; Youcef, Leila ; Chebbi, Meriem ; Bulgariu, Laura ; Patel, Nageshvar</creator><creatorcontrib>Soudani, Amina ; Youcef, Leila ; Chebbi, Meriem ; Bulgariu, Laura ; Patel, Nageshvar</creatorcontrib><description>In this work, biochars were used as adsorbents to remove Cu, Cd, and Zn ions in a real stabilized leachate from a controlled landfill. Oak fruit shells biochar (OFSBC) and date palm fibers biochar (DPFBC) were obtained by pyrolysis of oak fruit shells and date palm fibers at 700 °C and 400 °C, respectively. OFSBC and DPFBC showed well-developed structures and high specific surface areas (520.16 m
2
/g and 470.46 m
2
/g, respectively). Equilibrium adsorption of heavy metal ions on DPFBC and OFSBC occurred after 4 h and 2 h of stirring. The removal efficiencies of Cu, Cd, and Zn ions were 97.01%, 94.40%, and 80.59% with DPFBC and 90.10%, 88.33%, and 76.16% using OFSBC, respectively. The Avrami fractional order model was appropriate for describing kinetic adsorption. Increasing the dose of adsorbent improves heavy metal ion retention. Thermodynamic tests have proven the spontaneous and endothermic adsorption of these heavy metals. The electrostatic attraction, ion exchange, complexation, metal-π bending, and surface precipitation and pore filling were regarded as the most predominant heavy metal retention mechanisms from the landfill leachate onto the biochar surface. Separately, the DPFBC showed the best performance than OFSBC regarding the improvement of leachate quality. Chemical oxygen demand (COD), biological oxygen demand (BOD
5
), ammoniacal nitrogen (NH
3
-N), and phosphorus (P) were respectively removed at an efficiency of 53.57%, 29.17%, 36.07%, and 37.5%, respectively. Thus, the results allow highlighting that the adsorption on DPFBC and OFSBC can be an effective alternative in the practice of landfill leachate treatment.</description><identifier>ISSN: 1614-7499</identifier><identifier>ISSN: 0944-1344</identifier><identifier>EISSN: 1614-7499</identifier><identifier>DOI: 10.1007/s11356-024-34946-8</identifier><identifier>PMID: 39289265</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Adsorbents ; Adsorption ; Agricultural wastes ; Ammonia ; Aquatic Pollution ; Atmospheric Protection/Air Quality Control/Air Pollution ; Biochemical oxygen demand ; Cadmium ; Charcoal ; Chemical oxygen demand ; Copper ; Earth and Environmental Science ; Ecotoxicology ; Environment ; Environmental Chemistry ; Environmental Health ; Fibers ; Fruits ; Heavy metals ; Ion exchange ; Landfill ; Landfills ; Leachates ; Metal ions ; Pyrolysis ; Research Article ; Retention ; Shells ; Waste disposal sites ; Waste Water Technology ; Wastewater treatment ; Water Management ; Water Pollution Control ; Water pollution treatment ; Zinc</subject><ispartof>Environmental science and pollution research international, 2024-10, Vol.31 (47), p.57733-57747</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><rights>2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c1718-ee77e187aaabad2444ec904a8db9b22934f34358dd472ed74be82ddafce06453</cites><orcidid>0000-0003-0526-7129</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11356-024-34946-8$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11356-024-34946-8$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/39289265$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Soudani, Amina</creatorcontrib><creatorcontrib>Youcef, Leila</creatorcontrib><creatorcontrib>Chebbi, Meriem</creatorcontrib><creatorcontrib>Bulgariu, Laura</creatorcontrib><creatorcontrib>Patel, Nageshvar</creatorcontrib><title>Agricultural waste–based biochars for sustainable removal of heavy metals from stabilized landfill leachate</title><title>Environmental science and pollution research international</title><addtitle>Environ Sci Pollut Res</addtitle><addtitle>Environ Sci Pollut Res Int</addtitle><description>In this work, biochars were used as adsorbents to remove Cu, Cd, and Zn ions in a real stabilized leachate from a controlled landfill. Oak fruit shells biochar (OFSBC) and date palm fibers biochar (DPFBC) were obtained by pyrolysis of oak fruit shells and date palm fibers at 700 °C and 400 °C, respectively. OFSBC and DPFBC showed well-developed structures and high specific surface areas (520.16 m
2
/g and 470.46 m
2
/g, respectively). Equilibrium adsorption of heavy metal ions on DPFBC and OFSBC occurred after 4 h and 2 h of stirring. The removal efficiencies of Cu, Cd, and Zn ions were 97.01%, 94.40%, and 80.59% with DPFBC and 90.10%, 88.33%, and 76.16% using OFSBC, respectively. The Avrami fractional order model was appropriate for describing kinetic adsorption. Increasing the dose of adsorbent improves heavy metal ion retention. Thermodynamic tests have proven the spontaneous and endothermic adsorption of these heavy metals. The electrostatic attraction, ion exchange, complexation, metal-π bending, and surface precipitation and pore filling were regarded as the most predominant heavy metal retention mechanisms from the landfill leachate onto the biochar surface. Separately, the DPFBC showed the best performance than OFSBC regarding the improvement of leachate quality. Chemical oxygen demand (COD), biological oxygen demand (BOD
5
), ammoniacal nitrogen (NH
3
-N), and phosphorus (P) were respectively removed at an efficiency of 53.57%, 29.17%, 36.07%, and 37.5%, respectively. Thus, the results allow highlighting that the adsorption on DPFBC and OFSBC can be an effective alternative in the practice of landfill leachate treatment.</description><subject>Adsorbents</subject><subject>Adsorption</subject><subject>Agricultural wastes</subject><subject>Ammonia</subject><subject>Aquatic Pollution</subject><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>Biochemical oxygen demand</subject><subject>Cadmium</subject><subject>Charcoal</subject><subject>Chemical oxygen demand</subject><subject>Copper</subject><subject>Earth and Environmental Science</subject><subject>Ecotoxicology</subject><subject>Environment</subject><subject>Environmental Chemistry</subject><subject>Environmental Health</subject><subject>Fibers</subject><subject>Fruits</subject><subject>Heavy metals</subject><subject>Ion exchange</subject><subject>Landfill</subject><subject>Landfills</subject><subject>Leachates</subject><subject>Metal ions</subject><subject>Pyrolysis</subject><subject>Research Article</subject><subject>Retention</subject><subject>Shells</subject><subject>Waste disposal sites</subject><subject>Waste Water Technology</subject><subject>Wastewater treatment</subject><subject>Water Management</subject><subject>Water Pollution Control</subject><subject>Water pollution treatment</subject><subject>Zinc</subject><issn>1614-7499</issn><issn>0944-1344</issn><issn>1614-7499</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp90ctO3DAUBmALFTHcXoBFZakbNim-JY6XCBWoNFI37K3j-ASCnPHUTqjoqu_QN-RJcJmhVF2wsiV__n3kn5ATzj5zxvRZ5lzWTcWEqqQyqqnaHbLPG64qrYz58M9-QQ5yvmdMMCP0HllII1ojmnqfjOe3aejmMM0JAv0BecKnX78dZPTUDbG7g5RpHxPNc55gWIELSBOO8aHw2NM7hIdHOuIEobgUR1qYG8LwswQEWPl-CIEGhJI04RHZ7QvE4-16SG4uv9xcXFfLb1dfL86XVcc1bytErZG3GgAceKGUws4wBa13xglhpOqlknXrvdICvVYOW-E99B2yRtXykJxuYtcpfp8xT3YccoehzINxzlbywhrGalXop__ofZzTqgxXFK-FYrqRRYmN6lLMOWFv12kYIT1azuyfLuymC1u6sC9d2LZc-riNnt2I_u-V188vQG5ALkerW0xvb78T-wx48JdM</recordid><startdate>20241001</startdate><enddate>20241001</enddate><creator>Soudani, Amina</creator><creator>Youcef, Leila</creator><creator>Chebbi, Meriem</creator><creator>Bulgariu, Laura</creator><creator>Patel, Nageshvar</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QL</scope><scope>7SN</scope><scope>7T7</scope><scope>7TV</scope><scope>7U7</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>K9.</scope><scope>M7N</scope><scope>P64</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-0526-7129</orcidid></search><sort><creationdate>20241001</creationdate><title>Agricultural waste–based biochars for sustainable removal of heavy metals from stabilized landfill leachate</title><author>Soudani, Amina ; Youcef, Leila ; Chebbi, Meriem ; Bulgariu, Laura ; Patel, Nageshvar</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1718-ee77e187aaabad2444ec904a8db9b22934f34358dd472ed74be82ddafce06453</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Adsorbents</topic><topic>Adsorption</topic><topic>Agricultural wastes</topic><topic>Ammonia</topic><topic>Aquatic Pollution</topic><topic>Atmospheric Protection/Air Quality Control/Air Pollution</topic><topic>Biochemical oxygen demand</topic><topic>Cadmium</topic><topic>Charcoal</topic><topic>Chemical oxygen demand</topic><topic>Copper</topic><topic>Earth and Environmental Science</topic><topic>Ecotoxicology</topic><topic>Environment</topic><topic>Environmental Chemistry</topic><topic>Environmental Health</topic><topic>Fibers</topic><topic>Fruits</topic><topic>Heavy metals</topic><topic>Ion exchange</topic><topic>Landfill</topic><topic>Landfills</topic><topic>Leachates</topic><topic>Metal ions</topic><topic>Pyrolysis</topic><topic>Research Article</topic><topic>Retention</topic><topic>Shells</topic><topic>Waste disposal sites</topic><topic>Waste Water Technology</topic><topic>Wastewater treatment</topic><topic>Water Management</topic><topic>Water Pollution Control</topic><topic>Water pollution treatment</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Soudani, Amina</creatorcontrib><creatorcontrib>Youcef, Leila</creatorcontrib><creatorcontrib>Chebbi, Meriem</creatorcontrib><creatorcontrib>Bulgariu, Laura</creatorcontrib><creatorcontrib>Patel, Nageshvar</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Bacteriology Abstracts (Microbiology B)</collection><collection>Ecology Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Pollution Abstracts</collection><collection>Toxicology Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>Algology Mycology and Protozoology Abstracts (Microbiology C)</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>MEDLINE - Academic</collection><jtitle>Environmental science and pollution research international</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Soudani, Amina</au><au>Youcef, Leila</au><au>Chebbi, Meriem</au><au>Bulgariu, Laura</au><au>Patel, Nageshvar</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Agricultural waste–based biochars for sustainable removal of heavy metals from stabilized landfill leachate</atitle><jtitle>Environmental science and pollution research international</jtitle><stitle>Environ Sci Pollut Res</stitle><addtitle>Environ Sci Pollut Res Int</addtitle><date>2024-10-01</date><risdate>2024</risdate><volume>31</volume><issue>47</issue><spage>57733</spage><epage>57747</epage><pages>57733-57747</pages><issn>1614-7499</issn><issn>0944-1344</issn><eissn>1614-7499</eissn><abstract>In this work, biochars were used as adsorbents to remove Cu, Cd, and Zn ions in a real stabilized leachate from a controlled landfill. Oak fruit shells biochar (OFSBC) and date palm fibers biochar (DPFBC) were obtained by pyrolysis of oak fruit shells and date palm fibers at 700 °C and 400 °C, respectively. OFSBC and DPFBC showed well-developed structures and high specific surface areas (520.16 m
2
/g and 470.46 m
2
/g, respectively). Equilibrium adsorption of heavy metal ions on DPFBC and OFSBC occurred after 4 h and 2 h of stirring. The removal efficiencies of Cu, Cd, and Zn ions were 97.01%, 94.40%, and 80.59% with DPFBC and 90.10%, 88.33%, and 76.16% using OFSBC, respectively. The Avrami fractional order model was appropriate for describing kinetic adsorption. Increasing the dose of adsorbent improves heavy metal ion retention. Thermodynamic tests have proven the spontaneous and endothermic adsorption of these heavy metals. The electrostatic attraction, ion exchange, complexation, metal-π bending, and surface precipitation and pore filling were regarded as the most predominant heavy metal retention mechanisms from the landfill leachate onto the biochar surface. Separately, the DPFBC showed the best performance than OFSBC regarding the improvement of leachate quality. Chemical oxygen demand (COD), biological oxygen demand (BOD
5
), ammoniacal nitrogen (NH
3
-N), and phosphorus (P) were respectively removed at an efficiency of 53.57%, 29.17%, 36.07%, and 37.5%, respectively. Thus, the results allow highlighting that the adsorption on DPFBC and OFSBC can be an effective alternative in the practice of landfill leachate treatment.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><pmid>39289265</pmid><doi>10.1007/s11356-024-34946-8</doi><tpages>15</tpages><orcidid>https://orcid.org/0000-0003-0526-7129</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1614-7499 |
| ispartof | Environmental science and pollution research international, 2024-10, Vol.31 (47), p.57733-57747 |
| issn | 1614-7499 0944-1344 1614-7499 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_3106460054 |
| source | SpringerNature Journals |
| subjects | Adsorbents Adsorption Agricultural wastes Ammonia Aquatic Pollution Atmospheric Protection/Air Quality Control/Air Pollution Biochemical oxygen demand Cadmium Charcoal Chemical oxygen demand Copper Earth and Environmental Science Ecotoxicology Environment Environmental Chemistry Environmental Health Fibers Fruits Heavy metals Ion exchange Landfill Landfills Leachates Metal ions Pyrolysis Research Article Retention Shells Waste disposal sites Waste Water Technology Wastewater treatment Water Management Water Pollution Control Water pollution treatment Zinc |
| title | Agricultural waste–based biochars for sustainable removal of heavy metals from stabilized landfill leachate |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-22T23%3A17%3A14IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Agricultural%20waste%E2%80%93based%20biochars%20for%20sustainable%20removal%20of%20heavy%20metals%20from%20stabilized%20landfill%20leachate&rft.jtitle=Environmental%20science%20and%20pollution%20research%20international&rft.au=Soudani,%20Amina&rft.date=2024-10-01&rft.volume=31&rft.issue=47&rft.spage=57733&rft.epage=57747&rft.pages=57733-57747&rft.issn=1614-7499&rft.eissn=1614-7499&rft_id=info:doi/10.1007/s11356-024-34946-8&rft_dat=%3Cproquest_cross%3E3106460054%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=3115240763&rft_id=info:pmid/39289265&rfr_iscdi=true |