Production of pyrite-based catalysts supported on graphene oxide and zinc oxide to treat drug mixture via advanced oxidation processes
Advanced oxidation processes (AOP) stood out as an efficient alternative for the treatment of organic contaminants. In this work, there were proposed syntheses of mixed catalysts of pyrite and graphene oxide and pyrite and zinc oxide to treat a mixture of the drugs atenolol and propranolol in aqueou...
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| Veröffentlicht in: | Environmental science and pollution research international 2024-09, Vol.31 (44), p.55958-55973 |
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| creator | de Oliveira Marques Cavalcanti, Vanessa Napoleão, Daniella Carla Santana, Ingrid Larissa da Silva Santana, Rayany Magali da Rocha Lucena, Alex Leandro Andrade de da Motta Sobrinho, Maurício Alves |
| description | Advanced oxidation processes (AOP) stood out as an efficient alternative for the treatment of organic contaminants. In this work, there were proposed syntheses of mixed catalysts of pyrite and graphene oxide and pyrite and zinc oxide to treat a mixture of the drugs atenolol and propranolol in aqueous solution through the photo-Fenton process with ultraviolet radiation. The efficiency of the methodologies used in the syntheses was confirmed through different characterization analyses. It was verified that the pyrite and zinc oxide catalyst led to the best contaminant degradation percentages with values equal to 88 and 84% for the groups monitored at the wavelengths (
λ
) of 217 and 281 nm. The degradation kinetics presented a good fit to the kinetic model proposed by Chan and Chu (2003) with
R
2
equal to 0.99, indicating a pseudo-first-order degradation profile. Finally, toxicity tests were carried out with two types of seeds, watercress and cabbage, for the solution before and after treatment. The cabbage seeds showed a reduction in germination percentages for the samples after treatments, while no toxicity was observed for watercress ones. This highlights the importance of evaluating the implications caused by products in relation to different organisms representing the biota. |
| doi_str_mv | 10.1007/s11356-024-34931-1 |
| format | Article |
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λ
) of 217 and 281 nm. The degradation kinetics presented a good fit to the kinetic model proposed by Chan and Chu (2003) with
R
2
equal to 0.99, indicating a pseudo-first-order degradation profile. Finally, toxicity tests were carried out with two types of seeds, watercress and cabbage, for the solution before and after treatment. The cabbage seeds showed a reduction in germination percentages for the samples after treatments, while no toxicity was observed for watercress ones. This highlights the importance of evaluating the implications caused by products in relation to different organisms representing the biota.</description><identifier>ISSN: 1614-7499</identifier><identifier>ISSN: 0944-1344</identifier><identifier>EISSN: 1614-7499</identifier><identifier>DOI: 10.1007/s11356-024-34931-1</identifier><identifier>PMID: 39251534</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Aquatic Pollution ; Aqueous solutions ; Atenolol ; Atmospheric Protection/Air Quality Control/Air Pollution ; Biota ; Brassica oleracea ; cabbage ; Catalysts ; Contaminants ; Degradation ; drugs ; Earth and Environmental Science ; Ecotoxicology ; Environment ; Environmental Chemistry ; Environmental Health ; Germination ; Graphene ; graphene oxide ; kinetics ; Mixtures ; Organic contaminants ; Oxidation ; Propranolol ; Pyrite ; Research Article ; Rorippa nasturtium-aquaticum ; Seeds ; Toxicity ; Toxicity testing ; Ultraviolet radiation ; Waste Water Technology ; Water Management ; Water Pollution Control ; Watercress ; Wavelengths ; Zinc oxide ; Zinc oxides</subject><ispartof>Environmental science and pollution research international, 2024-09, Vol.31 (44), p.55958-55973</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><rights>2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c2041-4f22fc72001cdf98ae133c3d49273c95c6099157567fce648042977aaa621ec13</cites><orcidid>0000-0002-2760-562X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11356-024-34931-1$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11356-024-34931-1$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,777,781,27905,27906,41469,42538,51300</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/39251534$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>de Oliveira Marques Cavalcanti, Vanessa</creatorcontrib><creatorcontrib>Napoleão, Daniella Carla</creatorcontrib><creatorcontrib>Santana, Ingrid Larissa da Silva</creatorcontrib><creatorcontrib>Santana, Rayany Magali da Rocha</creatorcontrib><creatorcontrib>Lucena, Alex Leandro Andrade de</creatorcontrib><creatorcontrib>da Motta Sobrinho, Maurício Alves</creatorcontrib><title>Production of pyrite-based catalysts supported on graphene oxide and zinc oxide to treat drug mixture via advanced oxidation processes</title><title>Environmental science and pollution research international</title><addtitle>Environ Sci Pollut Res</addtitle><addtitle>Environ Sci Pollut Res Int</addtitle><description>Advanced oxidation processes (AOP) stood out as an efficient alternative for the treatment of organic contaminants. In this work, there were proposed syntheses of mixed catalysts of pyrite and graphene oxide and pyrite and zinc oxide to treat a mixture of the drugs atenolol and propranolol in aqueous solution through the photo-Fenton process with ultraviolet radiation. The efficiency of the methodologies used in the syntheses was confirmed through different characterization analyses. It was verified that the pyrite and zinc oxide catalyst led to the best contaminant degradation percentages with values equal to 88 and 84% for the groups monitored at the wavelengths (
λ
) of 217 and 281 nm. The degradation kinetics presented a good fit to the kinetic model proposed by Chan and Chu (2003) with
R
2
equal to 0.99, indicating a pseudo-first-order degradation profile. Finally, toxicity tests were carried out with two types of seeds, watercress and cabbage, for the solution before and after treatment. The cabbage seeds showed a reduction in germination percentages for the samples after treatments, while no toxicity was observed for watercress ones. This highlights the importance of evaluating the implications caused by products in relation to different organisms representing the biota.</description><subject>Aquatic Pollution</subject><subject>Aqueous solutions</subject><subject>Atenolol</subject><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>Biota</subject><subject>Brassica oleracea</subject><subject>cabbage</subject><subject>Catalysts</subject><subject>Contaminants</subject><subject>Degradation</subject><subject>drugs</subject><subject>Earth and Environmental Science</subject><subject>Ecotoxicology</subject><subject>Environment</subject><subject>Environmental Chemistry</subject><subject>Environmental Health</subject><subject>Germination</subject><subject>Graphene</subject><subject>graphene oxide</subject><subject>kinetics</subject><subject>Mixtures</subject><subject>Organic contaminants</subject><subject>Oxidation</subject><subject>Propranolol</subject><subject>Pyrite</subject><subject>Research Article</subject><subject>Rorippa nasturtium-aquaticum</subject><subject>Seeds</subject><subject>Toxicity</subject><subject>Toxicity testing</subject><subject>Ultraviolet radiation</subject><subject>Waste Water Technology</subject><subject>Water Management</subject><subject>Water Pollution Control</subject><subject>Watercress</subject><subject>Wavelengths</subject><subject>Zinc oxide</subject><subject>Zinc oxides</subject><issn>1614-7499</issn><issn>0944-1344</issn><issn>1614-7499</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNqNkctuFDEQRS0EIiHwAyyQJTZsGly2u91eoig8pEiwgLVVsauHjmbaje2OMnwA3407MzzEArHy69S9rrqMPQXxEoQwrzKAartGSN0obRU0cI-dQge6Mdra-3_sT9ijnK-FkMJK85CdKCtbaJU-Zd8_phgWX8Y48TjweZ_GQs0VZgrcY8HtPpfM8zLPMZV6V7FNwvkLTcTj7RiI4xT4t3Hyx2OJvCTCwkNaNnw33pYlEb8ZkWO4wcmvGhXEO8c5RU85U37MHgy4zfTkuJ6xz28uPp2_ay4_vH1__vqy8VJoaPQg5eCNFAJ8GGyPBEp5FXRtS3nb-k5YC61pOzN46nQvtLTGIGIngTyoM_bioFudvy6Ui9uN2dN2ixPFJTtVp2K6WtT-B1oHbwT0fUWf_4VexyVNtZGV6rWWpl8F5YHyKeacaHBzGneY9g6EWwN1h0Bd1XV3gbr1w8-O0svVjsKvkp8JVkAdgFyfpg2l397_kP0BEqOsBg</recordid><startdate>20240901</startdate><enddate>20240901</enddate><creator>de Oliveira Marques Cavalcanti, Vanessa</creator><creator>Napoleão, Daniella Carla</creator><creator>Santana, Ingrid Larissa da Silva</creator><creator>Santana, Rayany Magali da Rocha</creator><creator>Lucena, Alex Leandro Andrade de</creator><creator>da Motta Sobrinho, Maurício Alves</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QL</scope><scope>7SN</scope><scope>7T7</scope><scope>7TV</scope><scope>7U7</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>K9.</scope><scope>M7N</scope><scope>P64</scope><scope>7X8</scope><scope>7S9</scope><scope>L.6</scope><orcidid>https://orcid.org/0000-0002-2760-562X</orcidid></search><sort><creationdate>20240901</creationdate><title>Production of pyrite-based catalysts supported on graphene oxide and zinc oxide to treat drug mixture via advanced oxidation processes</title><author>de Oliveira Marques Cavalcanti, Vanessa ; Napoleão, Daniella Carla ; Santana, Ingrid Larissa da Silva ; Santana, Rayany Magali da Rocha ; Lucena, Alex Leandro Andrade de ; da Motta Sobrinho, Maurício Alves</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2041-4f22fc72001cdf98ae133c3d49273c95c6099157567fce648042977aaa621ec13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Aquatic Pollution</topic><topic>Aqueous solutions</topic><topic>Atenolol</topic><topic>Atmospheric Protection/Air Quality Control/Air Pollution</topic><topic>Biota</topic><topic>Brassica oleracea</topic><topic>cabbage</topic><topic>Catalysts</topic><topic>Contaminants</topic><topic>Degradation</topic><topic>drugs</topic><topic>Earth and Environmental Science</topic><topic>Ecotoxicology</topic><topic>Environment</topic><topic>Environmental Chemistry</topic><topic>Environmental Health</topic><topic>Germination</topic><topic>Graphene</topic><topic>graphene oxide</topic><topic>kinetics</topic><topic>Mixtures</topic><topic>Organic contaminants</topic><topic>Oxidation</topic><topic>Propranolol</topic><topic>Pyrite</topic><topic>Research Article</topic><topic>Rorippa nasturtium-aquaticum</topic><topic>Seeds</topic><topic>Toxicity</topic><topic>Toxicity testing</topic><topic>Ultraviolet radiation</topic><topic>Waste Water Technology</topic><topic>Water Management</topic><topic>Water Pollution Control</topic><topic>Watercress</topic><topic>Wavelengths</topic><topic>Zinc oxide</topic><topic>Zinc oxides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>de Oliveira Marques Cavalcanti, Vanessa</creatorcontrib><creatorcontrib>Napoleão, Daniella Carla</creatorcontrib><creatorcontrib>Santana, Ingrid Larissa da Silva</creatorcontrib><creatorcontrib>Santana, Rayany Magali da Rocha</creatorcontrib><creatorcontrib>Lucena, Alex Leandro Andrade de</creatorcontrib><creatorcontrib>da Motta Sobrinho, Maurício Alves</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Bacteriology Abstracts (Microbiology B)</collection><collection>Ecology Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Pollution Abstracts</collection><collection>Toxicology Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>Algology Mycology and Protozoology Abstracts (Microbiology C)</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>MEDLINE - Academic</collection><collection>AGRICOLA</collection><collection>AGRICOLA - Academic</collection><jtitle>Environmental science and pollution research international</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>de Oliveira Marques Cavalcanti, Vanessa</au><au>Napoleão, Daniella Carla</au><au>Santana, Ingrid Larissa da Silva</au><au>Santana, Rayany Magali da Rocha</au><au>Lucena, Alex Leandro Andrade de</au><au>da Motta Sobrinho, Maurício Alves</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Production of pyrite-based catalysts supported on graphene oxide and zinc oxide to treat drug mixture via advanced oxidation processes</atitle><jtitle>Environmental science and pollution research international</jtitle><stitle>Environ Sci Pollut Res</stitle><addtitle>Environ Sci Pollut Res Int</addtitle><date>2024-09-01</date><risdate>2024</risdate><volume>31</volume><issue>44</issue><spage>55958</spage><epage>55973</epage><pages>55958-55973</pages><issn>1614-7499</issn><issn>0944-1344</issn><eissn>1614-7499</eissn><abstract>Advanced oxidation processes (AOP) stood out as an efficient alternative for the treatment of organic contaminants. In this work, there were proposed syntheses of mixed catalysts of pyrite and graphene oxide and pyrite and zinc oxide to treat a mixture of the drugs atenolol and propranolol in aqueous solution through the photo-Fenton process with ultraviolet radiation. The efficiency of the methodologies used in the syntheses was confirmed through different characterization analyses. It was verified that the pyrite and zinc oxide catalyst led to the best contaminant degradation percentages with values equal to 88 and 84% for the groups monitored at the wavelengths (
λ
) of 217 and 281 nm. The degradation kinetics presented a good fit to the kinetic model proposed by Chan and Chu (2003) with
R
2
equal to 0.99, indicating a pseudo-first-order degradation profile. Finally, toxicity tests were carried out with two types of seeds, watercress and cabbage, for the solution before and after treatment. The cabbage seeds showed a reduction in germination percentages for the samples after treatments, while no toxicity was observed for watercress ones. This highlights the importance of evaluating the implications caused by products in relation to different organisms representing the biota.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><pmid>39251534</pmid><doi>10.1007/s11356-024-34931-1</doi><tpages>16</tpages><orcidid>https://orcid.org/0000-0002-2760-562X</orcidid></addata></record> |
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| ispartof | Environmental science and pollution research international, 2024-09, Vol.31 (44), p.55958-55973 |
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| subjects | Aquatic Pollution Aqueous solutions Atenolol Atmospheric Protection/Air Quality Control/Air Pollution Biota Brassica oleracea cabbage Catalysts Contaminants Degradation drugs Earth and Environmental Science Ecotoxicology Environment Environmental Chemistry Environmental Health Germination Graphene graphene oxide kinetics Mixtures Organic contaminants Oxidation Propranolol Pyrite Research Article Rorippa nasturtium-aquaticum Seeds Toxicity Toxicity testing Ultraviolet radiation Waste Water Technology Water Management Water Pollution Control Watercress Wavelengths Zinc oxide Zinc oxides |
| title | Production of pyrite-based catalysts supported on graphene oxide and zinc oxide to treat drug mixture via advanced oxidation processes |
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