Intramolecular through-space NMR spectroscopic effect of steric compression on 1H NMR spectroscopy

The intramolecular through-space NMR spectroscopic effect of steric compression is related to intramolecular through-space van der Waals repulsion. The electron cloud of a proton can be pushed away by the electron cloud of a nearby proton or functional group. As the electron population of the steric...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Organic & biomolecular chemistry 2024-10, Vol.22 (39), p.7915-7935
Hauptverfasser:	Zeng, Ziyu, Qasem, Ashraf M A, Blagbrough, Ian S, Woodman, Timothy J
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical equilibrium Compression Conformation Coupling Electron clouds Functional groups Magnetic resonance spectroscopy NMR NMR spectroscopy Nuclear magnetic resonance Protons
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!