Electro-, photo-, and photoelectrochemical degradation of chloramphenicol on self-doping Ti nanotubes
In this work, the photo-, electro-, and photo-electro-oxidation of chloramphenicol was investigated. The photo-experiments were carried out with different irradiation sources (an ultraviolet and a simulated solar source) using self-doped titanium nanotubes (SDTNT), a very promising and innovative ma...
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| Veröffentlicht in: | Environmental science and pollution research international 2024-09, Vol.31 (43), p.55119-55131 |
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| creator | da Silva, Marinez Marlene da Silva Santos, João Paulo Tenório de Oliveira, Adeildo Júnior da Silva, Diego David Fernandes, Carlos Henrique Magalhães de Vasconcelos Lanza, Marcos Roberto Tremiliosi-Filho, Germano Del Colle, Vinicius |
| description | In this work, the photo-, electro-, and photo-electro-oxidation of chloramphenicol was investigated. The photo-experiments were carried out with different irradiation sources (an ultraviolet and a simulated solar source) using self-doped titanium nanotubes (SDTNT), a very promising and innovative material that deserves further investigations in the degradation of different pollutants. The photo-electrooxidation (
j
= 15 mA cm
–2
) under simulated solar irradiation presented the best efficiency, with ca. 100% degradation and kinetic constant of
k
= 0.04427 min
–1
. The FTIR analysis demonstrated a structural modification of the standard molecule occurred for all conditions used, suggesting a modification in functional groups responsible for the biological activity. Furthermore, the TOC analysis showed a significant mineralization of the pollutant (66% from the initial concentration). In addition, both photo-electrooxidation approaches have demonstrated a positive value of
S
, where the simulated solar irradiation reached the highest value
S
= 0.6960. The experimental results pointed out evidence that the methodology employed herein for chloramphenicol degradation is greatly interesting and the photo-electrooxidation under simulated solar irradiation is a promising approach for this purpose. |
| doi_str_mv | 10.1007/s11356-024-34841-2 |
| format | Article |
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j
= 15 mA cm
–2
) under simulated solar irradiation presented the best efficiency, with ca. 100% degradation and kinetic constant of
k
= 0.04427 min
–1
. The FTIR analysis demonstrated a structural modification of the standard molecule occurred for all conditions used, suggesting a modification in functional groups responsible for the biological activity. Furthermore, the TOC analysis showed a significant mineralization of the pollutant (66% from the initial concentration). In addition, both photo-electrooxidation approaches have demonstrated a positive value of
S
, where the simulated solar irradiation reached the highest value
S
= 0.6960. The experimental results pointed out evidence that the methodology employed herein for chloramphenicol degradation is greatly interesting and the photo-electrooxidation under simulated solar irradiation is a promising approach for this purpose.</description><identifier>ISSN: 1614-7499</identifier><identifier>ISSN: 0944-1344</identifier><identifier>EISSN: 1614-7499</identifier><identifier>DOI: 10.1007/s11356-024-34841-2</identifier><identifier>PMID: 39245671</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Antibiotics ; Aquatic Pollution ; Atmospheric Protection/Air Quality Control/Air Pollution ; bioactive properties ; Biological activity ; Carbon ; Chemistry ; Chloramphenicol ; Chloramphenicol - chemistry ; Chloromycetin ; Degradation ; Earth and Environmental Science ; Ecotoxicology ; Efficiency ; Electrodes ; Environment ; Environmental Chemistry ; Environmental Health ; Environmental science ; Fourier transforms ; Functional groups ; Investigations ; Irradiation ; Kinetics ; Mineralization ; Nanotechnology ; Nanotubes ; Nanotubes - chemistry ; Oxidation ; Oxidation-Reduction ; Oxygen ; Pharmaceuticals ; Pollutants ; Pollution ; Review Article ; Solar radiation ; Structure-function relationships ; Titanium ; Titanium - chemistry ; Ultraviolet radiation ; Waste Water Technology ; Water Management ; Water Pollution Control</subject><ispartof>Environmental science and pollution research international, 2024-09, Vol.31 (43), p.55119-55131</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><rights>2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c2742-6cded91e6800af78c236dc09ded16571ceca4eca3ce2043083be555aa861aaa83</cites><orcidid>0000-0001-8595-5129</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11356-024-34841-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11356-024-34841-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/39245671$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>da Silva, Marinez Marlene</creatorcontrib><creatorcontrib>da Silva Santos, João Paulo Tenório</creatorcontrib><creatorcontrib>de Oliveira, Adeildo Júnior</creatorcontrib><creatorcontrib>da Silva, Diego David</creatorcontrib><creatorcontrib>Fernandes, Carlos Henrique Magalhães</creatorcontrib><creatorcontrib>de Vasconcelos Lanza, Marcos Roberto</creatorcontrib><creatorcontrib>Tremiliosi-Filho, Germano</creatorcontrib><creatorcontrib>Del Colle, Vinicius</creatorcontrib><title>Electro-, photo-, and photoelectrochemical degradation of chloramphenicol on self-doping Ti nanotubes</title><title>Environmental science and pollution research international</title><addtitle>Environ Sci Pollut Res</addtitle><addtitle>Environ Sci Pollut Res Int</addtitle><description>In this work, the photo-, electro-, and photo-electro-oxidation of chloramphenicol was investigated. The photo-experiments were carried out with different irradiation sources (an ultraviolet and a simulated solar source) using self-doped titanium nanotubes (SDTNT), a very promising and innovative material that deserves further investigations in the degradation of different pollutants. The photo-electrooxidation (
j
= 15 mA cm
–2
) under simulated solar irradiation presented the best efficiency, with ca. 100% degradation and kinetic constant of
k
= 0.04427 min
–1
. The FTIR analysis demonstrated a structural modification of the standard molecule occurred for all conditions used, suggesting a modification in functional groups responsible for the biological activity. Furthermore, the TOC analysis showed a significant mineralization of the pollutant (66% from the initial concentration). In addition, both photo-electrooxidation approaches have demonstrated a positive value of
S
, where the simulated solar irradiation reached the highest value
S
= 0.6960. The experimental results pointed out evidence that the methodology employed herein for chloramphenicol degradation is greatly interesting and the photo-electrooxidation under simulated solar irradiation is a promising approach for this purpose.</description><subject>Antibiotics</subject><subject>Aquatic Pollution</subject><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>bioactive properties</subject><subject>Biological activity</subject><subject>Carbon</subject><subject>Chemistry</subject><subject>Chloramphenicol</subject><subject>Chloramphenicol - chemistry</subject><subject>Chloromycetin</subject><subject>Degradation</subject><subject>Earth and Environmental Science</subject><subject>Ecotoxicology</subject><subject>Efficiency</subject><subject>Electrodes</subject><subject>Environment</subject><subject>Environmental Chemistry</subject><subject>Environmental Health</subject><subject>Environmental science</subject><subject>Fourier transforms</subject><subject>Functional groups</subject><subject>Investigations</subject><subject>Irradiation</subject><subject>Kinetics</subject><subject>Mineralization</subject><subject>Nanotechnology</subject><subject>Nanotubes</subject><subject>Nanotubes - chemistry</subject><subject>Oxidation</subject><subject>Oxidation-Reduction</subject><subject>Oxygen</subject><subject>Pharmaceuticals</subject><subject>Pollutants</subject><subject>Pollution</subject><subject>Review Article</subject><subject>Solar radiation</subject><subject>Structure-function relationships</subject><subject>Titanium</subject><subject>Titanium - chemistry</subject><subject>Ultraviolet radiation</subject><subject>Waste Water Technology</subject><subject>Water Management</subject><subject>Water Pollution Control</subject><issn>1614-7499</issn><issn>0944-1344</issn><issn>1614-7499</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqNkU1r3DAQhkVpaTYffyCHYuilh6rRt-xjWNKmsJDL5iy08njtYEuOZB_y76ONt03JoeQgzTDzzDtIL0KXlPyghOirRCmXChMmMBeloJh9QCuqqMBaVNXHf_ITdJrSAyGMVEx_Rie8YkIqTVcIbnpwUwz4ezG2YTpE6-slh6XlWhg6Z_uihn20tZ264IvQFK7tQ7TD2ILvXOiLXE3QN7gOY-f3xbYrvPVhmneQztGnxvYJLo7xDN3_vNmub_Hm7tfv9fUGO6YFw8rVUFcUVEmIbXTpGFe1I1WuUiU1deCsyIc7YERwUvIdSCmtLRW1-eZn6NuiO8bwOEOazNAlB31vPYQ5GU4l16UgTL4Dzb-lCeE0o1_foA9hjj4_5EBpzqRWOlNsoVwMKUVozBi7wcYnQ4k5-GUWv0z2y7z4ZVge-nKUnncD1H9H_hiUAb4AKbf8HuLr7v_IPgP5E6BQ</recordid><startdate>202409</startdate><enddate>202409</enddate><creator>da Silva, Marinez Marlene</creator><creator>da Silva Santos, João Paulo Tenório</creator><creator>de Oliveira, Adeildo Júnior</creator><creator>da Silva, Diego David</creator><creator>Fernandes, Carlos Henrique Magalhães</creator><creator>de Vasconcelos Lanza, Marcos Roberto</creator><creator>Tremiliosi-Filho, Germano</creator><creator>Del Colle, Vinicius</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QL</scope><scope>7SN</scope><scope>7T7</scope><scope>7TV</scope><scope>7U7</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>K9.</scope><scope>M7N</scope><scope>P64</scope><scope>7X8</scope><scope>7S9</scope><scope>L.6</scope><orcidid>https://orcid.org/0000-0001-8595-5129</orcidid></search><sort><creationdate>202409</creationdate><title>Electro-, photo-, and photoelectrochemical degradation of chloramphenicol on self-doping Ti nanotubes</title><author>da Silva, Marinez Marlene ; da Silva Santos, João Paulo Tenório ; de Oliveira, Adeildo Júnior ; da Silva, Diego David ; Fernandes, Carlos Henrique Magalhães ; de Vasconcelos Lanza, Marcos Roberto ; Tremiliosi-Filho, Germano ; Del Colle, Vinicius</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2742-6cded91e6800af78c236dc09ded16571ceca4eca3ce2043083be555aa861aaa83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Antibiotics</topic><topic>Aquatic Pollution</topic><topic>Atmospheric Protection/Air Quality Control/Air Pollution</topic><topic>bioactive properties</topic><topic>Biological activity</topic><topic>Carbon</topic><topic>Chemistry</topic><topic>Chloramphenicol</topic><topic>Chloramphenicol - chemistry</topic><topic>Chloromycetin</topic><topic>Degradation</topic><topic>Earth and Environmental Science</topic><topic>Ecotoxicology</topic><topic>Efficiency</topic><topic>Electrodes</topic><topic>Environment</topic><topic>Environmental Chemistry</topic><topic>Environmental Health</topic><topic>Environmental science</topic><topic>Fourier transforms</topic><topic>Functional groups</topic><topic>Investigations</topic><topic>Irradiation</topic><topic>Kinetics</topic><topic>Mineralization</topic><topic>Nanotechnology</topic><topic>Nanotubes</topic><topic>Nanotubes - chemistry</topic><topic>Oxidation</topic><topic>Oxidation-Reduction</topic><topic>Oxygen</topic><topic>Pharmaceuticals</topic><topic>Pollutants</topic><topic>Pollution</topic><topic>Review Article</topic><topic>Solar radiation</topic><topic>Structure-function relationships</topic><topic>Titanium</topic><topic>Titanium - chemistry</topic><topic>Ultraviolet radiation</topic><topic>Waste Water Technology</topic><topic>Water Management</topic><topic>Water Pollution Control</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>da Silva, Marinez Marlene</creatorcontrib><creatorcontrib>da Silva Santos, João Paulo Tenório</creatorcontrib><creatorcontrib>de Oliveira, Adeildo Júnior</creatorcontrib><creatorcontrib>da Silva, Diego David</creatorcontrib><creatorcontrib>Fernandes, Carlos Henrique Magalhães</creatorcontrib><creatorcontrib>de Vasconcelos Lanza, Marcos Roberto</creatorcontrib><creatorcontrib>Tremiliosi-Filho, Germano</creatorcontrib><creatorcontrib>Del Colle, Vinicius</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Bacteriology Abstracts (Microbiology B)</collection><collection>Ecology Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Pollution Abstracts</collection><collection>Toxicology Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>Algology Mycology and Protozoology Abstracts (Microbiology C)</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>MEDLINE - Academic</collection><collection>AGRICOLA</collection><collection>AGRICOLA - Academic</collection><jtitle>Environmental science and pollution research international</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>da Silva, Marinez Marlene</au><au>da Silva Santos, João Paulo Tenório</au><au>de Oliveira, Adeildo Júnior</au><au>da Silva, Diego David</au><au>Fernandes, Carlos Henrique Magalhães</au><au>de Vasconcelos Lanza, Marcos Roberto</au><au>Tremiliosi-Filho, Germano</au><au>Del Colle, Vinicius</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electro-, photo-, and photoelectrochemical degradation of chloramphenicol on self-doping Ti nanotubes</atitle><jtitle>Environmental science and pollution research international</jtitle><stitle>Environ Sci Pollut Res</stitle><addtitle>Environ Sci Pollut Res Int</addtitle><date>2024-09</date><risdate>2024</risdate><volume>31</volume><issue>43</issue><spage>55119</spage><epage>55131</epage><pages>55119-55131</pages><issn>1614-7499</issn><issn>0944-1344</issn><eissn>1614-7499</eissn><abstract>In this work, the photo-, electro-, and photo-electro-oxidation of chloramphenicol was investigated. The photo-experiments were carried out with different irradiation sources (an ultraviolet and a simulated solar source) using self-doped titanium nanotubes (SDTNT), a very promising and innovative material that deserves further investigations in the degradation of different pollutants. The photo-electrooxidation (
j
= 15 mA cm
–2
) under simulated solar irradiation presented the best efficiency, with ca. 100% degradation and kinetic constant of
k
= 0.04427 min
–1
. The FTIR analysis demonstrated a structural modification of the standard molecule occurred for all conditions used, suggesting a modification in functional groups responsible for the biological activity. Furthermore, the TOC analysis showed a significant mineralization of the pollutant (66% from the initial concentration). In addition, both photo-electrooxidation approaches have demonstrated a positive value of
S
, where the simulated solar irradiation reached the highest value
S
= 0.6960. The experimental results pointed out evidence that the methodology employed herein for chloramphenicol degradation is greatly interesting and the photo-electrooxidation under simulated solar irradiation is a promising approach for this purpose.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><pmid>39245671</pmid><doi>10.1007/s11356-024-34841-2</doi><tpages>13</tpages><orcidid>https://orcid.org/0000-0001-8595-5129</orcidid></addata></record> |
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| subjects | Antibiotics Aquatic Pollution Atmospheric Protection/Air Quality Control/Air Pollution bioactive properties Biological activity Carbon Chemistry Chloramphenicol Chloramphenicol - chemistry Chloromycetin Degradation Earth and Environmental Science Ecotoxicology Efficiency Electrodes Environment Environmental Chemistry Environmental Health Environmental science Fourier transforms Functional groups Investigations Irradiation Kinetics Mineralization Nanotechnology Nanotubes Nanotubes - chemistry Oxidation Oxidation-Reduction Oxygen Pharmaceuticals Pollutants Pollution Review Article Solar radiation Structure-function relationships Titanium Titanium - chemistry Ultraviolet radiation Waste Water Technology Water Management Water Pollution Control |
| title | Electro-, photo-, and photoelectrochemical degradation of chloramphenicol on self-doping Ti nanotubes |
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