Self-assembly of arrays of micro-rings by colloidal evaporative deposition

We describe self-assembly of arrays of micro-rings in a drying process of a mixture of H 2O and C 2H 5OH (1:1) and trace amounts of NH 4OH with suspended SiO 2 nano-particles of 102.5 nm average diameter. A drop of 2 mm diameter of the colloid is placed on a nearly vertical SiO 2 substrate. A drop s...

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Veröffentlicht in:Surface science 2007-11, Vol.601 (21), p.4922-4924
Hauptverfasser: Stefaniuk, Tomasz, Wrobel, Piotr, Dominiak, Radoslaw, Gawlik, Grzegorz, Bajdor, Krzysztof, Zielecka, Maria, Szoplik, Tomasz
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container_end_page 4924
container_issue 21
container_start_page 4922
container_title Surface science
container_volume 601
creator Stefaniuk, Tomasz
Wrobel, Piotr
Dominiak, Radoslaw
Gawlik, Grzegorz
Bajdor, Krzysztof
Zielecka, Maria
Szoplik, Tomasz
description We describe self-assembly of arrays of micro-rings in a drying process of a mixture of H 2O and C 2H 5OH (1:1) and trace amounts of NH 4OH with suspended SiO 2 nano-particles of 102.5 nm average diameter. A drop of 2 mm diameter of the colloid is placed on a nearly vertical SiO 2 substrate. A drop spills down and spreads into a wedge-shape thin film. Initially, the colloid wets the substrate. Due to different evaporation rates of solvent components the wettability of the colloid changes. The content of alcohol decreases and the liquid mixture does not wet the substrate any more. The colloidal thin film brakes into rhomboidal segments, which aggregate into a regular lattice of droplets. Each droplet evaporates and forms a micro-ring of about 80 μm in diameter. The micro-rings self-assemble into a rhomboid array with lattice constant ratio of 1:0.9.
doi_str_mv 10.1016/j.susc.2007.08.021
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subjects Colloid evaporation
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science
rheology
Evaporative deposition
Exact sciences and technology
Micro-ring
Micro-rings array
Physics
Self-assembly
Silicon dioxide nanosphere
Silicone dioxide surface
Wet coating
title Self-assembly of arrays of micro-rings by colloidal evaporative deposition
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