Pronounced Cold Crystallization and Hydrogen Bonding Distortion of Water Confined in Microphases of Double Zwitterionic Block Copolymer Aqueous Solutions
Advanced materials leveraging water control are garnering considerable interest, with the state of water emerging as a critical aspect of material design. This study explored the impact of microphase separation on water using aqueous solutions of double zwitterionic diblock copolymers, specifically...
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| Veröffentlicht in: | Langmuir 2024-09, Vol.40 (37), p.19612-19618 |
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| container_issue | 37 |
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| container_title | Langmuir |
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| creator | Higaki, Yuji Masuda, Takumi Shiomoto, Shohei Tanaka, Yukiko Kiuchi, Hisao Harada, Yoshihisa Tanaka, Masaru |
| description | Advanced materials leveraging water control are garnering considerable interest, with the state of water emerging as a critical aspect of material design. This study explored the impact of microphase separation on water using aqueous solutions of double zwitterionic diblock copolymers, specifically poly(carboxybetaine methacrylate) and poly(sulfobetaine methacrylate) (PCB2-b-PSB4). These copolymers form a mesoscale periodic ordered lattice structure consisting of two distinct aqueous phases. Through differential scanning calorimetry and X-ray emission spectroscopy, it was found that water in these PCB2-b-PSB4 aqueous solutions exhibits pronounced cold crystallization and subtle distortions in hydrogen-bonding configurations. |
| doi_str_mv | 10.1021/acs.langmuir.4c02254 |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 0743-7463 |
| ispartof | Langmuir, 2024-09, Vol.40 (37), p.19612-19618 |
| issn | 0743-7463 1520-5827 1520-5827 |
| language | eng |
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| source | American Chemical Society (ACS) |
| subjects | calorimetry cold composite polymers crystallization hydrogen hydrogen bonding spectroscopy sulfobetaine X-radiation zwitterions |
| title | Pronounced Cold Crystallization and Hydrogen Bonding Distortion of Water Confined in Microphases of Double Zwitterionic Block Copolymer Aqueous Solutions |
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