Synthesis and structure of a bimetallic hybrid inorganic/organic layered coordination polymer with an octamolybdate cluster variant trapped between the α and δ isomeric forms

Hydrothermal combination of CuSO 4, MoO 3, and 4-phenylpyridine (4-phpyr) in a 1:4:4.5 ratio under basic conditions afforded purple crystals of {[Cu(4-phpyr) 4] 2(Mo 8O 26)·4-phpyr} ( 1), which were analyzed by spectroscopy and single crystal X-ray diffraction. The asymmetric octamolybdate clusters...

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