Equilibrium liquidus temperatures of binary mixtures from differential scanning calorimetry

The measurements of solid–liquid phase diagrams for a binary mixture using a differential scanning calorimeter are revisited in this paper. A new method employing the DSC curves and a theoretical model to detect solid–liquid equilibrium temperature of the initial mixture before freezing is proposed....

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Veröffentlicht in:Chemical engineering science 2007-12, Vol.62 (23), p.6516-6523
Hauptverfasser: Kousksou, T., Jamil, A., Zeraouli, Y., Dumas, J.-P.
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container_title Chemical engineering science
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creator Kousksou, T.
Jamil, A.
Zeraouli, Y.
Dumas, J.-P.
description The measurements of solid–liquid phase diagrams for a binary mixture using a differential scanning calorimeter are revisited in this paper. A new method employing the DSC curves and a theoretical model to detect solid–liquid equilibrium temperature of the initial mixture before freezing is proposed. The liquidus temperatures for different compositions are found to be in good agreement with the available literature data.
doi_str_mv 10.1016/j.ces.2007.07.008
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subjects Applied sciences
Binary mixtures
Chemical engineering
DSC
Exact sciences and technology
Heat and mass transfer. Packings, plates
Heat transfer
Solid–liquid equilibrium
Thermodynamics
Water–ethanol
title Equilibrium liquidus temperatures of binary mixtures from differential scanning calorimetry
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