Equilibrium liquidus temperatures of binary mixtures from differential scanning calorimetry
The measurements of solid–liquid phase diagrams for a binary mixture using a differential scanning calorimeter are revisited in this paper. A new method employing the DSC curves and a theoretical model to detect solid–liquid equilibrium temperature of the initial mixture before freezing is proposed....
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Veröffentlicht in: | Chemical engineering science 2007-12, Vol.62 (23), p.6516-6523 |
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creator | Kousksou, T. Jamil, A. Zeraouli, Y. Dumas, J.-P. |
description | The measurements of solid–liquid phase diagrams for a binary mixture using a differential scanning calorimeter are revisited in this paper. A new method employing the DSC curves and a theoretical model to detect solid–liquid equilibrium temperature of the initial mixture before freezing is proposed. The liquidus temperatures for different compositions are found to be in good agreement with the available literature data. |
doi_str_mv | 10.1016/j.ces.2007.07.008 |
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A new method employing the DSC curves and a theoretical model to detect solid–liquid equilibrium temperature of the initial mixture before freezing is proposed. The liquidus temperatures for different compositions are found to be in good agreement with the available literature data.</description><subject>Applied sciences</subject><subject>Binary mixtures</subject><subject>Chemical engineering</subject><subject>DSC</subject><subject>Exact sciences and technology</subject><subject>Heat and mass transfer. 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subjects | Applied sciences Binary mixtures Chemical engineering DSC Exact sciences and technology Heat and mass transfer. Packings, plates Heat transfer Solid–liquid equilibrium Thermodynamics Water–ethanol |
title | Equilibrium liquidus temperatures of binary mixtures from differential scanning calorimetry |
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