Molecularly Imprinted Nanofiber Membranes from Carboxylated Polysulfone by Electrospray Deposition
It is demonstrated that polymeric materials can be directly converted into molecular (chiral) recognition nanofiber membranes by simultaneously applying an electrospray deposition and an alternative molecular imprinting during the membrane preparation process. Polysulfone with a degree of substituti...
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| Veröffentlicht in: | Macromolecular rapid communications. 2007-11, Vol.28 (21), p.2100-2105 |
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| container_title | Macromolecular rapid communications. |
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| creator | Yoshikawa, Masakazu Nakai, Koji Matsumoto, Hidetoshi Tanioka, Akihiko Guiver, Michael D. Robertson, Gilles P. |
| description | It is demonstrated that polymeric materials can be directly converted into molecular (chiral) recognition nanofiber membranes by simultaneously applying an electrospray deposition and an alternative molecular imprinting during the membrane preparation process. Polysulfone with a degree of substitution of 0.88 was adopted as the candidate polymeric material for molecularly imprinted nanofiber membranes. Molecularly imprinted nanofiber membranes imprinted by Z‐D‐Glu recognize the D‐isomer in preference to the corresponding L‐isomer and vice versa. The amino acid preferentially incorporated into the membrane is selectively permeated through the membrane by using a concentration gradient as a driving force for membrane transport. |
| doi_str_mv | 10.1002/marc.200700359 |
| format | Article |
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Rapid Commun</addtitle><date>2007-11-01</date><risdate>2007</risdate><volume>28</volume><issue>21</issue><spage>2100</spage><epage>2105</epage><pages>2100-2105</pages><issn>1022-1336</issn><eissn>1521-3927</eissn><abstract>It is demonstrated that polymeric materials can be directly converted into molecular (chiral) recognition nanofiber membranes by simultaneously applying an electrospray deposition and an alternative molecular imprinting during the membrane preparation process. Polysulfone with a degree of substitution of 0.88 was adopted as the candidate polymeric material for molecularly imprinted nanofiber membranes. Molecularly imprinted nanofiber membranes imprinted by Z‐D‐Glu recognize the D‐isomer in preference to the corresponding L‐isomer and vice versa. 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| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Applied sciences chiral separation electrospray deposition Exact sciences and technology Exchange resins and membranes Forms of application and semi-finished materials membranes molecular imprinting nanofiber membranes optical resolution Polymer industry, paints, wood polysulfones Technology of polymers |
| title | Molecularly Imprinted Nanofiber Membranes from Carboxylated Polysulfone by Electrospray Deposition |
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