Electrical and optical characterisation of CuInS2 crystals and polycrystalline coevaporated thin films

Single crystals CuInS2 were grown by iodine vapour transport method, whereas polycrystalline thin films were obtained by coevaporation technique from three sources. The temperature dependence of the hole mobility in valence band is analysed by taking into account contributions from several scatterin...

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Veröffentlicht in:Solar energy materials and solar cells 2007-12, Vol.91 (20), p.1916-1921
Hauptverfasser: AMARA, A, REZAIKI, W, FERDI, A, HENDAOUI, A, DRICI, A, GUERIOUNE, M, BERNEDE, J. C, MORSLI, M
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container_end_page 1921
container_issue 20
container_start_page 1916
container_title Solar energy materials and solar cells
container_volume 91
creator AMARA, A
REZAIKI, W
FERDI, A
HENDAOUI, A
DRICI, A
GUERIOUNE, M
BERNEDE, J. C
MORSLI, M
description Single crystals CuInS2 were grown by iodine vapour transport method, whereas polycrystalline thin films were obtained by coevaporation technique from three sources. The temperature dependence of the hole mobility in valence band is analysed by taking into account contributions from several scattering mechanisms of the charge carriers. To account for the temperature dependant conductivity of polycrystalline CuInS2 thin films, grainboundary conduction process was suggested. In the low temperature region, we interpret the data in terms of the Mott law and the analysis is very consistent with the variable range hopping. However, thermionic emission is predominant at high temperatures. Photoluminescence measurements have been performed on CuInS2 crystals and the analysis has revealed that the emission is mainly due to free-to-bound and donor-acceptor pair transitions. The band gap of that compound is derived from the excitonic emission line at 1.53eV.
doi_str_mv 10.1016/j.solmat.2007.07.007
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source Elsevier ScienceDirect Journals Complete
subjects Applied sciences
Energy
Exact sciences and technology
Natural energy
Photovoltaic conversion
Solar cells. Photoelectrochemical cells
Solar energy
title Electrical and optical characterisation of CuInS2 crystals and polycrystalline coevaporated thin films
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