Stabilizing zinc anodes via engineering the active sites and pore structure of functional composite layers

Functional composite layers composed of an amino-functionalized zirconium 1,4-dicarboxybenzene metal-organic framework were constructed on zinc anodes to mitigate the interface disturbances in aqueous batteries. These layers enable robust Zn adsorption and homogenized Zn transport and deposition kin...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2024-09, Vol.60 (73), p.9962-9965
Hauptverfasser: Li, Kun, Chen, Jiahao, Xu, Wang, Yan, Zhongfu, Yang, Borui, Li, Ting, He, Miao, Liu, Jing, Hu, Anjun, Long, Jianping
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container_end_page 9965
container_issue 73
container_start_page 9962
container_title Chemical communications (Cambridge, England)
container_volume 60
creator Li, Kun
Chen, Jiahao
Xu, Wang
Yan, Zhongfu
Yang, Borui
Li, Ting
He, Miao
Liu, Jing
Hu, Anjun
Long, Jianping
description Functional composite layers composed of an amino-functionalized zirconium 1,4-dicarboxybenzene metal-organic framework were constructed on zinc anodes to mitigate the interface disturbances in aqueous batteries. These layers enable robust Zn adsorption and homogenized Zn transport and deposition kinetics, facilitating achieving high stability in a symmetric cell (3500 h) and a full cell (35 000 cycles, 96.7%).
doi_str_mv 10.1039/d4cc03536d
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source Royal Society Of Chemistry Journals; Alma/SFX Local Collection
subjects Anodes
Metal-organic frameworks
Zinc
Zirconium
title Stabilizing zinc anodes via engineering the active sites and pore structure of functional composite layers
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