Functionalization of Crystalline Colloidal Arrays through Click Chemistry

The preparation of well‐defined and regioselectively functionalized ordered colloidal particles through the exploitation of ‘click' transformations is presented; specifically, the copper(I)‐catalyzed Huisgen 1,3‐dipolar cycloaddition between azides and terminal alkynes to form 1,2,3‐triazoles i...

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Veröffentlicht in:	Advanced materials (Weinheim) 2007-11, Vol.19 (21), p.3507-3512
Hauptverfasser:	Evanoff Jr, D. D., Hayes, S. E., Ying, Y., Shim, G. H., Lawrence, J. R., Carroll, J. B., Roeder, R. D., Houchins, J. M., Huebner, C. F., Foulger, S. H.
Format:	Artikel
Sprache:	eng
Schlagworte:	colloidal Colloids Photonic crystals Photonic crystals, colloidal Self-assembly
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	The preparation of well‐defined and regioselectively functionalized ordered colloidal particles through the exploitation of ‘click' transformations is presented; specifically, the copper(I)‐catalyzed Huisgen 1,3‐dipolar cycloaddition between azides and terminal alkynes to form 1,2,3‐triazoles is utilized. This approach is demonstrated through the attachment of 9‐azidomethylanthracene to post‐hydrogel stabilized, ordered poly(propargyl acrylate) colloidal particles.
ISSN:	0935-9648 1521-4095
DOI:	10.1002/adma.200602901