Crystallization‐Driven Controlled 2D Self‐Assemblies via Aqueous RAFT Emulsion Polymerization

Aqueous emulsion polymerization is a robust technique for preparing nanoparticles of block copolymers; however, it typically yields spherical nanoassemblies. The scale preparation of nanoassemblies with nonspherical high‐order morphologies is a challenge, particularly 2D core–shell nanosheets. In th...

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Veröffentlicht in:	Macromolecular rapid communications. 2024-12, Vol.45 (23), p.e2400549-n/a
Hauptverfasser:	Yu, Li, Cui, Yuhong, Xing, Mingxue, Sun, Yuemeng, Li, Zhengxiao, Liu, Yingchun, Qu, Xiongwei, Chen, Shengli
Format:	Artikel
Sprache:	eng
Schlagworte:	2D nanosheet Addition polymerization amphiphilic block copolymers Block copolymers Chain transfer Copolymers Crystallization crystallization‐driven self‐assembly (CDSA) Emulsion polymerization Emulsions Emulsions - chemistry Graft copolymers Methacrylates - chemistry Molecular Structure Morphology Nanoparticles Nanoparticles - chemistry Nanosheets Particle Size Polycaprolactone Polyesters - chemical synthesis Polyesters - chemistry Polyhydroxyethyl methacrylate Polymerization polymerization‐induced self‐assembly (PISA) Polymers - chemical synthesis Polymers - chemistry reversible addition‐fragmentation chain transfer (RAFT) emulsion polymerization Ring opening polymerization Robust control Seeds Self-assembly Two dimensional analysis Two dimensional flow Water - chemistry
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