ZnMn2(PO4)2·nH2O: An H2O‑Imbedding-Activated Cathode for Robust Aqueous Zinc-Ion Batteries
Component modulation endows Mn-based electrodes with prominent energy storage properties due to their adjustable crystal structure characteristics. Herein, ZnMn2(PO4)2·nH2O (ZMP·nH2O) was obtained by a hydration reaction from ZnMn2(PO4)2 (ZMP) during an electrode-aging evolution. Benefiting from the...
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| Veröffentlicht in: | Nano letters 2024-08, Vol.24 (32), p.9816-9823 |
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| container_title | Nano letters |
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| creator | Wang, Chunhui Xian, Keyi Zhao, Shuangshuang Yang, Lishan Zhou, Junjian Yang, Yahui Chen, Xiangping Yin, Jiang Wang, Jun Qin, Haozhe Tian, Zhongliang Lai, Yanqing Wang, Zhongchang Zhang, Bao Wang, Haiyan |
| description | Component modulation endows Mn-based electrodes with prominent energy storage properties due to their adjustable crystal structure characteristics. Herein, ZnMn2(PO4)2·nH2O (ZMP·nH2O) was obtained by a hydration reaction from ZnMn2(PO4)2 (ZMP) during an electrode-aging evolution. Benefiting from the introduction of lattice H2O molecules into the ZMP structure, the ion transmission path has been expanded along with the extended d-spacing, which will further facilitate the ZMP → ZMP·nH2O phase evolution and electrochemical reaction kinetics. Meanwhile, the hydrogen bond can be generated between H2O and O in PO4 3–, which strengthens the structure stability of ZMP·nH2O and lowers the conversion barrier from ZMP to ZMP·4H2O during the Zn2+ uptake/removal process. Thereof, ZMP·nH2O delivers enhanced electrochemical reaction kinetics with robust structure tolerance (106.52 mA h g–1 at 100 mA g–1 over 620 cycles). This high-energy aqueous Zn||ZMP·nH2O battery provides a facile strategy for engineering and exploration of high-performance ZIBs to realize the practical application of Mn-based cathodes. |
| doi_str_mv | 10.1021/acs.nanolett.4c01420 |
| format | Article |
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Herein, ZnMn2(PO4)2·nH2O (ZMP·nH2O) was obtained by a hydration reaction from ZnMn2(PO4)2 (ZMP) during an electrode-aging evolution. Benefiting from the introduction of lattice H2O molecules into the ZMP structure, the ion transmission path has been expanded along with the extended d-spacing, which will further facilitate the ZMP → ZMP·nH2O phase evolution and electrochemical reaction kinetics. Meanwhile, the hydrogen bond can be generated between H2O and O in PO4 3–, which strengthens the structure stability of ZMP·nH2O and lowers the conversion barrier from ZMP to ZMP·4H2O during the Zn2+ uptake/removal process. Thereof, ZMP·nH2O delivers enhanced electrochemical reaction kinetics with robust structure tolerance (106.52 mA h g–1 at 100 mA g–1 over 620 cycles). This high-energy aqueous Zn||ZMP·nH2O battery provides a facile strategy for engineering and exploration of high-performance ZIBs to realize the practical application of Mn-based cathodes.</description><identifier>ISSN: 1530-6984</identifier><identifier>ISSN: 1530-6992</identifier><identifier>EISSN: 1530-6992</identifier><identifier>DOI: 10.1021/acs.nanolett.4c01420</identifier><language>eng</language><publisher>American Chemical Society</publisher><ispartof>Nano letters, 2024-08, Vol.24 (32), p.9816-9823</ispartof><rights>2024 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0003-2141-4803 ; 0000-0003-4987-6006</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acs.nanolett.4c01420$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acs.nanolett.4c01420$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,27055,27903,27904,56717,56767</link.rule.ids></links><search><creatorcontrib>Wang, Chunhui</creatorcontrib><creatorcontrib>Xian, Keyi</creatorcontrib><creatorcontrib>Zhao, Shuangshuang</creatorcontrib><creatorcontrib>Yang, Lishan</creatorcontrib><creatorcontrib>Zhou, Junjian</creatorcontrib><creatorcontrib>Yang, Yahui</creatorcontrib><creatorcontrib>Chen, Xiangping</creatorcontrib><creatorcontrib>Yin, Jiang</creatorcontrib><creatorcontrib>Wang, Jun</creatorcontrib><creatorcontrib>Qin, Haozhe</creatorcontrib><creatorcontrib>Tian, Zhongliang</creatorcontrib><creatorcontrib>Lai, Yanqing</creatorcontrib><creatorcontrib>Wang, Zhongchang</creatorcontrib><creatorcontrib>Zhang, Bao</creatorcontrib><creatorcontrib>Wang, Haiyan</creatorcontrib><title>ZnMn2(PO4)2·nH2O: An H2O‑Imbedding-Activated Cathode for Robust Aqueous Zinc-Ion Batteries</title><title>Nano letters</title><addtitle>Nano Lett</addtitle><description>Component modulation endows Mn-based electrodes with prominent energy storage properties due to their adjustable crystal structure characteristics. Herein, ZnMn2(PO4)2·nH2O (ZMP·nH2O) was obtained by a hydration reaction from ZnMn2(PO4)2 (ZMP) during an electrode-aging evolution. Benefiting from the introduction of lattice H2O molecules into the ZMP structure, the ion transmission path has been expanded along with the extended d-spacing, which will further facilitate the ZMP → ZMP·nH2O phase evolution and electrochemical reaction kinetics. Meanwhile, the hydrogen bond can be generated between H2O and O in PO4 3–, which strengthens the structure stability of ZMP·nH2O and lowers the conversion barrier from ZMP to ZMP·4H2O during the Zn2+ uptake/removal process. Thereof, ZMP·nH2O delivers enhanced electrochemical reaction kinetics with robust structure tolerance (106.52 mA h g–1 at 100 mA g–1 over 620 cycles). This high-energy aqueous Zn||ZMP·nH2O battery provides a facile strategy for engineering and exploration of high-performance ZIBs to realize the practical application of Mn-based cathodes.</description><issn>1530-6984</issn><issn>1530-6992</issn><issn>1530-6992</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNo9kM1KAzEUhYMoWKtv4CLLupia_8y4G4vaQqUiXRUkZDIZnTJNdJJx7Sv4NO59FJ_EKa2uzuVyOHx8AJxjNMaI4Ettwthp5xsb45gZhBlBB2CAOUWJyDJy-H-n7BichLBGCGWUowF4Wrl7R0YPC3ZBvr_clCyuYO5gnz8fn7NNYcuyds9JbmL9rqMt4UTHF19aWPkWPvqiCxHmb531XYCr2plk5h281jHatrbhFBxVugn2bJ9DsLy9WU6myXxxN5vk80RLxhLJsZZCcNOjV2VKC1JkBceUFKjSGFNWkao0xBguJE1TJBnFmWFamFSUWBI6BKPd7Gvre5YQ1aYOxjaNdlswRVEqucCMs76KdtXemVr7rnU9l8JIbUWq7fNPpNqLpL_SHmko</recordid><startdate>20240814</startdate><enddate>20240814</enddate><creator>Wang, Chunhui</creator><creator>Xian, Keyi</creator><creator>Zhao, Shuangshuang</creator><creator>Yang, Lishan</creator><creator>Zhou, Junjian</creator><creator>Yang, Yahui</creator><creator>Chen, Xiangping</creator><creator>Yin, Jiang</creator><creator>Wang, Jun</creator><creator>Qin, Haozhe</creator><creator>Tian, Zhongliang</creator><creator>Lai, Yanqing</creator><creator>Wang, Zhongchang</creator><creator>Zhang, Bao</creator><creator>Wang, Haiyan</creator><general>American Chemical Society</general><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-2141-4803</orcidid><orcidid>https://orcid.org/0000-0003-4987-6006</orcidid></search><sort><creationdate>20240814</creationdate><title>ZnMn2(PO4)2·nH2O: An H2O‑Imbedding-Activated Cathode for Robust Aqueous Zinc-Ion Batteries</title><author>Wang, Chunhui ; Xian, Keyi ; Zhao, Shuangshuang ; Yang, Lishan ; Zhou, Junjian ; Yang, Yahui ; Chen, Xiangping ; Yin, Jiang ; Wang, Jun ; Qin, Haozhe ; Tian, Zhongliang ; Lai, Yanqing ; Wang, Zhongchang ; Zhang, Bao ; Wang, Haiyan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a744-751a7665c4c0fd83b2b9b5132b0fa1134f2fdc2cc567388074319c4a6c86d1723</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Chunhui</creatorcontrib><creatorcontrib>Xian, Keyi</creatorcontrib><creatorcontrib>Zhao, Shuangshuang</creatorcontrib><creatorcontrib>Yang, Lishan</creatorcontrib><creatorcontrib>Zhou, Junjian</creatorcontrib><creatorcontrib>Yang, Yahui</creatorcontrib><creatorcontrib>Chen, Xiangping</creatorcontrib><creatorcontrib>Yin, Jiang</creatorcontrib><creatorcontrib>Wang, Jun</creatorcontrib><creatorcontrib>Qin, Haozhe</creatorcontrib><creatorcontrib>Tian, Zhongliang</creatorcontrib><creatorcontrib>Lai, Yanqing</creatorcontrib><creatorcontrib>Wang, Zhongchang</creatorcontrib><creatorcontrib>Zhang, Bao</creatorcontrib><creatorcontrib>Wang, Haiyan</creatorcontrib><collection>MEDLINE - Academic</collection><jtitle>Nano letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Chunhui</au><au>Xian, Keyi</au><au>Zhao, Shuangshuang</au><au>Yang, Lishan</au><au>Zhou, Junjian</au><au>Yang, Yahui</au><au>Chen, Xiangping</au><au>Yin, Jiang</au><au>Wang, Jun</au><au>Qin, Haozhe</au><au>Tian, Zhongliang</au><au>Lai, Yanqing</au><au>Wang, Zhongchang</au><au>Zhang, Bao</au><au>Wang, Haiyan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>ZnMn2(PO4)2·nH2O: An H2O‑Imbedding-Activated Cathode for Robust Aqueous Zinc-Ion Batteries</atitle><jtitle>Nano letters</jtitle><addtitle>Nano Lett</addtitle><date>2024-08-14</date><risdate>2024</risdate><volume>24</volume><issue>32</issue><spage>9816</spage><epage>9823</epage><pages>9816-9823</pages><issn>1530-6984</issn><issn>1530-6992</issn><eissn>1530-6992</eissn><abstract>Component modulation endows Mn-based electrodes with prominent energy storage properties due to their adjustable crystal structure characteristics. Herein, ZnMn2(PO4)2·nH2O (ZMP·nH2O) was obtained by a hydration reaction from ZnMn2(PO4)2 (ZMP) during an electrode-aging evolution. Benefiting from the introduction of lattice H2O molecules into the ZMP structure, the ion transmission path has been expanded along with the extended d-spacing, which will further facilitate the ZMP → ZMP·nH2O phase evolution and electrochemical reaction kinetics. Meanwhile, the hydrogen bond can be generated between H2O and O in PO4 3–, which strengthens the structure stability of ZMP·nH2O and lowers the conversion barrier from ZMP to ZMP·4H2O during the Zn2+ uptake/removal process. Thereof, ZMP·nH2O delivers enhanced electrochemical reaction kinetics with robust structure tolerance (106.52 mA h g–1 at 100 mA g–1 over 620 cycles). This high-energy aqueous Zn||ZMP·nH2O battery provides a facile strategy for engineering and exploration of high-performance ZIBs to realize the practical application of Mn-based cathodes.</abstract><pub>American Chemical Society</pub><doi>10.1021/acs.nanolett.4c01420</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0003-2141-4803</orcidid><orcidid>https://orcid.org/0000-0003-4987-6006</orcidid></addata></record> |
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| title | ZnMn2(PO4)2·nH2O: An H2O‑Imbedding-Activated Cathode for Robust Aqueous Zinc-Ion Batteries |
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