Repurposing a supramolecular iridium catalyst via secondary Zn⋯Odouble bond, length as m-dashC weak interactions between the ligand and substrate leads to ortho-selective C(sp2)-H borylation of benzamides with unusual kinetics

The iridium-catalyzed C-H borylation of benzamides typically leads to meta and para selectivities using state-of-the-art iridium-based N,N-chelating bipyridine ligands. However, reaching ortho selectivity patterns requires extensive trial-and-error screening via molecular design at the ligand first...

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Veröffentlicht in:	Chemical science (Cambridge) 2024-07, Vol.15 (30), p.11794
Hauptverfasser:	Trouvé, Jonathan, Delahaye, Vanessa, Tomasini, Michele, Rajeshwaran, Purushothaman, Roisnel, Thierry, Poater, Albert, Gramage-Doria, Rafael
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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