Selective Hydroboration of C−C Single Bonds without Transition‐Metal Catalysis

Selective hydroboration of C−C single bonds presents a fundamental challenge in the chemical industry. Previously, only catalytic systems utilizing precious metals Ir and Rh, in conjunction with N‐ and P‐ ligands, could achieve this, ensuring bond cleavage and selectivity. In sharp contrast, we disc...

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Veröffentlicht in:	Angewandte Chemie International Edition 2024-12, Vol.63 (51), p.e202412368-n/a
Hauptverfasser:	Li, Sida, Hu, Chaopeng, Leo Liu, Liu, Wu, Lipeng
Format:	Artikel
Sprache:	eng
Schlagworte:	Activation Amides Amines Carbonyl compounds Carbonyl groups Carbonyls Catalysis Chemical bonds Chemical industry Cleavage Cyclopropane C−C single bond Dehydrogenation Density functional theory Ductile-brittle transition Esters Functional groups Halides Hydroboration Ketones Ligands Metals Nitriles Nitrogen Organic compounds Selective Shift reaction Transition metals Transition-metal free
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