How can heteroatoms boost the performance of photoactive nanomaterials for wastewater purification?

Photocatalysis, as an alternative for treating persistent water pollutants, holds immense promise. However, limitations hinder sustained treatment and recycling under varying light conditions. This comprehensive review delves into the novel paradigm of metal and non-metal doping to overcome these challenges. It begins by discussing the fundamental principles of photocatalysis and its inherent limitations. Understanding these constraints is crucial for developing effective strategies. Band gap narrowing by metal and non-metal doping modifies the band gap, enabling visible-light absorption. Impurity energy levels and oxygen vacancies influenced the doping energy levels and surface defects. Interfacial electron transfer and charge carrier recombination are the most important factors that impact overall efficiency. The comparative analysis of nanomaterials are reviewed on various, including nanometal oxides, nanocarbon materials, and advanced two-dimensional structures. The synthesis process are narratively presented, emphasizing production yields, selectivity, and efficiency. The review has potential applications in the environment for efficient pollutant removal and water purification, economic cost-effective and scalable production and technological advancement catalyst design, in spite of its challenges in material stability, synthesis methods and optimizing band gaps. The novelty of the review paper is on the proposal of a new paradigm of heterojunctions of doped metal and non-metal photocatalysts to promise highly efficient water treatment. This review bridges the gap between fundamental research and practical applications, offering insights into tailored nano photocatalysts. [Display omitted] •Characterization of metal and non-metal-doped heteroatom photocatalysts.•Compare doped heteroatom nanomaterials in photocatalysis.•Future challenges in heteroatom-doped nanomaterials.