Bifunctional Ligands: Evaluating the Role of Acidic Protons in the Secondary Coordination Sphere

To evaluate bifunctional ligand reactivity involving NH acidic sites in the secondary coordination sphere, complexes where the proton has been substituted with a methyl group (NMe) are often investigated. An alternative strategy involves substitution of the NH group for an O. This contribution consi...

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Veröffentlicht in:	Chemistry : a European journal 2024-10, Vol.30 (57), p.e202304292-n/a
Hauptverfasser:	Jain, Anant Kumar, Malakar, Santanu, Cannon, Austin T., Gonzalez, Sophia Miranda M., Keller, Taylor M., Carroll, Patrick J., Gau, Michael R., Kuo, Jonathan L., Goldberg, Karen I.
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbonyl compounds Carbonyls Coordination Fluxionality Hydrogen bonds Ligands Pincer ligands Polymers Protic ligands Protons Pyrazole Pyrazoles Pyridines Secondary coordination sphere interactions Substitution reactions
Online-Zugang:	Volltext
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