Removal and detection of phenols through an SPE-HPLC method using microporous organic networks as adsorbent
The design and development of a facile synthesis approach to construct novel materials for the rapid adsorption and removal of environmental pollutants are of significant interest. In this work, we report the rational design and facile synthesis of magnetic core-shell-based microporous organic netwo...
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| Veröffentlicht in: | Analytical methods 2024-07, Vol.16 (29), p.5112-5119 |
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| creator | Ali, Azam Sun, Huipeng Rizvi, Syed Faheem Askari Nana, Ding Zhang, Haixia |
| description | The design and development of a facile synthesis approach to construct novel materials for the rapid adsorption and removal of environmental pollutants are of significant interest. In this work, we report the rational design and facile synthesis of magnetic core-shell-based microporous organic networks, Fe
3
O
4
@MON-TBPT-TEB (TTMON, achieved by reacting 2,4,6-tris(
p
-bromophenyl) triazine and 1,3,5-triethynylbenzene) and Fe
3
O
4
@MON-TBPM-DEBP (TDMON, achieved by reacting tetrakis (4-bromophenyl) methane and 4-4′-diethynylbiphenyl). These MONs possessed excellent dispersity, electrostatic attraction as well as plenty of π-π and hydrophobic interaction sites enabled them to efficiently absorb targeted environmental pollutants. TTMON and TDMON exhibited excellent adsorption capacities of 440 and 510 mg g
−1
, respectively, at 25 °C for 2,4,6-trichlorophenol (TCP). TCP, 2,4-dichlorophenol (DCP), 2-naphthol (2-NT) and 4-nitrophenol (4-NP) from aqueous solution were treated by both MONs, followed by their analysis with high-performance liquid chromatography (HPLC). For TDMON, the proposed SPE-HPLC-UV method showed an LOD of 0.03 μg L
−1
, LOQ of 0.11 μg L
−1
, and a wide linear range of 1-1000 μg L
−1
for TCP. The adsorption kinetics, thermodynamics, isotherms, effect of pH and humic acid (HA), ionic strength, regeneration, and reusability of the MONs were also studied. The results revealed that the novel-designed MONs have potential applications as efficient adsorbents in sample pretreatment.
A rational design and facile synthesis approach were used for the construction of novel magnetically separating MONs with the potential to efficiently adsorb polycyclic aromatic hydrocarbons in water samples. |
| doi_str_mv | 10.1039/d4ay00799a |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_proquest_miscellaneous_3079171021</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3079171021</sourcerecordid><originalsourceid>FETCH-LOGICAL-c226t-ca815a2917a87d5707732cf9bb24b0caf584c198073f8f899cfaae8cf0ad1df63</originalsourceid><addsrcrecordid>eNpd0c9LwzAUB_AgitPpxbsS8CJCNWm6pjmOOZ0wcPjj4Kmk-bF1a5OZtMr-ezM3JwiBBPLh8d77AnCG0Q1GhN3KhK8QoozxPXCEaY9FLKVsf_dOUQccez9HKGUkxYegQzLGCErjI7B4VrX95BXkRkKpGiWa0hpoNVzOlLGVh83M2XY6CwC-TIbRaDIewFo1Myth60szhXUpnF3aoDy0bspNKaBRzZd1Cw95ONJbVyjTnIADzSuvTrd3F7zdD18Ho2j89PA46I8jEcdpEwme4R6PGaY8o7JHEaUkFpoVRZwUSHDdyxKBWYYo0ZkOkwjNucqERlxiqVPSBVebuktnP1rlm7wuvVBVxY0KTeYk7ApTjGIc6OU_OretM6G7oLIkQUnK1up6o8Kg3jul86Ura-5WOUb5OoL8Lum__0TQD_hiW7ItaiV39HfnAZxvgPNi9_uXIfkGq2SL0w</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3084404691</pqid></control><display><type>article</type><title>Removal and detection of phenols through an SPE-HPLC method using microporous organic networks as adsorbent</title><source>Royal Society Of Chemistry Journals 2008-</source><creator>Ali, Azam ; Sun, Huipeng ; Rizvi, Syed Faheem Askari ; Nana, Ding ; Zhang, Haixia</creator><creatorcontrib>Ali, Azam ; Sun, Huipeng ; Rizvi, Syed Faheem Askari ; Nana, Ding ; Zhang, Haixia</creatorcontrib><description>The design and development of a facile synthesis approach to construct novel materials for the rapid adsorption and removal of environmental pollutants are of significant interest. In this work, we report the rational design and facile synthesis of magnetic core-shell-based microporous organic networks, Fe
3
O
4
@MON-TBPT-TEB (TTMON, achieved by reacting 2,4,6-tris(
p
-bromophenyl) triazine and 1,3,5-triethynylbenzene) and Fe
3
O
4
@MON-TBPM-DEBP (TDMON, achieved by reacting tetrakis (4-bromophenyl) methane and 4-4′-diethynylbiphenyl). These MONs possessed excellent dispersity, electrostatic attraction as well as plenty of π-π and hydrophobic interaction sites enabled them to efficiently absorb targeted environmental pollutants. TTMON and TDMON exhibited excellent adsorption capacities of 440 and 510 mg g
−1
, respectively, at 25 °C for 2,4,6-trichlorophenol (TCP). TCP, 2,4-dichlorophenol (DCP), 2-naphthol (2-NT) and 4-nitrophenol (4-NP) from aqueous solution were treated by both MONs, followed by their analysis with high-performance liquid chromatography (HPLC). For TDMON, the proposed SPE-HPLC-UV method showed an LOD of 0.03 μg L
−1
, LOQ of 0.11 μg L
−1
, and a wide linear range of 1-1000 μg L
−1
for TCP. The adsorption kinetics, thermodynamics, isotherms, effect of pH and humic acid (HA), ionic strength, regeneration, and reusability of the MONs were also studied. The results revealed that the novel-designed MONs have potential applications as efficient adsorbents in sample pretreatment.
A rational design and facile synthesis approach were used for the construction of novel magnetically separating MONs with the potential to efficiently adsorb polycyclic aromatic hydrocarbons in water samples.</description><identifier>ISSN: 1759-9660</identifier><identifier>ISSN: 1759-9679</identifier><identifier>EISSN: 1759-9679</identifier><identifier>DOI: 10.1039/d4ay00799a</identifier><identifier>PMID: 38993062</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>2,4,6-Trichlorophenol ; Adsorbents ; Adsorption ; Aqueous solutions ; Electrostatic properties ; High performance liquid chromatography ; Humic acids ; Hydrophobicity ; Ionic strength ; Iron oxides ; Liquid chromatography ; Magnetic cores ; Nitrophenol ; p-Nitrophenol ; Phenols ; Pollutant removal ; Pollutants ; Synthesis ; Triazine ; Trichlorophenol ; Trichlorophenols</subject><ispartof>Analytical methods, 2024-07, Vol.16 (29), p.5112-5119</ispartof><rights>Copyright Royal Society of Chemistry 2024</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c226t-ca815a2917a87d5707732cf9bb24b0caf584c198073f8f899cfaae8cf0ad1df63</cites><orcidid>0000-0002-2965-3457 ; 0000-0002-8671-9168</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/38993062$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Ali, Azam</creatorcontrib><creatorcontrib>Sun, Huipeng</creatorcontrib><creatorcontrib>Rizvi, Syed Faheem Askari</creatorcontrib><creatorcontrib>Nana, Ding</creatorcontrib><creatorcontrib>Zhang, Haixia</creatorcontrib><title>Removal and detection of phenols through an SPE-HPLC method using microporous organic networks as adsorbent</title><title>Analytical methods</title><addtitle>Anal Methods</addtitle><description>The design and development of a facile synthesis approach to construct novel materials for the rapid adsorption and removal of environmental pollutants are of significant interest. In this work, we report the rational design and facile synthesis of magnetic core-shell-based microporous organic networks, Fe
3
O
4
@MON-TBPT-TEB (TTMON, achieved by reacting 2,4,6-tris(
p
-bromophenyl) triazine and 1,3,5-triethynylbenzene) and Fe
3
O
4
@MON-TBPM-DEBP (TDMON, achieved by reacting tetrakis (4-bromophenyl) methane and 4-4′-diethynylbiphenyl). These MONs possessed excellent dispersity, electrostatic attraction as well as plenty of π-π and hydrophobic interaction sites enabled them to efficiently absorb targeted environmental pollutants. TTMON and TDMON exhibited excellent adsorption capacities of 440 and 510 mg g
−1
, respectively, at 25 °C for 2,4,6-trichlorophenol (TCP). TCP, 2,4-dichlorophenol (DCP), 2-naphthol (2-NT) and 4-nitrophenol (4-NP) from aqueous solution were treated by both MONs, followed by their analysis with high-performance liquid chromatography (HPLC). For TDMON, the proposed SPE-HPLC-UV method showed an LOD of 0.03 μg L
−1
, LOQ of 0.11 μg L
−1
, and a wide linear range of 1-1000 μg L
−1
for TCP. The adsorption kinetics, thermodynamics, isotherms, effect of pH and humic acid (HA), ionic strength, regeneration, and reusability of the MONs were also studied. The results revealed that the novel-designed MONs have potential applications as efficient adsorbents in sample pretreatment.
A rational design and facile synthesis approach were used for the construction of novel magnetically separating MONs with the potential to efficiently adsorb polycyclic aromatic hydrocarbons in water samples.</description><subject>2,4,6-Trichlorophenol</subject><subject>Adsorbents</subject><subject>Adsorption</subject><subject>Aqueous solutions</subject><subject>Electrostatic properties</subject><subject>High performance liquid chromatography</subject><subject>Humic acids</subject><subject>Hydrophobicity</subject><subject>Ionic strength</subject><subject>Iron oxides</subject><subject>Liquid chromatography</subject><subject>Magnetic cores</subject><subject>Nitrophenol</subject><subject>p-Nitrophenol</subject><subject>Phenols</subject><subject>Pollutant removal</subject><subject>Pollutants</subject><subject>Synthesis</subject><subject>Triazine</subject><subject>Trichlorophenol</subject><subject>Trichlorophenols</subject><issn>1759-9660</issn><issn>1759-9679</issn><issn>1759-9679</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpd0c9LwzAUB_AgitPpxbsS8CJCNWm6pjmOOZ0wcPjj4Kmk-bF1a5OZtMr-ezM3JwiBBPLh8d77AnCG0Q1GhN3KhK8QoozxPXCEaY9FLKVsf_dOUQccez9HKGUkxYegQzLGCErjI7B4VrX95BXkRkKpGiWa0hpoNVzOlLGVh83M2XY6CwC-TIbRaDIewFo1Myth60szhXUpnF3aoDy0bspNKaBRzZd1Cw95ONJbVyjTnIADzSuvTrd3F7zdD18Ho2j89PA46I8jEcdpEwme4R6PGaY8o7JHEaUkFpoVRZwUSHDdyxKBWYYo0ZkOkwjNucqERlxiqVPSBVebuktnP1rlm7wuvVBVxY0KTeYk7ApTjGIc6OU_OretM6G7oLIkQUnK1up6o8Kg3jul86Ura-5WOUb5OoL8Lum__0TQD_hiW7ItaiV39HfnAZxvgPNi9_uXIfkGq2SL0w</recordid><startdate>20240725</startdate><enddate>20240725</enddate><creator>Ali, Azam</creator><creator>Sun, Huipeng</creator><creator>Rizvi, Syed Faheem Askari</creator><creator>Nana, Ding</creator><creator>Zhang, Haixia</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SE</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>H8G</scope><scope>JG9</scope><scope>L7M</scope><scope>P64</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-2965-3457</orcidid><orcidid>https://orcid.org/0000-0002-8671-9168</orcidid></search><sort><creationdate>20240725</creationdate><title>Removal and detection of phenols through an SPE-HPLC method using microporous organic networks as adsorbent</title><author>Ali, Azam ; Sun, Huipeng ; Rizvi, Syed Faheem Askari ; Nana, Ding ; Zhang, Haixia</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c226t-ca815a2917a87d5707732cf9bb24b0caf584c198073f8f899cfaae8cf0ad1df63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>2,4,6-Trichlorophenol</topic><topic>Adsorbents</topic><topic>Adsorption</topic><topic>Aqueous solutions</topic><topic>Electrostatic properties</topic><topic>High performance liquid chromatography</topic><topic>Humic acids</topic><topic>Hydrophobicity</topic><topic>Ionic strength</topic><topic>Iron oxides</topic><topic>Liquid chromatography</topic><topic>Magnetic cores</topic><topic>Nitrophenol</topic><topic>p-Nitrophenol</topic><topic>Phenols</topic><topic>Pollutant removal</topic><topic>Pollutants</topic><topic>Synthesis</topic><topic>Triazine</topic><topic>Trichlorophenol</topic><topic>Trichlorophenols</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ali, Azam</creatorcontrib><creatorcontrib>Sun, Huipeng</creatorcontrib><creatorcontrib>Rizvi, Syed Faheem Askari</creatorcontrib><creatorcontrib>Nana, Ding</creatorcontrib><creatorcontrib>Zhang, Haixia</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>MEDLINE - Academic</collection><jtitle>Analytical methods</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ali, Azam</au><au>Sun, Huipeng</au><au>Rizvi, Syed Faheem Askari</au><au>Nana, Ding</au><au>Zhang, Haixia</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Removal and detection of phenols through an SPE-HPLC method using microporous organic networks as adsorbent</atitle><jtitle>Analytical methods</jtitle><addtitle>Anal Methods</addtitle><date>2024-07-25</date><risdate>2024</risdate><volume>16</volume><issue>29</issue><spage>5112</spage><epage>5119</epage><pages>5112-5119</pages><issn>1759-9660</issn><issn>1759-9679</issn><eissn>1759-9679</eissn><abstract>The design and development of a facile synthesis approach to construct novel materials for the rapid adsorption and removal of environmental pollutants are of significant interest. In this work, we report the rational design and facile synthesis of magnetic core-shell-based microporous organic networks, Fe
3
O
4
@MON-TBPT-TEB (TTMON, achieved by reacting 2,4,6-tris(
p
-bromophenyl) triazine and 1,3,5-triethynylbenzene) and Fe
3
O
4
@MON-TBPM-DEBP (TDMON, achieved by reacting tetrakis (4-bromophenyl) methane and 4-4′-diethynylbiphenyl). These MONs possessed excellent dispersity, electrostatic attraction as well as plenty of π-π and hydrophobic interaction sites enabled them to efficiently absorb targeted environmental pollutants. TTMON and TDMON exhibited excellent adsorption capacities of 440 and 510 mg g
−1
, respectively, at 25 °C for 2,4,6-trichlorophenol (TCP). TCP, 2,4-dichlorophenol (DCP), 2-naphthol (2-NT) and 4-nitrophenol (4-NP) from aqueous solution were treated by both MONs, followed by their analysis with high-performance liquid chromatography (HPLC). For TDMON, the proposed SPE-HPLC-UV method showed an LOD of 0.03 μg L
−1
, LOQ of 0.11 μg L
−1
, and a wide linear range of 1-1000 μg L
−1
for TCP. The adsorption kinetics, thermodynamics, isotherms, effect of pH and humic acid (HA), ionic strength, regeneration, and reusability of the MONs were also studied. The results revealed that the novel-designed MONs have potential applications as efficient adsorbents in sample pretreatment.
A rational design and facile synthesis approach were used for the construction of novel magnetically separating MONs with the potential to efficiently adsorb polycyclic aromatic hydrocarbons in water samples.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>38993062</pmid><doi>10.1039/d4ay00799a</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-2965-3457</orcidid><orcidid>https://orcid.org/0000-0002-8671-9168</orcidid></addata></record> |
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| ispartof | Analytical methods, 2024-07, Vol.16 (29), p.5112-5119 |
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| language | eng |
| recordid | cdi_proquest_miscellaneous_3079171021 |
| source | Royal Society Of Chemistry Journals 2008- |
| subjects | 2,4,6-Trichlorophenol Adsorbents Adsorption Aqueous solutions Electrostatic properties High performance liquid chromatography Humic acids Hydrophobicity Ionic strength Iron oxides Liquid chromatography Magnetic cores Nitrophenol p-Nitrophenol Phenols Pollutant removal Pollutants Synthesis Triazine Trichlorophenol Trichlorophenols |
| title | Removal and detection of phenols through an SPE-HPLC method using microporous organic networks as adsorbent |
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