NaGeF5·2HF: the first quarternary phase in the H-Na-Ge-F system

NaGeF5·2HF: the first quarternary phase in the H-Na-Ge-F system

The structure of cis- or trans-bridged [GeF5]- anionic chains have been investigated [Mallouk et al. (1984). Inorg. Chem. 23, 3160-3166] showing the first crystal structures of μ-F-bridged pentafluorogermanates. Herein, we report the second crystal structure of trans-pentafluorogermanate anions pres...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Acta crystallographica. Section C, Structural chemistry Structural chemistry, 2024-08, Vol.80 (Pt 8), p.401
Hauptverfasser: Bockmair, Valentin, Hoch, Constantin, Schusterbauer, Irina, Kornath, Andreas J
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page
container_issue Pt 8
container_start_page 401
container_title Acta crystallographica. Section C, Structural chemistry
container_volume 80
creator Bockmair, Valentin
Hoch, Constantin
Schusterbauer, Irina
Kornath, Andreas J
description The structure of cis- or trans-bridged [GeF5]- anionic chains have been investigated [Mallouk et al. (1984). Inorg. Chem. 23, 3160-3166] showing the first crystal structures of μ-F-bridged pentafluorogermanates. Herein, we report the second crystal structure of trans-pentafluorogermanate anions present in the crystal structure of sodium trans-pentafluorogermanate(IV) bis(hydrogen fluoride), Na[GeF5]·2HF. The crystal structure [orthorhombic Pca21, a = 12.3786 (3), b = 7.2189 (2), c = 11.4969 (3) Å and Z = 8] is built up from infinite chains of trans-linked [GeF6]2- octahedra, extending along the b axis and spanning a network of pentagonal bipyramidal distorted Na-centred polyhedra. These [NaF7] polyhedra are linked in a trans-edge fashion via hydrogen fluoride molecules, in analogy to already known sodium hydrogen fluorides and potassium hydrogen fluorides.The structure of cis- or trans-bridged [GeF5]- anionic chains have been investigated [Mallouk et al. (1984). Inorg. Chem. 23, 3160-3166] showing the first crystal structures of μ-F-bridged pentafluorogermanates. Herein, we report the second crystal structure of trans-pentafluorogermanate anions present in the crystal structure of sodium trans-pentafluorogermanate(IV) bis(hydrogen fluoride), Na[GeF5]·2HF. The crystal structure [orthorhombic Pca21, a = 12.3786 (3), b = 7.2189 (2), c = 11.4969 (3) Å and Z = 8] is built up from infinite chains of trans-linked [GeF6]2- octahedra, extending along the b axis and spanning a network of pentagonal bipyramidal distorted Na-centred polyhedra. These [NaF7] polyhedra are linked in a trans-edge fashion via hydrogen fluoride molecules, in analogy to already known sodium hydrogen fluorides and potassium hydrogen fluorides.
doi_str_mv 10.1107/S2053229624006338
format Article
fullrecord <record><control><sourceid>proquest</sourceid><recordid>TN_cdi_proquest_miscellaneous_3077995113</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3077995113</sourcerecordid><originalsourceid>FETCH-proquest_miscellaneous_30779951133</originalsourceid><addsrcrecordid>eNqVirEKwjAURYMoWNQPcMvoEn1JrLFOglg7ddFdgrzSSm1rXjr4Ze5-mVQcXJ3O5dzD2FTCXEowi6OCUCsVrdQSYKX1useCTonO9X_2kE2IrgAgpQqNkQHbpvaAcfh6qiTecJ8jzwpHnt9b6zy6yroHb3JLyIvqcyciteKAIub0II-3MRtktiScfDlis3h_2iWicfW9RfLnW0EXLEtbYd3SWYMxURRKqfUf6RsEGkLi</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3077995113</pqid></control><display><type>article</type><title>NaGeF5·2HF: the first quarternary phase in the H-Na-Ge-F system</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Bockmair, Valentin ; Hoch, Constantin ; Schusterbauer, Irina ; Kornath, Andreas J</creator><creatorcontrib>Bockmair, Valentin ; Hoch, Constantin ; Schusterbauer, Irina ; Kornath, Andreas J</creatorcontrib><description>The structure of cis- or trans-bridged [GeF5]- anionic chains have been investigated [Mallouk et al. (1984). Inorg. Chem. 23, 3160-3166] showing the first crystal structures of μ-F-bridged pentafluorogermanates. Herein, we report the second crystal structure of trans-pentafluorogermanate anions present in the crystal structure of sodium trans-pentafluorogermanate(IV) bis(hydrogen fluoride), Na[GeF5]·2HF. The crystal structure [orthorhombic Pca21, a = 12.3786 (3), b = 7.2189 (2), c = 11.4969 (3) Å and Z = 8] is built up from infinite chains of trans-linked [GeF6]2- octahedra, extending along the b axis and spanning a network of pentagonal bipyramidal distorted Na-centred polyhedra. These [NaF7] polyhedra are linked in a trans-edge fashion via hydrogen fluoride molecules, in analogy to already known sodium hydrogen fluorides and potassium hydrogen fluorides.The structure of cis- or trans-bridged [GeF5]- anionic chains have been investigated [Mallouk et al. (1984). Inorg. Chem. 23, 3160-3166] showing the first crystal structures of μ-F-bridged pentafluorogermanates. Herein, we report the second crystal structure of trans-pentafluorogermanate anions present in the crystal structure of sodium trans-pentafluorogermanate(IV) bis(hydrogen fluoride), Na[GeF5]·2HF. The crystal structure [orthorhombic Pca21, a = 12.3786 (3), b = 7.2189 (2), c = 11.4969 (3) Å and Z = 8] is built up from infinite chains of trans-linked [GeF6]2- octahedra, extending along the b axis and spanning a network of pentagonal bipyramidal distorted Na-centred polyhedra. These [NaF7] polyhedra are linked in a trans-edge fashion via hydrogen fluoride molecules, in analogy to already known sodium hydrogen fluorides and potassium hydrogen fluorides.</description><identifier>ISSN: 2053-2296</identifier><identifier>EISSN: 2053-2296</identifier><identifier>DOI: 10.1107/S2053229624006338</identifier><language>eng</language><ispartof>Acta crystallographica. Section C, Structural chemistry, 2024-08, Vol.80 (Pt 8), p.401</ispartof><rights>open access.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,778,782,27911,27912</link.rule.ids></links><search><creatorcontrib>Bockmair, Valentin</creatorcontrib><creatorcontrib>Hoch, Constantin</creatorcontrib><creatorcontrib>Schusterbauer, Irina</creatorcontrib><creatorcontrib>Kornath, Andreas J</creatorcontrib><title>NaGeF5·2HF: the first quarternary phase in the H-Na-Ge-F system</title><title>Acta crystallographica. Section C, Structural chemistry</title><description>The structure of cis- or trans-bridged [GeF5]- anionic chains have been investigated [Mallouk et al. (1984). Inorg. Chem. 23, 3160-3166] showing the first crystal structures of μ-F-bridged pentafluorogermanates. Herein, we report the second crystal structure of trans-pentafluorogermanate anions present in the crystal structure of sodium trans-pentafluorogermanate(IV) bis(hydrogen fluoride), Na[GeF5]·2HF. The crystal structure [orthorhombic Pca21, a = 12.3786 (3), b = 7.2189 (2), c = 11.4969 (3) Å and Z = 8] is built up from infinite chains of trans-linked [GeF6]2- octahedra, extending along the b axis and spanning a network of pentagonal bipyramidal distorted Na-centred polyhedra. These [NaF7] polyhedra are linked in a trans-edge fashion via hydrogen fluoride molecules, in analogy to already known sodium hydrogen fluorides and potassium hydrogen fluorides.The structure of cis- or trans-bridged [GeF5]- anionic chains have been investigated [Mallouk et al. (1984). Inorg. Chem. 23, 3160-3166] showing the first crystal structures of μ-F-bridged pentafluorogermanates. Herein, we report the second crystal structure of trans-pentafluorogermanate anions present in the crystal structure of sodium trans-pentafluorogermanate(IV) bis(hydrogen fluoride), Na[GeF5]·2HF. The crystal structure [orthorhombic Pca21, a = 12.3786 (3), b = 7.2189 (2), c = 11.4969 (3) Å and Z = 8] is built up from infinite chains of trans-linked [GeF6]2- octahedra, extending along the b axis and spanning a network of pentagonal bipyramidal distorted Na-centred polyhedra. These [NaF7] polyhedra are linked in a trans-edge fashion via hydrogen fluoride molecules, in analogy to already known sodium hydrogen fluorides and potassium hydrogen fluorides.</description><issn>2053-2296</issn><issn>2053-2296</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNqVirEKwjAURYMoWNQPcMvoEn1JrLFOglg7ddFdgrzSSm1rXjr4Ze5-mVQcXJ3O5dzD2FTCXEowi6OCUCsVrdQSYKX1useCTonO9X_2kE2IrgAgpQqNkQHbpvaAcfh6qiTecJ8jzwpHnt9b6zy6yroHb3JLyIvqcyciteKAIub0II-3MRtktiScfDlis3h_2iWicfW9RfLnW0EXLEtbYd3SWYMxURRKqfUf6RsEGkLi</recordid><startdate>20240801</startdate><enddate>20240801</enddate><creator>Bockmair, Valentin</creator><creator>Hoch, Constantin</creator><creator>Schusterbauer, Irina</creator><creator>Kornath, Andreas J</creator><scope>7X8</scope></search><sort><creationdate>20240801</creationdate><title>NaGeF5·2HF: the first quarternary phase in the H-Na-Ge-F system</title><author>Bockmair, Valentin ; Hoch, Constantin ; Schusterbauer, Irina ; Kornath, Andreas J</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-proquest_miscellaneous_30779951133</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bockmair, Valentin</creatorcontrib><creatorcontrib>Hoch, Constantin</creatorcontrib><creatorcontrib>Schusterbauer, Irina</creatorcontrib><creatorcontrib>Kornath, Andreas J</creatorcontrib><collection>MEDLINE - Academic</collection><jtitle>Acta crystallographica. Section C, Structural chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bockmair, Valentin</au><au>Hoch, Constantin</au><au>Schusterbauer, Irina</au><au>Kornath, Andreas J</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>NaGeF5·2HF: the first quarternary phase in the H-Na-Ge-F system</atitle><jtitle>Acta crystallographica. Section C, Structural chemistry</jtitle><date>2024-08-01</date><risdate>2024</risdate><volume>80</volume><issue>Pt 8</issue><spage>401</spage><pages>401-</pages><issn>2053-2296</issn><eissn>2053-2296</eissn><abstract>The structure of cis- or trans-bridged [GeF5]- anionic chains have been investigated [Mallouk et al. (1984). Inorg. Chem. 23, 3160-3166] showing the first crystal structures of μ-F-bridged pentafluorogermanates. Herein, we report the second crystal structure of trans-pentafluorogermanate anions present in the crystal structure of sodium trans-pentafluorogermanate(IV) bis(hydrogen fluoride), Na[GeF5]·2HF. The crystal structure [orthorhombic Pca21, a = 12.3786 (3), b = 7.2189 (2), c = 11.4969 (3) Å and Z = 8] is built up from infinite chains of trans-linked [GeF6]2- octahedra, extending along the b axis and spanning a network of pentagonal bipyramidal distorted Na-centred polyhedra. These [NaF7] polyhedra are linked in a trans-edge fashion via hydrogen fluoride molecules, in analogy to already known sodium hydrogen fluorides and potassium hydrogen fluorides.The structure of cis- or trans-bridged [GeF5]- anionic chains have been investigated [Mallouk et al. (1984). Inorg. Chem. 23, 3160-3166] showing the first crystal structures of μ-F-bridged pentafluorogermanates. Herein, we report the second crystal structure of trans-pentafluorogermanate anions present in the crystal structure of sodium trans-pentafluorogermanate(IV) bis(hydrogen fluoride), Na[GeF5]·2HF. The crystal structure [orthorhombic Pca21, a = 12.3786 (3), b = 7.2189 (2), c = 11.4969 (3) Å and Z = 8] is built up from infinite chains of trans-linked [GeF6]2- octahedra, extending along the b axis and spanning a network of pentagonal bipyramidal distorted Na-centred polyhedra. These [NaF7] polyhedra are linked in a trans-edge fashion via hydrogen fluoride molecules, in analogy to already known sodium hydrogen fluorides and potassium hydrogen fluorides.</abstract><doi>10.1107/S2053229624006338</doi></addata></record>
fulltext fulltext
identifier ISSN: 2053-2296
ispartof Acta crystallographica. Section C, Structural chemistry, 2024-08, Vol.80 (Pt 8), p.401
issn 2053-2296
2053-2296
language eng
recordid cdi_proquest_miscellaneous_3077995113
source Wiley Online Library Journals Frontfile Complete
title NaGeF5·2HF: the first quarternary phase in the H-Na-Ge-F system
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-16T05%3A51%3A13IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=NaGeF5%C2%B72HF:%20the%20first%20quarternary%20phase%20in%20the%20H-Na-Ge-F%20system&rft.jtitle=Acta%20crystallographica.%20Section%20C,%20Structural%20chemistry&rft.au=Bockmair,%20Valentin&rft.date=2024-08-01&rft.volume=80&rft.issue=Pt%208&rft.spage=401&rft.pages=401-&rft.issn=2053-2296&rft.eissn=2053-2296&rft_id=info:doi/10.1107/S2053229624006338&rft_dat=%3Cproquest%3E3077995113%3C/proquest%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=3077995113&rft_id=info:pmid/&rfr_iscdi=true