Using Coordination Chemistry to Control “Click” Reactions: The Selective Formation of Asymmetrically Ligated Polyoxometalates

The Cu­(I)-catalyzed azide–alkyne cycloaddition reaction between (NBu4)2[V6O13((OCH2)3CCH2N3)2] and 3-ethynylpyridine led to the formation of products capable of forming poorly soluble coordination compounds with transition metal ions such as Cu­(I) and Zn­(II). The formation of these poorly soluble...

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Veröffentlicht in:	Inorganic chemistry 2024-07, Vol.63 (29), p.13785-13792
Hauptverfasser:	Petrovskii, Stanislav K., Moors, Marco, Fuhrmann, Daniel, Lorenz, Jonas, Monakhov, Kirill Yu
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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