ISODISTROTLaMTeO6 (M = Ga3+ and Mn3+): the critical role of electronic configuration and cation ordering in crystal structures

In this work, PbSb2O6-type oxides LaMTeO6 (M = Ga3+ and Mn3+) were synthesized and structurally characterized by Rietveld refinements against high-resolution X-ray powder diffraction data. The Ga3+/Te6+ partial ordering within the honeycomb-like two-dimensional [GaTeO6]3− anionic layer leads to the...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2024-07, Vol.53 (28), p.11830-11835
Hauptverfasser:	Tang, Shunjie, Yuxuan Qi, Jiang, Pengfei, Yang, Tao
Format:	Artikel
Sprache:	eng
Schlagworte:	Antiferromagnetism Cations Configurations Crystal structure Distortion Electron spin Jahn-Teller effect Lattice parameters Magnetic transitions Physical properties Superstructures Symmetry X ray powder diffraction
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