Water Microdroplets Surrounded by Alcohol Vapor Cause Spontaneous Oxidation of Alcohols to Organic Peroxides

Using real-time mass spectrometric (MS) monitoring, we demonstrate one-step, catalyst-free spontaneous oxidation of various alcohols (ROH) to key reactive intermediates for the formation of ROO– compounds on the surface of water microdroplets surrounded by alcohol vapor, carried out under ambient co...

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Veröffentlicht in:	Journal of the American Chemical Society 2024-07, Vol.146 (27), p.18498-18503
Hauptverfasser:	Mofidfar, Mohammad, Mehrgardi, Masoud A., Zare, Richard N.
Format:	Artikel
Sprache:	eng
Schlagworte:	alcohols electron transfer hydrogen liquid-air interface mass spectrometry oxidation reaction mechanisms solvation vapors
Online-Zugang:	Volltext
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