Long‐Term Comparisons of Photoluminescence Affected by Organic Cations of Formamidinium and Methylammonium in Monophasic Lead Iodide Perovskite Quantum Dots

This study compared the photoluminescence (PL) stabilities of formamidinium (FA) and methylammonium (MA) in lead iodide perovskite quantum dots (QDs). To exclude other factors, such as size and purity, that may affect stability, MAPbI3 and FAPbI3 QDs with nearly identical sizes (~10.0 nm) were synthesized by controlling the ligand concentration and synthesis temperature. Transmission electron microscopy images and X‐ray diffraction patterns confirmed homogeneous single‐phase perovskite structures. Additionally, the bandgaps and sizes of the synthesized QDs closely matched those of the infinite quantum well model, which guaranteed that the photostability was solely caused by the different organic molecules in the two QDs. We analyzed the PL peak centers and full‐width at half maximum of the QDs for 32 days. The enhanced stability of FAPbI3 was found to be caused by the nearly zero redshift (1.615 eV) of its PL peak, in contrast to the redshift (1.685→1.670 eV) of MAPbI3. Highly pure single‐phase formamidinium lead iodide (FAPbI3) and methyl ammonium lead iodide (MAPbI3) perovskite quantum dots were synthesized with nearly identical diameters of ~10±1 nm. Comparison of long‐term photoluminescence (PL) for 32 days showed that the PL peak center of FAPbI3 rarely shifted compared to MAPbI3, indicating higher stability to ambient condition.