Enhanced Thermoelectric Performance of Nanostructured 2D Tin Telluride

A lot of experimental studies are conducted on theoretically predicted thermoelectric 2D materials. Such materials can pave the way for charging ultra‐thin electronic devices, self‐charging wearable devices, and medical implants. This study systematically explores the thermoelectric attributes of bulk and 2D nanostructured Tin Telluride (SnTe), employing experimental investigations and theoretical analyses based on semiclassical Boltzmann transport theory. The bulk SnTe is synthesized through flame melting, while the 2D SnTe is produced via liquid phase exfoliation. The comprehensive assessment of thermoelectric properties integrated experimental measurements utilizing a Physical Property Measurement System and theoretical calculations from the BoltzTraP code. Experimental thermoelectric studies show a high ZT of 0.17 for 2D SnTe when compared to bulk (0.005) at room temperature. This rise in ZT is due to the high Seebeck coefficient and low thermal conductivity of nanostructured 2D SnTe. Density functional theory (DFT) studies reveal the contribution of the density of states (DOS) and energy bandgap in enhancing the Seebeck coefficient and lowering thermal conductivity by interface scattering. Bulk and 2D SnTe are synthesized using flame melting and liquid phase exfoliation. Nanostructured 2D SnTe shows a Seebeck coefficient of 280 µV K−1, four times higher than bulk SnTe. This is due to increased DOS and bandgap. Enhanced interface scattering reduces thermal conductivity, yielding a high ZT of 0.17, promising wearable self‐charging devices.