Reduction of (pddi)Cr reveals redox noninnocence via C-C bond formation amidst competing electrophilicity: (cpta)CrMen- (n = 0, 1) and (pta)Cr

Reversible cyclopropane formation is probed as a means of redox noninnocence in diimine/diamide chelates via reduction and complex anion formation. Competition from imine attack renders complications in the latter approach, and electrochemical measurements with calculational support provide the rati...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2024-06, Vol.60 (53), p.6785
Hauptverfasser:	D'Arpino, Alexander A, Wolczanski, Peter T, MacMillan, Samantha N, Cundari, Thomas R, Krumov, Mihail R
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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