Activation of carbon disulfide by a hypersilyl germylene
In this work, the insertion of CS 2 into the Ge-Si bond of PhC(N t Bu) 2 Ge-Si(SiMe 3 ) 3 ( 1 ) has been investigated, resulting in the formation of PhC(N t Bu) 2 Ge-C(&z.dbd;S)-S-Si(SiMe 3 ) 3 ( 2 ). Interestingly, the addition of NHC to 2 allows the release of NHC·CS 2 with concomitant regener...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2024-07, Vol.53 (26), p.1814-1818 |
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| container_issue | 26 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 53 |
| creator | Ajithkumar, V. S Khilari, Nripen Ghanwat, Pratiksha B Venugopal, Geethu Koley, Debasis Sen, Sakya S |
| description | In this work, the insertion of CS
2
into the Ge-Si bond of PhC(N
t
Bu)
2
Ge-Si(SiMe
3
)
3
(
1
) has been investigated, resulting in the formation of PhC(N
t
Bu)
2
Ge-C(&z.dbd;S)-S-Si(SiMe
3
)
3
(
2
). Interestingly, the addition of NHC to
2
allows the release of NHC·CS
2
with concomitant regeneration of
1
. Addition of another equivalent of
1
or an analogous hypersilyl silylene, [PhC(N
t
Bu)
2
Si-Si(SiMe
3
)
3
], to
2
led to the formation of compounds with a Ge&z.dbd;S (
3
) or a Si&z.dbd;S (
4
) bond.
In this work, the insertion of CS
2
into the Ge-Si bond of PhC(N
t
Bu)
2
Ge-Si(SiMe
3
)
3
(
1
) has been investigated, resulting in the formation of PhC(N
t
Bu)
2
Ge-C(&z.dbd;S)-S-Si(SiMe
3
)
3
(
2
). |
| doi_str_mv | 10.1039/d4dt01573h |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_rsc_p</sourceid><recordid>TN_cdi_proquest_miscellaneous_3066790601</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3074298372</sourcerecordid><originalsourceid>FETCH-LOGICAL-c296t-c51211baba2d6f194ca8f5f10da1eeb9f40dfb0aa944f266d3e006ce04e574103</originalsourceid><addsrcrecordid>eNpd0UtLw0AQB_BFFFurF-9KwIsI0dlHNtljadUKBS_1HDb7sCl51N1EyLd3tbWCpx3YH8PMfxC6xHCPgYoHzXQHOEnp-giNMUvTWBDKjg814SN05v0GgBBIyCka0SxLRArZGGVT1ZWfsivbJmptpKQrQqVL31e21CYqhkhG62FrnC-roYrejauHyjTmHJ1YWXlzsX8n6O3pcTVbxMvX55fZdBkrIngXqwQTjAtZSKK5xYIpmdnEYtASG1MIy0DbAqQUjFnCuaYGgCsDzCQpC-tN0O2u79a1H73xXV6XXpmqko1pe59T4DwVwAEHevOPbtreNWG6oFJGREZTEtTdTinXeu-MzbeurKUbcgz5d575nM1XP3kuAr7et-yL2ugD_Q0wgKsdcF4dfv8OQr8Ai_V5GQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3074298372</pqid></control><display><type>article</type><title>Activation of carbon disulfide by a hypersilyl germylene</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Ajithkumar, V. S ; Khilari, Nripen ; Ghanwat, Pratiksha B ; Venugopal, Geethu ; Koley, Debasis ; Sen, Sakya S</creator><creatorcontrib>Ajithkumar, V. S ; Khilari, Nripen ; Ghanwat, Pratiksha B ; Venugopal, Geethu ; Koley, Debasis ; Sen, Sakya S</creatorcontrib><description>In this work, the insertion of CS
2
into the Ge-Si bond of PhC(N
t
Bu)
2
Ge-Si(SiMe
3
)
3
(
1
) has been investigated, resulting in the formation of PhC(N
t
Bu)
2
Ge-C(&z.dbd;S)-S-Si(SiMe
3
)
3
(
2
). Interestingly, the addition of NHC to
2
allows the release of NHC·CS
2
with concomitant regeneration of
1
. Addition of another equivalent of
1
or an analogous hypersilyl silylene, [PhC(N
t
Bu)
2
Si-Si(SiMe
3
)
3
], to
2
led to the formation of compounds with a Ge&z.dbd;S (
3
) or a Si&z.dbd;S (
4
) bond.
In this work, the insertion of CS
2
into the Ge-Si bond of PhC(N
t
Bu)
2
Ge-Si(SiMe
3
)
3
(
1
) has been investigated, resulting in the formation of PhC(N
t
Bu)
2
Ge-C(&z.dbd;S)-S-Si(SiMe
3
)
3
(
2
).</description><identifier>ISSN: 1477-9226</identifier><identifier>ISSN: 1477-9234</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/d4dt01573h</identifier><identifier>PMID: 38859708</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Carbon disulfide ; Germanium ; Silicon</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2024-07, Vol.53 (26), p.1814-1818</ispartof><rights>Copyright Royal Society of Chemistry 2024</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c296t-c51211baba2d6f194ca8f5f10da1eeb9f40dfb0aa944f266d3e006ce04e574103</cites><orcidid>0000-0002-4955-5408 ; 0000-0002-7912-3972 ; 0009-0009-9686-7605</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/38859708$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Ajithkumar, V. S</creatorcontrib><creatorcontrib>Khilari, Nripen</creatorcontrib><creatorcontrib>Ghanwat, Pratiksha B</creatorcontrib><creatorcontrib>Venugopal, Geethu</creatorcontrib><creatorcontrib>Koley, Debasis</creatorcontrib><creatorcontrib>Sen, Sakya S</creatorcontrib><title>Activation of carbon disulfide by a hypersilyl germylene</title><title>Dalton transactions : an international journal of inorganic chemistry</title><addtitle>Dalton Trans</addtitle><description>In this work, the insertion of CS
2
into the Ge-Si bond of PhC(N
t
Bu)
2
Ge-Si(SiMe
3
)
3
(
1
) has been investigated, resulting in the formation of PhC(N
t
Bu)
2
Ge-C(&z.dbd;S)-S-Si(SiMe
3
)
3
(
2
). Interestingly, the addition of NHC to
2
allows the release of NHC·CS
2
with concomitant regeneration of
1
. Addition of another equivalent of
1
or an analogous hypersilyl silylene, [PhC(N
t
Bu)
2
Si-Si(SiMe
3
)
3
], to
2
led to the formation of compounds with a Ge&z.dbd;S (
3
) or a Si&z.dbd;S (
4
) bond.
In this work, the insertion of CS
2
into the Ge-Si bond of PhC(N
t
Bu)
2
Ge-Si(SiMe
3
)
3
(
1
) has been investigated, resulting in the formation of PhC(N
t
Bu)
2
Ge-C(&z.dbd;S)-S-Si(SiMe
3
)
3
(
2
).</description><subject>Carbon disulfide</subject><subject>Germanium</subject><subject>Silicon</subject><issn>1477-9226</issn><issn>1477-9234</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpd0UtLw0AQB_BFFFurF-9KwIsI0dlHNtljadUKBS_1HDb7sCl51N1EyLd3tbWCpx3YH8PMfxC6xHCPgYoHzXQHOEnp-giNMUvTWBDKjg814SN05v0GgBBIyCka0SxLRArZGGVT1ZWfsivbJmptpKQrQqVL31e21CYqhkhG62FrnC-roYrejauHyjTmHJ1YWXlzsX8n6O3pcTVbxMvX55fZdBkrIngXqwQTjAtZSKK5xYIpmdnEYtASG1MIy0DbAqQUjFnCuaYGgCsDzCQpC-tN0O2u79a1H73xXV6XXpmqko1pe59T4DwVwAEHevOPbtreNWG6oFJGREZTEtTdTinXeu-MzbeurKUbcgz5d575nM1XP3kuAr7et-yL2ugD_Q0wgKsdcF4dfv8OQr8Ai_V5GQ</recordid><startdate>20240702</startdate><enddate>20240702</enddate><creator>Ajithkumar, V. S</creator><creator>Khilari, Nripen</creator><creator>Ghanwat, Pratiksha B</creator><creator>Venugopal, Geethu</creator><creator>Koley, Debasis</creator><creator>Sen, Sakya S</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-4955-5408</orcidid><orcidid>https://orcid.org/0000-0002-7912-3972</orcidid><orcidid>https://orcid.org/0009-0009-9686-7605</orcidid></search><sort><creationdate>20240702</creationdate><title>Activation of carbon disulfide by a hypersilyl germylene</title><author>Ajithkumar, V. S ; Khilari, Nripen ; Ghanwat, Pratiksha B ; Venugopal, Geethu ; Koley, Debasis ; Sen, Sakya S</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c296t-c51211baba2d6f194ca8f5f10da1eeb9f40dfb0aa944f266d3e006ce04e574103</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Carbon disulfide</topic><topic>Germanium</topic><topic>Silicon</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ajithkumar, V. S</creatorcontrib><creatorcontrib>Khilari, Nripen</creatorcontrib><creatorcontrib>Ghanwat, Pratiksha B</creatorcontrib><creatorcontrib>Venugopal, Geethu</creatorcontrib><creatorcontrib>Koley, Debasis</creatorcontrib><creatorcontrib>Sen, Sakya S</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ajithkumar, V. S</au><au>Khilari, Nripen</au><au>Ghanwat, Pratiksha B</au><au>Venugopal, Geethu</au><au>Koley, Debasis</au><au>Sen, Sakya S</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Activation of carbon disulfide by a hypersilyl germylene</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2024-07-02</date><risdate>2024</risdate><volume>53</volume><issue>26</issue><spage>1814</spage><epage>1818</epage><pages>1814-1818</pages><issn>1477-9226</issn><issn>1477-9234</issn><eissn>1477-9234</eissn><abstract>In this work, the insertion of CS
2
into the Ge-Si bond of PhC(N
t
Bu)
2
Ge-Si(SiMe
3
)
3
(
1
) has been investigated, resulting in the formation of PhC(N
t
Bu)
2
Ge-C(&z.dbd;S)-S-Si(SiMe
3
)
3
(
2
). Interestingly, the addition of NHC to
2
allows the release of NHC·CS
2
with concomitant regeneration of
1
. Addition of another equivalent of
1
or an analogous hypersilyl silylene, [PhC(N
t
Bu)
2
Si-Si(SiMe
3
)
3
], to
2
led to the formation of compounds with a Ge&z.dbd;S (
3
) or a Si&z.dbd;S (
4
) bond.
In this work, the insertion of CS
2
into the Ge-Si bond of PhC(N
t
Bu)
2
Ge-Si(SiMe
3
)
3
(
1
) has been investigated, resulting in the formation of PhC(N
t
Bu)
2
Ge-C(&z.dbd;S)-S-Si(SiMe
3
)
3
(
2
).</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>38859708</pmid><doi>10.1039/d4dt01573h</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0002-4955-5408</orcidid><orcidid>https://orcid.org/0000-0002-7912-3972</orcidid><orcidid>https://orcid.org/0009-0009-9686-7605</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2024-07, Vol.53 (26), p.1814-1818 |
| issn | 1477-9226 1477-9234 1477-9234 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_3066790601 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Carbon disulfide Germanium Silicon |
| title | Activation of carbon disulfide by a hypersilyl germylene |
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