Efficient one-pot transformation of furfural to pentanediol over Cu-modified cobalt-based catalysts
[Display omitted] •One-pot conversion of furfural to 1,5-pentanediol was achieved.•High yield 1,5-pentanediol (53.4%) was obtained over 5Cu-30Co/CeO2 catalyst.•Cu-Co metal synergy resulted in elevated selectivity for 1,5-pentanediol. Pentanediols are substances with significant market potential as t...
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Veröffentlicht in: | Bioresource technology 2024-07, Vol.403, p.130858-130858, Article 130858 |
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creator | Wang, Feng Zhao, Kangyu Xu, Qiong Yin, Dulin Liu, Xianxiang |
description | [Display omitted]
•One-pot conversion of furfural to 1,5-pentanediol was achieved.•High yield 1,5-pentanediol (53.4%) was obtained over 5Cu-30Co/CeO2 catalyst.•Cu-Co metal synergy resulted in elevated selectivity for 1,5-pentanediol.
Pentanediols are substances with significant market potential as the key monomers for advanced polymeric materials. In this study, we successfully achieved directly hydrogenolysis of biomass-based furfural to 1,5-pentanediol with a remarkable yield of 53.4 % using Cu-modified cobalt supported on cerium dioxide catalysts. Through comprehensive characterization techniques, including H2-TPR, NH3-TPD, XPS, EPR and Raman analysis, the study revealed that the introduction of Cu altered the dispersion of Co species, attenuated the interaction between Co species and cerium dioxide, enhanced its reduction extent, and fostered the formation of plentiful cobalt oxide species and oxygen vacancies on the catalyst’s surface. The cooperative influence of Cu and Co heightened the selectivity of the hydrogenolysis reaction. This work provides a novel strategy for the development of greener and more efficient catalytic processes based on non-precious metals that for the selective conversion of biomass-derived furfural to high-value pentanediols. |
doi_str_mv | 10.1016/j.biortech.2024.130858 |
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•One-pot conversion of furfural to 1,5-pentanediol was achieved.•High yield 1,5-pentanediol (53.4%) was obtained over 5Cu-30Co/CeO2 catalyst.•Cu-Co metal synergy resulted in elevated selectivity for 1,5-pentanediol.
Pentanediols are substances with significant market potential as the key monomers for advanced polymeric materials. In this study, we successfully achieved directly hydrogenolysis of biomass-based furfural to 1,5-pentanediol with a remarkable yield of 53.4 % using Cu-modified cobalt supported on cerium dioxide catalysts. Through comprehensive characterization techniques, including H2-TPR, NH3-TPD, XPS, EPR and Raman analysis, the study revealed that the introduction of Cu altered the dispersion of Co species, attenuated the interaction between Co species and cerium dioxide, enhanced its reduction extent, and fostered the formation of plentiful cobalt oxide species and oxygen vacancies on the catalyst’s surface. The cooperative influence of Cu and Co heightened the selectivity of the hydrogenolysis reaction. This work provides a novel strategy for the development of greener and more efficient catalytic processes based on non-precious metals that for the selective conversion of biomass-derived furfural to high-value pentanediols.</description><identifier>ISSN: 0960-8524</identifier><identifier>EISSN: 1873-2976</identifier><identifier>DOI: 10.1016/j.biortech.2024.130858</identifier><identifier>PMID: 38777229</identifier><language>eng</language><publisher>England: Elsevier Ltd</publisher><subject>Biomass ; Catalysis ; Cerium - chemistry ; Cobalt - chemistry ; Copper - chemistry ; Furaldehyde - chemistry ; Furfural ; Glycols - chemistry ; Hydrogenolysis ; Pentanediol ; Ring opening</subject><ispartof>Bioresource technology, 2024-07, Vol.403, p.130858-130858, Article 130858</ispartof><rights>2024 Elsevier Ltd</rights><rights>Copyright © 2024 Elsevier Ltd. All rights reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c315t-20982c51f12bd0d48190d0125a972c8fa50321c60ef9f54a3f07653a97899c423</cites><orcidid>0000-0001-5549-6339</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.biortech.2024.130858$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/38777229$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Wang, Feng</creatorcontrib><creatorcontrib>Zhao, Kangyu</creatorcontrib><creatorcontrib>Xu, Qiong</creatorcontrib><creatorcontrib>Yin, Dulin</creatorcontrib><creatorcontrib>Liu, Xianxiang</creatorcontrib><title>Efficient one-pot transformation of furfural to pentanediol over Cu-modified cobalt-based catalysts</title><title>Bioresource technology</title><addtitle>Bioresour Technol</addtitle><description>[Display omitted]
•One-pot conversion of furfural to 1,5-pentanediol was achieved.•High yield 1,5-pentanediol (53.4%) was obtained over 5Cu-30Co/CeO2 catalyst.•Cu-Co metal synergy resulted in elevated selectivity for 1,5-pentanediol.
Pentanediols are substances with significant market potential as the key monomers for advanced polymeric materials. In this study, we successfully achieved directly hydrogenolysis of biomass-based furfural to 1,5-pentanediol with a remarkable yield of 53.4 % using Cu-modified cobalt supported on cerium dioxide catalysts. Through comprehensive characterization techniques, including H2-TPR, NH3-TPD, XPS, EPR and Raman analysis, the study revealed that the introduction of Cu altered the dispersion of Co species, attenuated the interaction between Co species and cerium dioxide, enhanced its reduction extent, and fostered the formation of plentiful cobalt oxide species and oxygen vacancies on the catalyst’s surface. The cooperative influence of Cu and Co heightened the selectivity of the hydrogenolysis reaction. This work provides a novel strategy for the development of greener and more efficient catalytic processes based on non-precious metals that for the selective conversion of biomass-derived furfural to high-value pentanediols.</description><subject>Biomass</subject><subject>Catalysis</subject><subject>Cerium - chemistry</subject><subject>Cobalt - chemistry</subject><subject>Copper - chemistry</subject><subject>Furaldehyde - chemistry</subject><subject>Furfural</subject><subject>Glycols - chemistry</subject><subject>Hydrogenolysis</subject><subject>Pentanediol</subject><subject>Ring opening</subject><issn>0960-8524</issn><issn>1873-2976</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkMFOJCEQQMnGzTrO7i9MOHrpsYCmgZtmorsmJl70TGgasky6mxFoE_9eJqNeTSohlXpFVT2ENgS2BEh3td_2Iabi7P8tBdpuCQPJ5Q-0IlKwhirRnaEVqA4ayWl7ji5y3gMAI4L-QudMCiEoVStkb70PNri54Di75hALLsnM2cc0mRLijKPHfkk1zIhLxIeKmtkNIY44vrqEd0szxSH44AZsY2_G0vQmHxNTzPiWS_6NfnozZvfn412j57vbp92_5uHx7_3u5qGxjPDSUFCSWk48of0AQyuJggEI5UYJaqU3HBgltgPnleetYR5Ex1mtSqVsS9kaXZ7-PaT4srhc9BSydeNY941L1gy4olx2ICranVCbYs7JeX1IYTLpTRPQR8F6rz8F66NgfRJcGzcfM5Z-csNX26fRClyfAFcvfQ0u6XzUa6ux5GzRQwzfzXgHCcKQHw</recordid><startdate>202407</startdate><enddate>202407</enddate><creator>Wang, Feng</creator><creator>Zhao, Kangyu</creator><creator>Xu, Qiong</creator><creator>Yin, Dulin</creator><creator>Liu, Xianxiang</creator><general>Elsevier Ltd</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-5549-6339</orcidid></search><sort><creationdate>202407</creationdate><title>Efficient one-pot transformation of furfural to pentanediol over Cu-modified cobalt-based catalysts</title><author>Wang, Feng ; Zhao, Kangyu ; Xu, Qiong ; Yin, Dulin ; Liu, Xianxiang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c315t-20982c51f12bd0d48190d0125a972c8fa50321c60ef9f54a3f07653a97899c423</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Biomass</topic><topic>Catalysis</topic><topic>Cerium - chemistry</topic><topic>Cobalt - chemistry</topic><topic>Copper - chemistry</topic><topic>Furaldehyde - chemistry</topic><topic>Furfural</topic><topic>Glycols - chemistry</topic><topic>Hydrogenolysis</topic><topic>Pentanediol</topic><topic>Ring opening</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Feng</creatorcontrib><creatorcontrib>Zhao, Kangyu</creatorcontrib><creatorcontrib>Xu, Qiong</creatorcontrib><creatorcontrib>Yin, Dulin</creatorcontrib><creatorcontrib>Liu, Xianxiang</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Bioresource technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Feng</au><au>Zhao, Kangyu</au><au>Xu, Qiong</au><au>Yin, Dulin</au><au>Liu, Xianxiang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Efficient one-pot transformation of furfural to pentanediol over Cu-modified cobalt-based catalysts</atitle><jtitle>Bioresource technology</jtitle><addtitle>Bioresour Technol</addtitle><date>2024-07</date><risdate>2024</risdate><volume>403</volume><spage>130858</spage><epage>130858</epage><pages>130858-130858</pages><artnum>130858</artnum><issn>0960-8524</issn><eissn>1873-2976</eissn><abstract>[Display omitted]
•One-pot conversion of furfural to 1,5-pentanediol was achieved.•High yield 1,5-pentanediol (53.4%) was obtained over 5Cu-30Co/CeO2 catalyst.•Cu-Co metal synergy resulted in elevated selectivity for 1,5-pentanediol.
Pentanediols are substances with significant market potential as the key monomers for advanced polymeric materials. In this study, we successfully achieved directly hydrogenolysis of biomass-based furfural to 1,5-pentanediol with a remarkable yield of 53.4 % using Cu-modified cobalt supported on cerium dioxide catalysts. Through comprehensive characterization techniques, including H2-TPR, NH3-TPD, XPS, EPR and Raman analysis, the study revealed that the introduction of Cu altered the dispersion of Co species, attenuated the interaction between Co species and cerium dioxide, enhanced its reduction extent, and fostered the formation of plentiful cobalt oxide species and oxygen vacancies on the catalyst’s surface. The cooperative influence of Cu and Co heightened the selectivity of the hydrogenolysis reaction. This work provides a novel strategy for the development of greener and more efficient catalytic processes based on non-precious metals that for the selective conversion of biomass-derived furfural to high-value pentanediols.</abstract><cop>England</cop><pub>Elsevier Ltd</pub><pmid>38777229</pmid><doi>10.1016/j.biortech.2024.130858</doi><tpages>1</tpages><orcidid>https://orcid.org/0000-0001-5549-6339</orcidid></addata></record> |
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subjects | Biomass Catalysis Cerium - chemistry Cobalt - chemistry Copper - chemistry Furaldehyde - chemistry Furfural Glycols - chemistry Hydrogenolysis Pentanediol Ring opening |
title | Efficient one-pot transformation of furfural to pentanediol over Cu-modified cobalt-based catalysts |
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