Water-Regulated Evolution of Inversion, Reinversion, and Amplification of Circularly Polarized Luminescence of Supramolecular Organogels Based on Glutamide–Cyanostilbene Amphiphile
Water incorporated with supramolecular building blocks in organic solvents can play a key role in the circularly polarized luminescence (CPL) inversion and amplification of supramolecular assemblies. Herein, we demonstrate that fine-tuning the water content regulated the assembly structure evolution...
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| Veröffentlicht in: | Langmuir 2024-06, Vol.40 (22), p.11548-11557 |
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| container_title | Langmuir |
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| creator | Yang, Yun-Han Wei, Jin-Jian Zhang, Ling |
| description | Water incorporated with supramolecular building blocks in organic solvents can play a key role in the circularly polarized luminescence (CPL) inversion and amplification of supramolecular assemblies. Herein, we demonstrate that fine-tuning the water content regulated the assembly structure evolution and made the circular dichroism and CPL sign of the system undergo intriguing inversion, reinversion, and amplification processes based on a unique and interesting glutamide–cyanostilbene system, as supported by morphology, spectroscopic observations, and time-dependent density functional theory calculation. |
| doi_str_mv | 10.1021/acs.langmuir.4c00652 |
| format | Article |
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| language | eng |
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| source | ACS Publications |
| subjects | circular dichroism spectroscopy density functional theory evolution luminescence organogels surfactants water content |
| title | Water-Regulated Evolution of Inversion, Reinversion, and Amplification of Circularly Polarized Luminescence of Supramolecular Organogels Based on Glutamide–Cyanostilbene Amphiphile |
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