AnB8−: borozene complexes with monovalent actinide
In light of recently reported monovalent lanthanide in borozene complexes LnB8− (Ln = La, Pr, Tb, Tm, Yb), the corresponding AnB8− (An = Ac, Pa, Bk, Md, No) actinide species within the same group were theoretically investigated in respect of oxidation state, stability, electronic structure and chemi...
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| Veröffentlicht in: | Physical chemistry chemical physics : PCCP 2024-06, Vol.26 (22), p.16091-16095 |
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| container_title | Physical chemistry chemical physics : PCCP |
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| creator | Wan-Lu, Li Burkhardt, Jordan |
| description | In light of recently reported monovalent lanthanide in borozene complexes LnB8− (Ln = La, Pr, Tb, Tm, Yb), the corresponding AnB8− (An = Ac, Pa, Bk, Md, No) actinide species within the same group were theoretically investigated in respect of oxidation state, stability, electronic structure and chemical bonding pattern. Our investigations reveal the feasibility of actinides, especially for the late actinide borozene compounds (BkB8−, MdB8−, NoB8−) adopting a monovalent oxidation state of +I, a phenomenon fine-tuned by the doubly aromatic borozene B82−. Early actinides (AcB8−, PaB8−) however exhibit a tendency towards higher trivalent oxidation states. |
| doi_str_mv | 10.1039/d4cp01646g |
| format | Article |
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Our investigations reveal the feasibility of actinides, especially for the late actinide borozene compounds (BkB8−, MdB8−, NoB8−) adopting a monovalent oxidation state of +I, a phenomenon fine-tuned by the doubly aromatic borozene B82−. 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Our investigations reveal the feasibility of actinides, especially for the late actinide borozene compounds (BkB8−, MdB8−, NoB8−) adopting a monovalent oxidation state of +I, a phenomenon fine-tuned by the doubly aromatic borozene B82−. 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Our investigations reveal the feasibility of actinides, especially for the late actinide borozene compounds (BkB8−, MdB8−, NoB8−) adopting a monovalent oxidation state of +I, a phenomenon fine-tuned by the doubly aromatic borozene B82−. Early actinides (AcB8−, PaB8−) however exhibit a tendency towards higher trivalent oxidation states.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d4cp01646g</doi><tpages>5</tpages></addata></record> |
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| ispartof | Physical chemistry chemical physics : PCCP, 2024-06, Vol.26 (22), p.16091-16095 |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Actinides Chemical bonds Electronic structure Oxidation Valence |
| title | AnB8−: borozene complexes with monovalent actinide |
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