Mechanical Properties of a Sustainable Low-Carbon Geopolymer Concrete Using a Pumice-Derived Sodium Silicate Solution
A geopolymer is an inorganic amorphous cementitious material, emerging as an alternative sustainable binder for greener concrete production over Ordinary Portland Cement (OPC). Geopolymer concrete production promotes waste reuse since the applicable precursor materials include agricultural and indus...
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description | A geopolymer is an inorganic amorphous cementitious material, emerging as an alternative sustainable binder for greener concrete production over Ordinary Portland Cement (OPC). Geopolymer concrete production promotes waste reuse since the applicable precursor materials include agricultural and industrial waste that requires disposal, helping to reduce waste in landfills and ensuring sustainable environmental protection. This study investigates the development of an environmentally friendly sodium silicate alternative (SSA) derived from pumice powder (PP) in place of a commercial Na
SiO
solution at a 10 M concentration. Six concrete batches were produced at alkaline/precursor (A/P) ratios of 0.1, 0.2, 0.3, 0.4, and 0.5. The geopolymer mix AF4, with an A/P ratio of 0.4, became the optimum geopolymer concrete design; however, it recorded lower compressive, tensile splitting, and flexural strengths, respectively, against the control OPC concrete. The geopolymer formulations, however, obtained 28-day-hardened concrete densities comparable to the control concrete. The 28-day compressive strength of the OPC concrete was 29.4 MPa, higher than the 18.8 MPa recorded for AF4. However, the 56-day strength of AF4 improved to 22.4 MPa, an around 19% increase compared to the 30.8 MPa achieved by the control mix on day 56, having experienced only a 5% strength increase. The low mechanical performances of the geopolymer formulation could be attributed to extra water added to the original geopolymer design to improve the workability of the geopolymer mix. Therefore, the SSA alkaline solution using PP showed some potential for developing geopolymer concrete for low-strength construction applications. |
doi_str_mv | 10.3390/ma17081792 |
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SiO
solution at a 10 M concentration. Six concrete batches were produced at alkaline/precursor (A/P) ratios of 0.1, 0.2, 0.3, 0.4, and 0.5. The geopolymer mix AF4, with an A/P ratio of 0.4, became the optimum geopolymer concrete design; however, it recorded lower compressive, tensile splitting, and flexural strengths, respectively, against the control OPC concrete. The geopolymer formulations, however, obtained 28-day-hardened concrete densities comparable to the control concrete. The 28-day compressive strength of the OPC concrete was 29.4 MPa, higher than the 18.8 MPa recorded for AF4. However, the 56-day strength of AF4 improved to 22.4 MPa, an around 19% increase compared to the 30.8 MPa achieved by the control mix on day 56, having experienced only a 5% strength increase. The low mechanical performances of the geopolymer formulation could be attributed to extra water added to the original geopolymer design to improve the workability of the geopolymer mix. Therefore, the SSA alkaline solution using PP showed some potential for developing geopolymer concrete for low-strength construction applications.</description><identifier>ISSN: 1996-1944</identifier><identifier>EISSN: 1996-1944</identifier><identifier>DOI: 10.3390/ma17081792</identifier><identifier>PMID: 38673149</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Agricultural wastes ; Alkalinity ; Amorphous materials ; Carbon dioxide ; Caustic soda ; Cement ; Compressive strength ; Concrete ; Concrete mixing ; Environmental impact ; Environmental protection ; Flexural strength ; Geopolymers ; Industrial wastes ; Mechanical properties ; Portland cements ; Precursors ; Pumice ; Silica ; Sodium ; Sodium silicates ; Waste materials ; Workability</subject><ispartof>Materials, 2024-04, Vol.17 (8), p.1792</ispartof><rights>COPYRIGHT 2024 MDPI AG</rights><rights>2024 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c390t-3eddd7f09ed6609e40e0e3d6cb5611f131065c5b32c1ced88791fe610c1de03d3</citedby><cites>FETCH-LOGICAL-c390t-3eddd7f09ed6609e40e0e3d6cb5611f131065c5b32c1ced88791fe610c1de03d3</cites><orcidid>0000-0002-6702-4811 ; 0000-0002-5968-5089 ; 0000-0002-3273-846X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/38673149$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Oti, Jonathan</creatorcontrib><creatorcontrib>Adeleke, Blessing O</creatorcontrib><creatorcontrib>Anowie, Francis X</creatorcontrib><creatorcontrib>Kinuthia, John M</creatorcontrib><creatorcontrib>Ekwulo, Emma</creatorcontrib><title>Mechanical Properties of a Sustainable Low-Carbon Geopolymer Concrete Using a Pumice-Derived Sodium Silicate Solution</title><title>Materials</title><addtitle>Materials (Basel)</addtitle><description>A geopolymer is an inorganic amorphous cementitious material, emerging as an alternative sustainable binder for greener concrete production over Ordinary Portland Cement (OPC). Geopolymer concrete production promotes waste reuse since the applicable precursor materials include agricultural and industrial waste that requires disposal, helping to reduce waste in landfills and ensuring sustainable environmental protection. This study investigates the development of an environmentally friendly sodium silicate alternative (SSA) derived from pumice powder (PP) in place of a commercial Na
SiO
solution at a 10 M concentration. Six concrete batches were produced at alkaline/precursor (A/P) ratios of 0.1, 0.2, 0.3, 0.4, and 0.5. The geopolymer mix AF4, with an A/P ratio of 0.4, became the optimum geopolymer concrete design; however, it recorded lower compressive, tensile splitting, and flexural strengths, respectively, against the control OPC concrete. The geopolymer formulations, however, obtained 28-day-hardened concrete densities comparable to the control concrete. The 28-day compressive strength of the OPC concrete was 29.4 MPa, higher than the 18.8 MPa recorded for AF4. However, the 56-day strength of AF4 improved to 22.4 MPa, an around 19% increase compared to the 30.8 MPa achieved by the control mix on day 56, having experienced only a 5% strength increase. The low mechanical performances of the geopolymer formulation could be attributed to extra water added to the original geopolymer design to improve the workability of the geopolymer mix. Therefore, the SSA alkaline solution using PP showed some potential for developing geopolymer concrete for low-strength construction applications.</description><subject>Agricultural wastes</subject><subject>Alkalinity</subject><subject>Amorphous materials</subject><subject>Carbon dioxide</subject><subject>Caustic soda</subject><subject>Cement</subject><subject>Compressive strength</subject><subject>Concrete</subject><subject>Concrete mixing</subject><subject>Environmental impact</subject><subject>Environmental protection</subject><subject>Flexural strength</subject><subject>Geopolymers</subject><subject>Industrial wastes</subject><subject>Mechanical properties</subject><subject>Portland cements</subject><subject>Precursors</subject><subject>Pumice</subject><subject>Silica</subject><subject>Sodium</subject><subject>Sodium silicates</subject><subject>Waste materials</subject><subject>Workability</subject><issn>1996-1944</issn><issn>1996-1944</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNpdkV1LHTEQhkNRVKw3_oAS8KYU1mZOdrObSzlWWzhF4ej1kk1mbSSbHJON4r839dgPnMBMCM87meEl5BjYKeeSfZ0UtKyDVi4-kAOQUlQg63rnv_s-OUrpnpXgHLqF3CP7vBMth1oekPwT9S_lrVaOXsewwThbTDSMVNF1TrOyXg0O6So8VUsVh-DpJYZNcM8TRroMXkeckd4m6--K5DpPVmN1jtE-oqHrYGye6Nq68kHB1sHl2Qb_keyOyiU8equH5Pbi283ye7W6uvyxPFtVuqw2VxyNMe3IJBohSq4ZMuRG6KERACNwYKLRzcAXGjSarmsljCiAaTDIuOGH5PO27yaGh4xp7iebNDqnPIaces7qVjasq2VBT96h9yFHX6Z7pRirm6Yu1OmWulMOe-vHMEelyzFYFg8eR1vez1rJG8EaDkXwZSvQMaQUcew30U4qPvfA-t8G9v8MLPCntxnyMKH5i_6xi78AJFaVLw</recordid><startdate>20240413</startdate><enddate>20240413</enddate><creator>Oti, Jonathan</creator><creator>Adeleke, Blessing O</creator><creator>Anowie, Francis X</creator><creator>Kinuthia, John M</creator><creator>Ekwulo, Emma</creator><general>MDPI AG</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-6702-4811</orcidid><orcidid>https://orcid.org/0000-0002-5968-5089</orcidid><orcidid>https://orcid.org/0000-0002-3273-846X</orcidid></search><sort><creationdate>20240413</creationdate><title>Mechanical Properties of a Sustainable Low-Carbon Geopolymer Concrete Using a Pumice-Derived Sodium Silicate Solution</title><author>Oti, Jonathan ; Adeleke, Blessing O ; Anowie, Francis X ; Kinuthia, John M ; Ekwulo, Emma</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c390t-3eddd7f09ed6609e40e0e3d6cb5611f131065c5b32c1ced88791fe610c1de03d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Agricultural wastes</topic><topic>Alkalinity</topic><topic>Amorphous materials</topic><topic>Carbon dioxide</topic><topic>Caustic soda</topic><topic>Cement</topic><topic>Compressive strength</topic><topic>Concrete</topic><topic>Concrete mixing</topic><topic>Environmental impact</topic><topic>Environmental protection</topic><topic>Flexural strength</topic><topic>Geopolymers</topic><topic>Industrial wastes</topic><topic>Mechanical properties</topic><topic>Portland cements</topic><topic>Precursors</topic><topic>Pumice</topic><topic>Silica</topic><topic>Sodium</topic><topic>Sodium silicates</topic><topic>Waste materials</topic><topic>Workability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Oti, Jonathan</creatorcontrib><creatorcontrib>Adeleke, Blessing O</creatorcontrib><creatorcontrib>Anowie, Francis X</creatorcontrib><creatorcontrib>Kinuthia, John M</creatorcontrib><creatorcontrib>Ekwulo, Emma</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>MEDLINE - Academic</collection><jtitle>Materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Oti, Jonathan</au><au>Adeleke, Blessing O</au><au>Anowie, Francis X</au><au>Kinuthia, John M</au><au>Ekwulo, Emma</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Mechanical Properties of a Sustainable Low-Carbon Geopolymer Concrete Using a Pumice-Derived Sodium Silicate Solution</atitle><jtitle>Materials</jtitle><addtitle>Materials (Basel)</addtitle><date>2024-04-13</date><risdate>2024</risdate><volume>17</volume><issue>8</issue><spage>1792</spage><pages>1792-</pages><issn>1996-1944</issn><eissn>1996-1944</eissn><abstract>A geopolymer is an inorganic amorphous cementitious material, emerging as an alternative sustainable binder for greener concrete production over Ordinary Portland Cement (OPC). Geopolymer concrete production promotes waste reuse since the applicable precursor materials include agricultural and industrial waste that requires disposal, helping to reduce waste in landfills and ensuring sustainable environmental protection. This study investigates the development of an environmentally friendly sodium silicate alternative (SSA) derived from pumice powder (PP) in place of a commercial Na
SiO
solution at a 10 M concentration. Six concrete batches were produced at alkaline/precursor (A/P) ratios of 0.1, 0.2, 0.3, 0.4, and 0.5. The geopolymer mix AF4, with an A/P ratio of 0.4, became the optimum geopolymer concrete design; however, it recorded lower compressive, tensile splitting, and flexural strengths, respectively, against the control OPC concrete. The geopolymer formulations, however, obtained 28-day-hardened concrete densities comparable to the control concrete. The 28-day compressive strength of the OPC concrete was 29.4 MPa, higher than the 18.8 MPa recorded for AF4. However, the 56-day strength of AF4 improved to 22.4 MPa, an around 19% increase compared to the 30.8 MPa achieved by the control mix on day 56, having experienced only a 5% strength increase. The low mechanical performances of the geopolymer formulation could be attributed to extra water added to the original geopolymer design to improve the workability of the geopolymer mix. Therefore, the SSA alkaline solution using PP showed some potential for developing geopolymer concrete for low-strength construction applications.</abstract><cop>Switzerland</cop><pub>MDPI AG</pub><pmid>38673149</pmid><doi>10.3390/ma17081792</doi><orcidid>https://orcid.org/0000-0002-6702-4811</orcidid><orcidid>https://orcid.org/0000-0002-5968-5089</orcidid><orcidid>https://orcid.org/0000-0002-3273-846X</orcidid><oa>free_for_read</oa></addata></record> |
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subjects | Agricultural wastes Alkalinity Amorphous materials Carbon dioxide Caustic soda Cement Compressive strength Concrete Concrete mixing Environmental impact Environmental protection Flexural strength Geopolymers Industrial wastes Mechanical properties Portland cements Precursors Pumice Silica Sodium Sodium silicates Waste materials Workability |
title | Mechanical Properties of a Sustainable Low-Carbon Geopolymer Concrete Using a Pumice-Derived Sodium Silicate Solution |
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