Water and Air Stable Copper(I) Complexes of Tetracationic Catenane Ligands for Oxidative C−C Cross‐Coupling

Aqueous soluble and stable Cu(I) molecular catalysts featuring a catenane ligand composed of two dicationic, mutually repelling but mechanically interlocked macrocycles are reported. The ligand interlocking not only fine‐tunes the coordination sphere and kinetically stabilizes the Cu(I) against air...

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Veröffentlicht in:	Angewandte Chemie International Edition 2024-07, Vol.63 (28), p.e202405971-n/a
Hauptverfasser:	Tang, Man Pang, Zhu, Lihui, Deng, Yulin, Shi, Yi‐Xiang, Kin‐Man Lai, Samuel, Mo, Xiaoyong, Pang, Xin‐Yu, Liu, Chunyu, Jiang, Wei, Tse, Edmund Chun Ming, Au‐Yeung, Ho Yu
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Catalysts catenane cationic ligands Copper Cross coupling Disproportionation Hydrogen peroxide Hydrophobicity Indoles Ligands mechanical interlocking Mechanical properties Oxidants Oxidation oxidative coupling Oxidizing agents Substrates Transition metals
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