Triple Role of Proton Sponge (DMAN) in the Palladium-Catalyzed Direct Stereoselective Synthesis of C‑Aryl Glycosides from Glycals

The triple role of 1,8-bis­(dimethylamino)­naphthalene (proton sponge) as a reductant, ligand precursor, and organic base in the palladium-catalyzed Heck-type coupling reaction of glycals with aryl iodides affords the rapid and stereoselective synthesis of 2′,3′-unsaturated α-C-aryl glycosides in ex...

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Veröffentlicht in:	Organic letters 2024-05, Vol.26 (17), p.3563-3568
Hauptverfasser:	Pradhan, Priyanka, Moktan, Sangay, Biswas, Ashish, Das, Animesh, Lenka, Rajesh, Kancharla, Pavan K.
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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