Ultrathin Zn-Gallate Catalyst: A Remarkable Performer in CO2 and Propylene Oxide Polymerization
Zn-gallate, an innovative catalyst synthesized using cost-effective zinc salts and gallic acid without complicated synthetic procedures, has been successfully applied in the copolymerization of CO2 and propylene oxide. Zn-gallate displays exceptionally thin sheets with a thickness of 1–2 nm, leading...
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| Veröffentlicht in: | ACS sustainable chemistry & engineering 2024-03, Vol.12 (10), p.3933-3940 |
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| creator | Yang, Yongmoon Sung, Kihyuk Lee, Jong Doo Ha, Junho Kim, Heeyoun Baek, Jinsu Seo, Jeong Hwa Kim, Seung-Joo Lee, Bun Yeoul Son, Seung Uk Kim, Byeong-Su Kim, Yongsun Park, Ji-Yong Jang, Hye-Young |
| description | Zn-gallate, an innovative catalyst synthesized using cost-effective zinc salts and gallic acid without complicated synthetic procedures, has been successfully applied in the copolymerization of CO2 and propylene oxide. Zn-gallate displays exceptionally thin sheets with a thickness of 1–2 nm, leading to remarkable catalytic activity, high carbonate linkage proportion, and minimal monomer formation (3.01 kg/g-cat, fCO2 = 0.97, and selectivity 91%). Zn-gallate outperforms other heterogeneous catalysts for the polymerization of CO2 and propylene oxide. Furthermore, the polycarbonates synthesized using Zn-gallate exhibit substantially high molecular weights. A comprehensive characterization of Zn-gallate has been undertaken, employing SEM, TEM, BET, AFM, PXRD, IR, CP-TOSS 13C NMR, XPS, TGA, and ICP analyses, which provided valuable insights into the exceptional catalytic properties of this novel catalyst. |
| doi_str_mv | 10.1021/acssuschemeng.3c06058 |
| format | Article |
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Zn-gallate displays exceptionally thin sheets with a thickness of 1–2 nm, leading to remarkable catalytic activity, high carbonate linkage proportion, and minimal monomer formation (3.01 kg/g-cat, fCO2 = 0.97, and selectivity 91%). Zn-gallate outperforms other heterogeneous catalysts for the polymerization of CO2 and propylene oxide. Furthermore, the polycarbonates synthesized using Zn-gallate exhibit substantially high molecular weights. A comprehensive characterization of Zn-gallate has been undertaken, employing SEM, TEM, BET, AFM, PXRD, IR, CP-TOSS 13C NMR, XPS, TGA, and ICP analyses, which provided valuable insights into the exceptional catalytic properties of this novel catalyst.</description><identifier>ISSN: 2168-0485</identifier><identifier>EISSN: 2168-0485</identifier><identifier>DOI: 10.1021/acssuschemeng.3c06058</identifier><language>eng</language><publisher>American Chemical Society</publisher><subject>carbon dioxide ; carbonates ; catalysts ; catalytic activity ; copolymerization ; cost effectiveness ; gallic acid ; green chemistry ; propylene oxide ; zinc</subject><ispartof>ACS sustainable chemistry & engineering, 2024-03, Vol.12 (10), p.3933-3940</ispartof><rights>2024 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0002-6419-3054 ; 0000-0003-4471-2328 ; 0000-0002-4779-9302 ; 0000-0002-9945-5181 ; 0000-0002-1491-6103 ; 0000-0002-6393-9176 ; 0000-0001-5117-3532</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acssuschemeng.3c06058$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acssuschemeng.3c06058$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,27053,27901,27902,56713,56763</link.rule.ids></links><search><creatorcontrib>Yang, Yongmoon</creatorcontrib><creatorcontrib>Sung, Kihyuk</creatorcontrib><creatorcontrib>Lee, Jong Doo</creatorcontrib><creatorcontrib>Ha, Junho</creatorcontrib><creatorcontrib>Kim, Heeyoun</creatorcontrib><creatorcontrib>Baek, Jinsu</creatorcontrib><creatorcontrib>Seo, Jeong Hwa</creatorcontrib><creatorcontrib>Kim, Seung-Joo</creatorcontrib><creatorcontrib>Lee, Bun Yeoul</creatorcontrib><creatorcontrib>Son, Seung Uk</creatorcontrib><creatorcontrib>Kim, Byeong-Su</creatorcontrib><creatorcontrib>Kim, Yongsun</creatorcontrib><creatorcontrib>Park, Ji-Yong</creatorcontrib><creatorcontrib>Jang, Hye-Young</creatorcontrib><title>Ultrathin Zn-Gallate Catalyst: A Remarkable Performer in CO2 and Propylene Oxide Polymerization</title><title>ACS sustainable chemistry & engineering</title><addtitle>ACS Sustainable Chem. Eng</addtitle><description>Zn-gallate, an innovative catalyst synthesized using cost-effective zinc salts and gallic acid without complicated synthetic procedures, has been successfully applied in the copolymerization of CO2 and propylene oxide. Zn-gallate displays exceptionally thin sheets with a thickness of 1–2 nm, leading to remarkable catalytic activity, high carbonate linkage proportion, and minimal monomer formation (3.01 kg/g-cat, fCO2 = 0.97, and selectivity 91%). Zn-gallate outperforms other heterogeneous catalysts for the polymerization of CO2 and propylene oxide. Furthermore, the polycarbonates synthesized using Zn-gallate exhibit substantially high molecular weights. A comprehensive characterization of Zn-gallate has been undertaken, employing SEM, TEM, BET, AFM, PXRD, IR, CP-TOSS 13C NMR, XPS, TGA, and ICP analyses, which provided valuable insights into the exceptional catalytic properties of this novel catalyst.</description><subject>carbon dioxide</subject><subject>carbonates</subject><subject>catalysts</subject><subject>catalytic activity</subject><subject>copolymerization</subject><subject>cost effectiveness</subject><subject>gallic acid</subject><subject>green chemistry</subject><subject>propylene oxide</subject><subject>zinc</subject><issn>2168-0485</issn><issn>2168-0485</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpVkM9LwzAUx4MoOOb-BCFHL5350TStt1F0CsKGuIuXkKavrjNNZ5KC86-3sh30Xd47fHh8vx-ErimZU8LorTYhDMFsoQP3PueGZETkZ2jCaJYnJM3F-Z_7Es1C2JFxioKznE6Q2tjoddy2Dr-5ZKmt1RFwqaO2hxDv8AK_QKf9h64s4DX4pvcdeDzi5Yph7Wq89v3-YMEBXn219Qj19jAi7beObe-u0EWjbYDZaU_R5uH-tXxMnlfLp3LxnGjGSUwkyLxmpiCNyWkmioJwyg3lRFQcaiEYFyaTpk6pTGWasqYRNZdAJMlNVbOKT9HN8e_e958DhKi6NhgY6zjoh6A4SUkqJWdiROkRHdWpXT94NwZTlKhfn-qfT3XyyX8Avw9sPQ</recordid><startdate>20240311</startdate><enddate>20240311</enddate><creator>Yang, Yongmoon</creator><creator>Sung, Kihyuk</creator><creator>Lee, Jong Doo</creator><creator>Ha, Junho</creator><creator>Kim, Heeyoun</creator><creator>Baek, Jinsu</creator><creator>Seo, Jeong Hwa</creator><creator>Kim, Seung-Joo</creator><creator>Lee, Bun Yeoul</creator><creator>Son, Seung Uk</creator><creator>Kim, Byeong-Su</creator><creator>Kim, Yongsun</creator><creator>Park, Ji-Yong</creator><creator>Jang, Hye-Young</creator><general>American Chemical Society</general><scope>7S9</scope><scope>L.6</scope><orcidid>https://orcid.org/0000-0002-6419-3054</orcidid><orcidid>https://orcid.org/0000-0003-4471-2328</orcidid><orcidid>https://orcid.org/0000-0002-4779-9302</orcidid><orcidid>https://orcid.org/0000-0002-9945-5181</orcidid><orcidid>https://orcid.org/0000-0002-1491-6103</orcidid><orcidid>https://orcid.org/0000-0002-6393-9176</orcidid><orcidid>https://orcid.org/0000-0001-5117-3532</orcidid></search><sort><creationdate>20240311</creationdate><title>Ultrathin Zn-Gallate Catalyst: A Remarkable Performer in CO2 and Propylene Oxide Polymerization</title><author>Yang, Yongmoon ; Sung, Kihyuk ; Lee, Jong Doo ; Ha, Junho ; Kim, Heeyoun ; Baek, Jinsu ; Seo, Jeong Hwa ; Kim, Seung-Joo ; Lee, Bun Yeoul ; Son, Seung Uk ; Kim, Byeong-Su ; Kim, Yongsun ; Park, Ji-Yong ; Jang, Hye-Young</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a230t-7e78d2c90fc8165990313c1305b3ed55235c67cd41747442ff5d37e0708cbd2b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>carbon dioxide</topic><topic>carbonates</topic><topic>catalysts</topic><topic>catalytic activity</topic><topic>copolymerization</topic><topic>cost effectiveness</topic><topic>gallic acid</topic><topic>green chemistry</topic><topic>propylene oxide</topic><topic>zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yang, Yongmoon</creatorcontrib><creatorcontrib>Sung, Kihyuk</creatorcontrib><creatorcontrib>Lee, Jong Doo</creatorcontrib><creatorcontrib>Ha, Junho</creatorcontrib><creatorcontrib>Kim, Heeyoun</creatorcontrib><creatorcontrib>Baek, Jinsu</creatorcontrib><creatorcontrib>Seo, Jeong Hwa</creatorcontrib><creatorcontrib>Kim, Seung-Joo</creatorcontrib><creatorcontrib>Lee, Bun Yeoul</creatorcontrib><creatorcontrib>Son, Seung Uk</creatorcontrib><creatorcontrib>Kim, Byeong-Su</creatorcontrib><creatorcontrib>Kim, Yongsun</creatorcontrib><creatorcontrib>Park, Ji-Yong</creatorcontrib><creatorcontrib>Jang, Hye-Young</creatorcontrib><collection>AGRICOLA</collection><collection>AGRICOLA - Academic</collection><jtitle>ACS sustainable chemistry & engineering</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yang, Yongmoon</au><au>Sung, Kihyuk</au><au>Lee, Jong Doo</au><au>Ha, Junho</au><au>Kim, Heeyoun</au><au>Baek, Jinsu</au><au>Seo, Jeong Hwa</au><au>Kim, Seung-Joo</au><au>Lee, Bun Yeoul</au><au>Son, Seung Uk</au><au>Kim, Byeong-Su</au><au>Kim, Yongsun</au><au>Park, Ji-Yong</au><au>Jang, Hye-Young</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ultrathin Zn-Gallate Catalyst: A Remarkable Performer in CO2 and Propylene Oxide Polymerization</atitle><jtitle>ACS sustainable chemistry & engineering</jtitle><addtitle>ACS Sustainable Chem. Eng</addtitle><date>2024-03-11</date><risdate>2024</risdate><volume>12</volume><issue>10</issue><spage>3933</spage><epage>3940</epage><pages>3933-3940</pages><issn>2168-0485</issn><eissn>2168-0485</eissn><abstract>Zn-gallate, an innovative catalyst synthesized using cost-effective zinc salts and gallic acid without complicated synthetic procedures, has been successfully applied in the copolymerization of CO2 and propylene oxide. Zn-gallate displays exceptionally thin sheets with a thickness of 1–2 nm, leading to remarkable catalytic activity, high carbonate linkage proportion, and minimal monomer formation (3.01 kg/g-cat, fCO2 = 0.97, and selectivity 91%). Zn-gallate outperforms other heterogeneous catalysts for the polymerization of CO2 and propylene oxide. Furthermore, the polycarbonates synthesized using Zn-gallate exhibit substantially high molecular weights. A comprehensive characterization of Zn-gallate has been undertaken, employing SEM, TEM, BET, AFM, PXRD, IR, CP-TOSS 13C NMR, XPS, TGA, and ICP analyses, which provided valuable insights into the exceptional catalytic properties of this novel catalyst.</abstract><pub>American Chemical Society</pub><doi>10.1021/acssuschemeng.3c06058</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-6419-3054</orcidid><orcidid>https://orcid.org/0000-0003-4471-2328</orcidid><orcidid>https://orcid.org/0000-0002-4779-9302</orcidid><orcidid>https://orcid.org/0000-0002-9945-5181</orcidid><orcidid>https://orcid.org/0000-0002-1491-6103</orcidid><orcidid>https://orcid.org/0000-0002-6393-9176</orcidid><orcidid>https://orcid.org/0000-0001-5117-3532</orcidid></addata></record> |
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| subjects | carbon dioxide carbonates catalysts catalytic activity copolymerization cost effectiveness gallic acid green chemistry propylene oxide zinc |
| title | Ultrathin Zn-Gallate Catalyst: A Remarkable Performer in CO2 and Propylene Oxide Polymerization |
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